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Nowadays,widespread researches have been focused on the development of effective photocatalysts to remove pollutants of the aquatic system.In accordance with the universal studies,two new sets of UiO-66@metal oxide(including ZnO and TiO_2)/graphene oxide heterojunctions were synthesized for photodegradation of aromatic(tetracycline)and nonaromatic(malathion) pollutants which are challenging cases in the environment.The dosage of the photocatalyst,pH of the solution,the type of metal oxide,and the presence of various scavengers are assayed parameters in this work.In the optimum condition,maximum photodegradation efficiency is achieved in 90 min for tetracycline(81%) and malathion(100%) by the UiO-66@ZnO/graphene oxide.The superior separation of charge carriers by Z-scheme mechanism,excellent electron mobility on layers of graphene oxide and high surface area are factors that enhanced the efficiency.Furthermore,in comparison with pure UiO-66,the band gaps belong to heterojunctions revealed a red shift in the absorption edge,which can be responsible for more expand adsorption of the solar spectrum.Total organic carbon analysis verified the decontamination of these pollutants in the solution.The produced main intermediates during the photocatalytic process were identified and the possible degradation pathway proposed.In general,the superior photocatalytic activity suggests that these designed photocatalysts can be a promising choice for having a clean future. 相似文献
124.
Abu Jahid Md. Kamrul Hasan Monju Md. Sanwar Hossain Md. Farhad Hossain 《International Journal of Green Energy》2019,16(1):12-33
Increasing deployment of cellular networks across the globe is pushing the energy consumption in cellular networks at an exceptional rate. The integration of renewable energy (RE) harvesting technology into future mobile networks has the potential to positively cope with environmental contamination and ensure self-energy sustainability as a means to decrease fossil fuel consumption. Diesel generator (DG) in conjunction with on-site RE harvester has emerged as an economic and extent efficient option where commercial grid supply is not viable. This paper is focused on the cost aware energy management framework addressing to least net present cost (NPC) for the envisioned hybrid powered green cellular base stations (BSs) considering tempo-spatial traffic dynamics. In such wireless networks, solar photovoltaic modules are considered as a primary energy source, while the DG and energy storage device are kept as the standby supply in case of inadequate solar energy to ensure zero outage. A comprehensive simulation-based investigation is carried out in the context of downlink Long-Term Evolution (LTE) cellular networks for evaluating cost-efficiency and reliability performance under a wide range of network settings. Particularly, this paper examines the energy yield, greenhouse gas emissions, and cost analysis based on the optimal architecture of Remote Radio Head-enabled LTE BS. Moreover, wireless network performance in terms of throughput, energy efficiency gain, and radio efficiency is thoroughly investigated using Monte Carlo simulations. Numerical results demonstrate a substantial reduction of carbon footprints with minimum NPC while satisfying the quality of service requirements. 相似文献
125.
Hanan A. Al-Ashaal Maha A. Fahmy Farouk R. Melek Nagwa H. Aly Zenab M. Hasan 《毒物与环境化学》2013,95(5):965-986
Aim of this study is to evaluate the protective role of Glycine max L. (soybean) against aluminum sulfate-induced genotoxicity. A diet containing 30% soybean and extracts obtained with various organic solvents were administered orally to male white Swiss mice prior to intraperitoneal injection of Al2(SO4)3. Light microscopy was used for the examination of genotoxicity involving somatic cells, germ cells, and sperms. The main secondary metabolites contained in each extract were isolated and identified by chromatographic and spectral analyses. Administration of soy diet and extracts to the examined mice induced significant anti-mutagenic activity against bone marrow aberrations and spermatocyte and sperm abnormalities. At the end of this study, maximum protection was achieved using the methanolic extract (83% and 79%) followed by those obtained with chloroform (71% and 49%) and n-hexane (51% and 39%) for bone marrow aberrations and spermatocyte abnormalities, respectively. The observed activity of soybean extracts might be related to the main constituents isolated and identified. These main constituents were the isoflavone glycosides genistin and daidzin in addition to saponins (methanol extract), lignan matairesinol (chloroform extract), and β-sitosterol, unsaturated fatty acids as well as phospholipids (n-hexane extract). The results illustrated that soy extracts can be considered as alternative anti-mutagenic nutraceuticals and promising source for developing anti-mutagenic drugs. 相似文献
126.
