Experimental flammability limits and associated theoretical flame temperatures as a tool for predicting the temperature dependence of these limits

The utility and limitations of adiabatic flame temperature calculations and minimum mixture energies in predicting the temperature dependence of flammability limits are explored. The limiting flame temperatures at constant pressure (1 bar) are calculated using a standard widely-used thermodynamic computer program. The computation is based on the calculated limiting flame temperature value at the reference initial temperature and the experimental limit concentration. The values recently determined in large chambers for the lower and upper flammability limits of a variety of simple organic and inorganic gases (methane, ethylene, dimethy lether, and carbon monoxide) are used as the basis for the predictions of the limiting flame temperature concept. Such thermodynamic calculations are compared with more traditional ones based on a limiting mixture energy and a constant average heat capacity of the reactant mixture. The advantages and limitations of the methods are discussed in this paper.     

Airborne fine particulate matter (PM2.5) at industrial,high- and low-density residential sites in a Nigerian megacity

Abstract

Airborne particulate matter PM_2.5 was collected in an industrial, a low-density, and a high-density residential area of Lagos from December 2010 to November 2011, and elemental composition was determined by proton-induced X-ray emission. Across the months, mass concentrations ranged from 13 to 237?µg?m^?3, exceeding the World Health Organization guideline value of 10?µg?m^?3. Data on 24 elements were obtained, with maximum values during Harmattan season months; source identification and apportionment studies by positive matrix factorization suggested that petroleum oil combustion (70%) was the major source of PM_2.5 and could pose a great hazard to Lagos receptors.     

Analysis of Cd,Cu, Pb,Zn, Hg and Mn in kidneys and liver from human cadavers – A case study in South Western Nigeria

In this study, autopsy tissue samples from human liver and kidneys were analysed for Cd, Cu, Pb, Zn, Hg and Mn in 25 subjects (16 males and 9 females) ranging in age from 2 to 70 years. Tissue samples that were pathologically normal were obtained at postmortem and concentrations of metals were determined. In both kidneys and liver, the concentrations of metals followed the order Cd > Hg > Pb > Zn > Mn > Cu irrespective of gender and age group, except in female kidneys where the order was Cd > Pb > Hg > Zn > Mn > Cu. Generally, males had higher concentrations of metals in both the kidneys and liver. Significant correlations of the metals were found in kidney and liver tissues.     

An analysis of the environmental health impact of the Barekese Dam in Kumasi, Ghana

Although dams have beneficial effects, they are also acknowledged as having serious environmental repercussions if they are not properly managed. The objective of this work was to examine the impact of the Barekese Dam in Ghana on the health status of three riparian communities downstream against a control. The environmental health status of the communities was analysed with reference to traditional endemic communicable water-related diseases in the catchment area, which were identified as malaria, urinary schistosomiasis, infectious hepatitis, diarrhoeal diseases and scabies. Case-control study was then conducted in the three phases of the dam (pre-construction, at the end of the construction and in the late operational phases) to analyse the health status of the communities as a function of the phases of the dam. The results showed that the control community consistently had a much better health status than two of the riparian communities, which were closer to the dam in all the three phases. However, it had a better health status than the third riparian community, which was farthest downstream, only in the first two phases. This community maintained a fairly constant health status retrospectively and did not appear to have been affected by the presence of the dam. On contrary, the health status of the two communities in close proximity to the dam deteriorated in the late operational phase. The study therefore showed that there was a strong association between the presence of the dam and poorer health status of the downstream communities in close proximity to it.     

A SCREENING MODEL FOR WATER RESOURCES PLANNING1

ABSTRACT: Techniques of optimization and simulation are merged to select the most efficient arrangement of components for regional water resources development and management. Application is made to the Elkhorn River Basin in Nebraska. The Basin extends over 7,000 square miles and includes 184 proposed reservoirs. Structure sizes, locations and operating policies are selected for optimal plans based on economic efficiency and regional development. Results indicate that substantial savings in time and costs over conventional planning techniques are effected. Agreement between model output and agency design values was noted.     

Does insurance sector development improve environmental quality? Evidence from BRICS

Environmental Science and Pollution Research - The effect of financial development measured by banks, bonds, and stocks on carbon dioxide emissions (CO2E) has been widely studied while not much is...     

Kolaviron suppresses dysfunctional reproductive axis associated with multi-walled carbon nanotubes exposure in male rats

Reproductive toxicity associated with excessive exposure to multi-walled carbon nanotubes (MWCNTs), which are commonly used in medicine as valuable drug delivery systems, is well documented. Kolaviron, a bioflavonoid isolated from Garcinia kola seeds, elicits numerous health beneficial effects related to its anti-inflammatory, anti-genotoxic activities, anti-apoptotic, and antioxidant properties. However, information on the role of kolaviron in MWCNTs-induced reproductive toxicity is not available in the literature. Herein, we assessed the protective effects of kolaviron on MWCNTs-induced dysfunctional reproductive axis in rats following exposure to MWCNTs (1 mg/kg) and concurrent treatment with kolaviron (50 or 100 mg/kg body weight) for 15 successive days. Results showed that MWCNTs-induced dysfunctional reproductive axis as evidenced by deficits in pituitary and testicular hormones, marker enzymes of testicular function, and sperm functional characteristics were abrogated in rats co-administered with kolaviron. Moreover, co-administration of kolaviron-abated MWCNTs-induced inhibition of antioxidant enzyme activities increases in oxidative stress and inflammatory indices. This is evidenced by diminished levels of tumor necrosis factor-alpha, nitric oxide, lipid peroxidation, reactive oxygen, and nitrogen species as well as reduced activity of myeloperoxidase in testes, epididymis, and hypothalamus of the rats. Biochemical data on the chemoprotection of MWCNTs-induced reproductive toxicity were corroborated by histological findings. Taken together, kolaviron suppressed dysfunctional reproductive axis associated with MWCNTs exposure via abrogation of oxidative stress and inflammation in male rats.

     

Reuse of walnut shell waste in the development of fired ceramic bricks

Environmental Science and Pollution Research - The development of agricultural waste–doped fired bricks is an important step toward achieving lightweight eco-efficient bricks with improved...     

Anaerobic ammonia-oxidizing bacteria in tropical bioaugmented zero water exchange aquaculture ponds

Environmental Science and Pollution Research - Bioaugmented zero water exchange aquaculture production systems (ZWEAPS) maintained with minimal or no water exchange prevent the ammonia accumulation...