全文获取类型
收费全文 | 1421篇 |
免费 | 99篇 |
国内免费 | 511篇 |
专业分类
安全科学 | 123篇 |
废物处理 | 87篇 |
环保管理 | 99篇 |
综合类 | 844篇 |
基础理论 | 275篇 |
污染及防治 | 448篇 |
评价与监测 | 54篇 |
社会与环境 | 46篇 |
灾害及防治 | 55篇 |
出版年
2024年 | 1篇 |
2023年 | 25篇 |
2022年 | 83篇 |
2021年 | 68篇 |
2020年 | 67篇 |
2019年 | 55篇 |
2018年 | 61篇 |
2017年 | 65篇 |
2016年 | 70篇 |
2015年 | 100篇 |
2014年 | 117篇 |
2013年 | 147篇 |
2012年 | 124篇 |
2011年 | 154篇 |
2010年 | 100篇 |
2009年 | 91篇 |
2008年 | 82篇 |
2007年 | 80篇 |
2006年 | 72篇 |
2005年 | 68篇 |
2004年 | 46篇 |
2003年 | 51篇 |
2002年 | 37篇 |
2001年 | 34篇 |
2000年 | 40篇 |
1999年 | 41篇 |
1998年 | 31篇 |
1997年 | 24篇 |
1996年 | 16篇 |
1995年 | 23篇 |
1994年 | 18篇 |
1993年 | 16篇 |
1992年 | 6篇 |
1991年 | 4篇 |
1990年 | 4篇 |
1989年 | 4篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1986年 | 1篇 |
排序方式: 共有2031条查询结果,搜索用时 218 毫秒
991.
Wang G.Yang X.Li Y.Ding X.Shen Y. 《应用与环境生物学报》2018,(3):450-456
Nitrous oxide (N2O) is one of the potent greenhouse gases (GHG) that depletes the stratospheric ozone. Nitrogen fertilizers are considered to be a major source of nitrous oxide (N2O) emissions from arable soils. To investigate the characteristics of N2O emission, its influencing factors, and its response to nitrogen application in dry grassland in the Loess Plateau, one of the most intensively used agricultural regions in China, we conducted a field trial with two treatments including N0 (0 kg hm-2) and N150 (150 kg hm-2) at the Qingyang Loess Plateau grassland agricultural research station of Lanzhou University. An LGR-N2O/CO gas analyzer was used to monitor the emissions. The results showed that the N2O fluxes of the N0 and N150 treatments during the monitoring period were -0.0036 and 0.0118 mg m-2 h-1, respectively; the flux in case of the N150 treatment was significantly higher than that for the N0 treatment. The N2O emission flux has a distinct diurnal variation characteristic, which first showed the trend of decreasing and then increasing. Regression analysis indicated a significant positive correlation between the N2O flux and the surface soil water content at a depth of 10 cm. The N2O emission flux increased by 131.3%, compared with that during the non-precipitation days. At the same time, the N2O emission flux showed a trend of decreasing with the increase of the surface soil temperature at a depth of 10 cm. The daily emission characteristics indicated that there may be a significant underestimation of the N2O flux at the daily or longer time-scale, based on the N2O flux value measured at 9:00-11:00. In summary, the N2O emissions from the sown alfalfa grassland of the eastern Gansu are strongly affected by precipitation and nitrogen application and have obvious daily dynamic characteristics. It is recommended that the accuracy and representativeness of N2O emission flux data be enhanced by continuous dynamic measurement using the instrument. © 2018 Science Press. All rights reserved. 相似文献
992.
氧化锌(ZnO)纳米粒子已被发现具有生物毒性,氧化应激被认为是最重要的因素之一。前期实验证实,ZnO纳米粒子能显著减少锰超氧化物歧化酶(Mn SOD)蛋白的表达,降低Mn SOD活性。本文通过检测乳酸脱氢酶(LDH)释放、线粒体活性氧(ROS)水平和膜电位(Δφm)、延迟整流钾电流变化和Na~+/K~+-ATP酶的表达及活性等变化,检测ZnO纳米粒子对小鼠光感受器细胞的细胞毒作用。结果表明,ZnO纳米粒子可显著增强小鼠光感受器细胞中LDH的释放、增加线粒体内ROS水平并下调Δφm、阻断延迟整流钾电流,同时降低Na~+/K~+-ATP酶的表达及活性,从而对小鼠视网膜光感受器细胞产生细胞毒作用,提示ZnO纳米粒子可通过线粒体通路引起氧化应激,从而抑制小鼠光感受器细胞Na~+/K~+-ATP酶表达和活性,产生细胞毒性,导致细胞死亡。本文的研究结果有助于理解ZnO纳米粒子引起细胞毒性的作用机理。 相似文献
993.