In this study, the effects of environmental hypercapnia on hemato-immunological parameters and the activities of respiratory enzymes such as carbonic anhydrase (CA) and Na+, K+-ATPase were investigated in rainbow trout (Oncorhynchus mykiss) tissues (gill, liver and kidney). Batches of 12 fish were exposed to 4.5 mg L?1 (control) and 14 mg L?1 CO2. No mortalities occurred during the 14 days of the experimental period. Red blood cell (RBC), hemoglobin (Hb), and hematocrit (Ht) levels, and innate immune parameters such as nitro blue tetrazolium (NBT), lysozyme, and myeloperoxidase activities, and the melano-macrophage frequency were negatively affected by elevated CO2 levels. Patterns of change in CA activity differed among the gill, liver, and kidney. Compared with the activities of CA in the control group, the CA enzyme was significantly stimulated at day 7 in the gill tissue, whereas it was stimulated at day 14 of the experiment in the liver tissue of fish exposed to 14 mg L?1 CO2 (P < 0.05). In contrast to the pattern of CA enzyme activities, the Na+, K+-ATPase enzymes were stimulated significantly in the liver after day 7 but inhibited in the kidney and gill (P < 0.05). These results suggest that a subchronic exposure to hypercapnia of rainbow trout tissues may lead to adaptive changes in the respiratory enzymes and negatively affects hemato-immunological parameters. 相似文献
127.
Zinc borate is used as flame retardant for plastics and cellulose fibers, paper, rubber, and textiles. Despite its wide industrial use, there is limited information concerning its toxicity. The aim of the present study was to investigate the concentration dependence (0–280 mg L?1) of its genotoxic activity on cultured human lymphocytes by using sister chromatid exchange and chromosomal aberration assays. Total antioxidant capacity and the extent of oxidative stress were also determined. Zinc borate was found to be non-genotoxic at all tested concentrations. It exhibited antioxidant activity at concentrations lower than 40 mg L?1, and total oxidative stress levels were not changed at any applied concentration of zinc borate. 相似文献
128.
Farha Masood Fariha Hasan Safia Ahmed P. Chen Abdul Hameed 《Journal of Polymers and the Environment》2012,20(3):865-871
The biodegradable and biocompatible copolymer poly-(3-hydroxybutyrate-co-5 mol% 3-hydroxyvalerate), poly-(3HB-co-5 mol% 3HV), was synthesized by Bacillus cereus S10 and the highest yield was determined as 69.91 % at pH 7 and 30 °C after 48 h of incubation using a glucose as the sole carbon source. Poly-(3HB-co-5 mol% 3HV) was purified from bacterial biomass using chloroform. FTIR analysis showed absorption bands at 1,723, 1,274, 1,373, 1,453, 2,932 cm?1 corresponding to C=O, C–O stretching, CH3, –CH2 and –CH groups, respectively. 1H-NMR and 13C-NMR analysis confirmed that the copolymer was composed of 95 mol% of 3-hydroxybutrate and 5 mol% of 3-HV monomeric units. Poly-(3-HB-co-5 mol% 3HV) was used for nanoparticles preparation. The diameter of nanoparticles was 202 nm. 相似文献
129.
Islam Muhammad Saiful Hasan Md. Rashed Islam Zahidul 《Environmental science and pollution research international》2023,30(8):19994-20005
Environmental Science and Pollution Research - Microplastics (MPs), together with microfibers, have emerged as a contaminant of concern all around the globe. MPs have been detected in freshwater,... 相似文献
130.
Jindal Bharat Bhushan Alomayri Thamer Hasan Assaedi Kaze Cyriaque Rodrigue 《Environmental science and pollution research international》2023,30(10):25299-25324
Environmental Science and Pollution Research - In the last three decades, the gigantic demand for sustainable and environmentally friendly concrete with reduced environmental footprints has... 相似文献