全文获取类型
收费全文 | 671篇 |
免费 | 7篇 |
国内免费 | 2篇 |
专业分类
安全科学 | 22篇 |
废物处理 | 21篇 |
环保管理 | 76篇 |
综合类 | 181篇 |
基础理论 | 126篇 |
污染及防治 | 157篇 |
评价与监测 | 63篇 |
社会与环境 | 32篇 |
灾害及防治 | 2篇 |
出版年
2023年 | 7篇 |
2022年 | 16篇 |
2021年 | 17篇 |
2020年 | 11篇 |
2019年 | 13篇 |
2018年 | 22篇 |
2017年 | 18篇 |
2016年 | 42篇 |
2015年 | 22篇 |
2014年 | 36篇 |
2013年 | 41篇 |
2012年 | 25篇 |
2011年 | 38篇 |
2010年 | 24篇 |
2009年 | 17篇 |
2008年 | 26篇 |
2007年 | 25篇 |
2006年 | 17篇 |
2005年 | 10篇 |
2004年 | 6篇 |
2003年 | 10篇 |
2002年 | 9篇 |
2001年 | 6篇 |
2000年 | 6篇 |
1999年 | 5篇 |
1998年 | 5篇 |
1997年 | 7篇 |
1996年 | 6篇 |
1994年 | 14篇 |
1993年 | 11篇 |
1991年 | 8篇 |
1990年 | 9篇 |
1989年 | 6篇 |
1985年 | 5篇 |
1978年 | 5篇 |
1976年 | 6篇 |
1974年 | 4篇 |
1973年 | 4篇 |
1972年 | 5篇 |
1970年 | 7篇 |
1965年 | 4篇 |
1964年 | 5篇 |
1962年 | 4篇 |
1961年 | 4篇 |
1960年 | 5篇 |
1959年 | 5篇 |
1957年 | 7篇 |
1956年 | 4篇 |
1955年 | 9篇 |
1934年 | 4篇 |
排序方式: 共有680条查询结果,搜索用时 343 毫秒
91.
The stereoisomers of metolachlor and its two polar metabolites [ethane sulfonic acid (ESA) and oxanilic acid (OXA)] were separated using liquid chromatography-mass spectrometry (LC-MS) and capillary zone electrophoresis (CZE), respectively. The separation of metolachlor enantiomers was achieved using a LC-MS equipped with a chiral stationary phase based on cellulose tris(3,5-dimethylphenyl carbamate) and an atmospheric pressure chemical ionization source operated under positive ion mode. The enantiomers of ESA and OXA were separated using CZE with gamma-cyclodextrin (gamma-CD) as chiral selector. Various CZE conditions were investigated to achieve the best resolution of the ESA and OXA enantiomers. The optimum background CZE electrolyte was found to consist of borate buffer (pH=9) containing 20% methanol (v/v) and 2.5% gamma-CD (w/v). Maximum resolution of ESA and OXA enantiomers was achieved using a capillary temperature of 15 degrees C and applied voltage of 30 kV. The applicability of the LC-MS and CZE methods was demonstrated successfully on the enantiomeric analysis of metolachlor and its metabolites in samples from a soil and water degradation study that was set up to probe the stereoselectivity of metolachlor biodegradation. These techniques allow the enantiomeric ratios of the target analytes to be followed over time during the degradation process and thus will prove useful in determining the role of chirality in pesticide degradation and metabolite formation. 相似文献
92.
Araújo CV Cohin-de-Pinho SJ da S Santos J Delgado F Santana LC Chastinet CB da Silva EM 《Chemosphere》2006,65(4):599-603
The suitability and viability of acute in situ bioassays were investigated in the biomonitoring program of an acidic lake contaminated with sulphur residues. Responses of organisms observed in laboratory and in situ bioassays were also assessed to determine whether or not they were similar and comparable, regarding accuracy and precision. Newborn Poecilia reticulata were employed as test organisms and exposed to the same water samples under in situ and laboratory conditions. Mortality/immobility was the endpoint assessed and dead/immobile organisms were counted at various time intervals during exposure. The mean calculated LT50 values and 95% confidence intervals were 1.61 (1.36-1.87) h in the laboratory bioassays and 0.72 (0.55-0.89) h in the in situ bioassays. Statistical comparison of these values revealed a significant difference (p<0.05). In situ bioassays were more accurate than those carried out in the laboratory, demonstrating higher sensitivity and better reproduction of what occurs in nature, while laboratory bioassays were more precise. 相似文献
93.
Maysa Venturoso Gongora Buckeridge Serra Paula Rezende Camargo José Eduardo Zaia Maria Georgina Marques Tonello 《International journal of occupational safety and ergonomics》2018,24(1):62-67
Background. The effect of physical exercise in the workplace (PEW) on health promotion of workers is contradictory. Objective. To evaluate the effects of the PEW in musculoskeletal disorders (MSDs), perception of stress and quality of life in workers. Methods. The participants were divided into two groups: control group (n?=?46) including non-participant workers of the PEW program, and PEW group (n?=?50) including workers who regularly participate in the exercise program. All workers answered the Nordic general questionnaire, the perceived stress scale and the quality-of-life questionnaire. Results. The PEW group reported a lower prevalence of MSDs for the trunk in the last 7 days and 12 months (p?=?0.021 and p?=?0.001, respectively), and for the upper limbs in the last 12 months (p?=?0.001) compared with the control group. The results for the perception of stress and quality of life showed no significant differences between the groups. Conclusion. PEW is a potential method to reduce MSDs in workers, but it was not efficient in reducing stress levels or improving the quality of life of the workers. 相似文献
94.