Shanshan Ding Wen Huang Shaogui Yang Danjun Mao Julong Yuan Yuxuan Dai Jijie Kong Cheng Sun Huan He Shiyin Li Limin Zhang 《Frontiers of Environmental Science & Engineering》2018,12(1):5
The novel microwave catalyst MgFe2O4-SiC was synthesized via sol-gel method, to remove azo dye Direct Black BN (DB BN) through adsorption and microwave-induced catalytic reaction. Microwave-induced catalytic degradation of DB BN, including adsorption behavior and its influencing factors of DB BN on MgFe2O4-SiC were investigated. According to the obtained results, it indicated that the pseudo-second-order kinetics model was suitable for the adsorption of DB BN onto MgFe2O4-SiC. Besides, the consequence of adsorption isotherm depicted that the adsorption of DB BN was in accordance with the Langmuir isotherm, which verified that the singer layer adsorption of MgFe2O4-SiC was dominant than the multi-layer one. The excellent adsorption capacities of MgFe2O4-SiC were kept in the range of initial pH from 3 to 7. In addition, it could be concluded that the degradation rate of DB BN decreased over ten percent after the adsorption equilibrium had been attained, and the results from the result of comparative experiments manifested that the adsorption process was not conducive to the process of microwave-induced catalytic degradation. The degradation intermediates and products of DB BN were identified and determined by GC-MS and LC-MS. Furthermore, combined with the catalytic mechanism of MgFe2O4-SiC, the proposed degradation pathways of DB BN were the involution of microwave-induced $OH and holes in this catalytic system the breakage of azo bond, hydroxyl substitution, hydroxyl addition, nitration reaction, deamination reaction, desorbate reaction, dehydroxy group and ring-opening reaction.
相似文献
994.
焦化行业产生的环境污染问题一直倍受关注,尤其是在中国唐山等焦化企业聚集地.为探讨唐山地区焦化厂周围地表水中多环芳烃(Polycyclic Aromatic Hydrocarbons,PAHs)的污染特征并对其进行风险评价,选取该地区某典型焦化厂,通过对其周围水样的采集与检测,解析了该焦化厂周边地表水中PAHs的组成特征、生态风险商值及(非)致癌风险指数,并对模型参数进行了敏感性分析.结果显示,区域内地表水体中∑16PAHs平均含量为0.757 μg·L-1,以低分子量蒽(Anthracene,Ant)和高分子量荧蒽(Fluoranthene,Flt)为主,其中,Ant为距离焦化厂较远水体的特征污染物,而焦化厂内部及外围水体则以Flt为特征污染物.生态风险评价表明,∑PAHs在研究区大部分地表水中存在较高生态风险.健康风险评价表明,整体上女性承受的(非)致癌风险高于男性;皮肤暴露产生了一定的(非)致癌风险,且其非致癌风险指数呈现出随年龄增加而上升的趋势.敏感性分析显示,体重、暴露频率、每日饮用水摄入量等参数在模型中对各个暴露途径均有较高影响,需要在风险评价中加强关注.该研究有利于推动对焦化场地地表水PAHs污染的治理与防控,也为进一步探索焦化场地PAHs污染和迁移特征提供了理论基础. 相似文献
995.
为探讨硅肥对农田土壤Cd污染的修复效果,在田间试验条件下,研究了不同硅肥处理对Cd轻度污染农田水稻的修复效果。结果表明:不同硅肥处理可以降低Cd轻度污染农田中水稻糙米Cd含量,降幅为2.02%~16.00%,提高土壤pH值0.36~0.45,降低土壤有效态Cd含量,降幅为34.88%~45.47%,水稻产量增加3.63%~6.23%,基施与叶面喷施联合施用硅肥对农田土壤Cd污染的修复效果最好。 相似文献
996.
拒马河是北京周边具有独特生物多样性的河流,目前面临很多水生态环境问题.鱼类生物完整性指数(F-IBI)是评价河流生态健康的重要方法.本研究于2018年5月和10月,在拒马河北京段设置9个采样点,利用地笼和刺网进行调查,共获得鱼类样本2001尾,隶属于4目9科.根据采样情况,初步设置了5大类21个初选指标,经过对指标完整性、相关性和取值范围分析,筛选得出6个评价指标:鱼类总物种数(M1)、鲤科占总种数的百分比(M3)、中上层鱼种类数百分比(M9)、杂食性鱼类种类数百分比(M13)、产粘性卵鱼类种类数百分比(M19)和鱼类总个体数(M20),构建了适用于拒马河的F-IBI指标体系,运用该体系对拒马河北京段的河流健康状况进行了评价,并将F-IBI与几个主要水环境参数和拦河坝相关数据进行了相关性分析.研究结果表明,拒马河北京段河流健康整体处于较差水平,F-IBI与水质理化因子无显著相关性,与参数"采样点与上游最近拦河坝的距离"呈显著相关.结果表明,拒马河北京段河流健康指数的关键影响因素不是水质理化因子,可能与拦河坝导致的河流片段化有关. 相似文献
997.
Yue Hu Ding Dong Kun Wan Chao Chen Xin Yu Huirong Lin 《Frontiers of Environmental Science & Engineering》2021,15(2):28
998.
网状Ti/TiO2电极光电催化氧化若丹明B 总被引:5,自引:0,他引:5
用阳极氧化法制备出一种网状Ti/TiO2电极,扫描电镜和拉曼光谱对电极表面TiO2膜的形貌和晶体结构的检测结果表明:膜的结构和性能受阳极氧化过程中氧化速率的影响,在控制实验条件下,锐钛型TiO2是其主要结晶形态.若丹明B的光电催化降解和光催化降解的实验结果表明:外加偏压可以有效地提高有机物的光催化降解效率.TOC的测定结果显示,在光电催化氧化过程中,若丹明B几乎完全矿化.若丹明B在光电催化降解过程中,生色基团的破坏与脱乙基作用同时发生. 相似文献
999.
1000.
Zhuo Xiaocun Huang Haiyan Lan Fang He Chen Pan Qiong Zhang Yahe Shi Quan 《Environmental Chemistry Letters》2019,17(2):1117-1123
Environmental Chemistry Letters - Advanced oxidation processes have been extensively used in industrial wastewater treatment. However, the molecular transformation of dissolved organic... 相似文献