Senna Guilherme Nohra Serra Eduardo Gonçalves 《Environment, Development and Sustainability》2021,23(11):16325-16342
Environment, Development and Sustainability - This paper estimates the genuine progress indicator (GPI) for the state of Rio de Janeiro (RJ), Brazil, from 2002 to 2016 as an alternative indicator... 相似文献
95.
Agroecosystem energy transitions: exploring the energy-land nexus in the course of industrialization
Regional Environmental Change - 相似文献
96.
Ferrazzo Suéllen Tonatto Tímbola Rafael de Souza Bragagnolo Lucimara Prestes Elvis Korf Eduardo Pavan Prietto Pedro Domingos Marques Ulsen Carina 《Environmental science and pollution research international》2020,27(30):37718-37732
Environmental Science and Pollution Research - Exposure of geomaterials to acidic leachates may compromise their structure and functionality due to changes in physicochemical, mineralogical, and... 相似文献
97.
Thais Cristina de Oliveira Souza Rafael Coll Delgado Iris Cristiane Magistrali Gilsonley Lopes dos Santos Daniel Costa de Carvalho Paulo Eduardo Teodoro Carlos Antônio da Silva Júnior Rodrigo Hotzz Caúla 《Environmental monitoring and assessment》2018,190(11):688
This study aimed to analyze the spectral trend of vegetation with rainfall in El Niño-Southern Oscillation events (ENSO) in the Atlantic Forest, Brazil. Monthly rainfall data were collected from 85 conventional meteorological stations (EMC), data from the Enhanced Vegetation Index 2 (EVI2) and ENSO events (El Niño, La Niña, and Neutral) in the period from 2001 to 2013. Afterwards, state cluster analysis was performed using the results of non-parametric tests. The Mann-Kendall (MK) non-parametric test did not identify a trend pattern in rainfall distribution in the Atlantic Forest. The results for EVI2 by state and region showed that the trend is decreasing in the Northeast Region, except for the states of Alagoas and Pernambuco. Southeast region showed an increasing trend of EVI2 (except for Rio de Janeiro and São Paulo), while the South region showed a decreasing trend. In the Midwest, the trend was significantly decreasing. In the prognosis elaborated for the future, the regions with significant declines of the vegetation were the Northeast and Midwest. This study shows that the Atlantic Forest in some regions of Brazil has been suffering from the growing urbanization process and there is a trend of soil degradation. 相似文献
98.
99.
Ana Victoria Marta-Sanchez Sergiane Souza Caldas Antunielle Schneider Sónia Maria Vaz Sanches Cardoso Ednei Gilberto Primel 《Environmental science and pollution research international》2018,25(15):14460-14470
Parabens have been widely used as antimicrobial agents, mainly in food products, pharmaceuticals, and cosmetics. Although they are known as safe preservatives, they also cause some harm to human health, which has been discussed lately. Therefore, the aim of this study was to evaluate the occurrence of nine parabens (including isomers) in mineral and drinking waters, besides in drinking water treatment sludge (DWTS) samples with determination by liquid chromatography tandem mass spectrometry (LC-MS/MS). Both methods solid phase extraction (SPE) and QuEChERS were validated. Calibration curves showed a correlation coefficient of 0.99 for all compounds. LOQ values ranged from 0.04 to 4 μg L?1 in aqueous matrices and from 5 to 500 ng g?1 in DWTS. Recoveries between 70 and 115% were reached with RSD below 20% for all compounds in SPE whereas recoveries between 62 and 119% were found with RSD below 20% for almost all compounds in QuEChERS. Matrix effect had low values (<?20%); it was only above 20% for methylparaben in the SPE and for pentylparaben in the QuEChERS. Using a quick and simple extraction procedures with SPE, QuEChERS, and LC-MS/MS analyses, these methods proved to be selective and sensitive. They were successfully applied to real samples (treated water, mineral water, and sludge), and methylparaben was detected at concentration levels below 0.242 μg L?1 in mineral and treated water samples and 10 ng g?1 in DWTS samples. 相似文献
100.
Summary. Analysis of South-East Asian troidine swallowtails revealed high variability in the content of aristolochic acids among individuals.
The presence or absence of these compounds depends on the Aristolochia species available as food plant for the larvae. Only one plant species (Aristolochia philippinensis) contained a high concentration of aristolochic acids, while other species from various localities contained none or only
marginal amounts. Whether aristolochic acids have a distinct function in chemical defense of these swallowtails is still an
open question.
Received 11 December 2000; accepted 4 August 2001. 相似文献