Explosion temperatures and pressures of metals and other elemental dust clouds

The Pittsburgh Research Laboratory of the National Institute for Occupational Safety and Health (NIOSH) conducted a study of the explosibility of various metals and other elemental dusts, with a focus on the experimental explosion temperatures. The data are useful for understanding the basics of dust cloud combustion, as well as for evaluating explosion hazards in the minerals and metals processing industries. The dusts studied included boron, carbon, magnesium, aluminum, silicon, sulfur, titanium, chromium, iron, nickel, copper, zinc, niobium, molybdenum, tin, hafnium, tantalum, tungsten, and lead. The dusts were chosen to cover a wide range of physical properties—from the more volatile materials such as magnesium, aluminum, sulfur, and zinc to the highly “refractory” elements such as carbon, niobium, molybdenum, tantalum, and tungsten. These flammability studies were conducted in a 20-L chamber, using strong pyrotechnic ignitors. A unique multiwavelength infrared pyrometer was used to measure the temperatures. For the elemental dusts studied, all ignited and burned as air-dispersed dust clouds except for nickel, copper, molybdenum, and lead. The measured maximum explosion temperatures ranged from 1550 K for tin and tungsten powders to 2800 K for aluminum, magnesium, and titanium powders. The measured temperatures are compared to the calculated, adiabatic flame temperatures.     

Application of the DPSIR framework to environmental degradation assessment in northern Ghana

In many communities in northern Ghana, the environment has been altered by complex natural and human driven forces with significant impact on the lives of their inhabitants. The need to formulate an improved, holistic and consistent methodological approach to assess the problem is critical for sustainable natural resource management. This paper examines the potential of the DPSIR environmental assessment framework utilizing GIS‐based participatory methodology in the assessment of environmental degradation in northern Ghana. Community truthing tools such as key informant interviews, focus group discussions, participant observation and participatory Geographical Information Systems (GIS) were employed as a means of soliciting societal responses integrated to conventional GIS spatial analysis to measure the indicators of the Driving force–Pressure–State–Impacts–Response (DPSIR) assessment framework. Post classification GIS imagery results show a marked natural vegetation decrease of 634 km2 (42%) of the study area with a corresponding increase of 600 km² (39%) of grasses and built‐up and barren environment in the period of 14 years from 1990 to 2004. This is attributed to extreme climatic conditions and human driven causes such as poverty, population growth, migration and land tenure system. Poverty reduction strategies, amendment of the Mining and Mineral Law (PNDC law 153), improvement of the existing land tenure system and the control of migrants and Fulani herdsmen from neighbouring Burkina Faso were some of the solutions selected by the research participants, to be emphasized in the National Environmental Action Plan (EPA Act 490). This paper concludes that the DPSIR environmental assessment framework is an effective means of organizing complex environmental information to facilitate policy decision making.     

Tubular electrostatic precipitators of two-stage design

Although the “two stage” electrostatic precipitator concept was first developed in 1910, until recently most of their use was confined to in-plant air cleaning. In the last decade, plate type designs have been modified to make them suitable for industrial applications involving organic emissions, most notably in asphalt saturating, plastic curing, food processing, printing, textile finishing, and heat treating industries. However, plate type designs are inadequate in applications where very high loading and/or high particulate content are involved.Tubular design with wider spacing and higher voltages incorporates the best features of both the single stage and two stage type precipitators. These units have been used in molybdenum roasting, zirconium calcining, ammonia scrubbing of oxides of sulfur, meat broiling, foundry exhaust, etc.The paper discusses design parameters, field test data, and operating data on these units. Comparisons with single-stage type precipitators are made wherever applicable. Advantages and disadvantages of two stage precipitators are also discussed.     

Hazardous air pollutants from mobile sources in the Metropolitan Area of Mexico City

Environmental agencies are currently in the process of implementing a new air management program, which includes the improvement of fuel quality. In this work, exhaust emissions data and estimated relative risk for various fuels testing in-use vehicles, equipped with three different exhaust emission control technologies, are presented. Aromatics, sulfur, and olefins contents; type of oxygenated compound; and Reid vapor pressure were varied. The aim also includes calculating the ozone (O3) forming potential and a relative cancer risk of emissions from current and formulated gasoline blends in Mexico. The proposed gasoline decreases carbon monoxide, total hydrocarbons (THC), and nitrogen oxides emissions by 18 and 14%, respectively, when compared with gasoline sold in the rest of the country and within ozone nonattainment metropolitan areas in Mexico, respectively.     

Disclosure of stigmatized identities at work: An interdisciplinary review and agenda for future research

This review focuses on the disclosure decisions faced by employees with concealable stigmatized identities—one of the most challenging decisions these individuals must make on a day-to-day basis. Indeed, multiple theoretical frameworks have provided a foundation for understanding the antecedents and outcomes associated with the decision to disclose or not to disclose a stigmatized identity. What is less clear, however, is the extent to which these frameworks have been empirically supported. This systematic review serves to unify the extant literature and prompt continued research related to employees with concealable stigmatized identities. Specifically, we draw upon multiple fields of study, including applied psychology, management, social psychology, and occupational health as a means to systematically synthesize the existing empirical research related to disclosure of stigmatized identities at work. In addition to advancing the scholarly knowledge of disclosure, this review also provides practical utility to organizations as they continue to create work environments that foster inclusion of all stigmatized and nonstigmatized employees.     

The unusual suspects? Perception of underlying causes of anthropogenic climate change in coastal communities in Cambodia and Tanzania

Public perception of the underlying causes of anthropogenic climate change is a complex and subjective issue that is critical to effective risk communication. This issue is important to scientists and policymakers because of the role of individual perceptions in influencing their protective behaviour towards risk (e.g., the adoption of climate risk reduction and mitigation strategies). This cross-sectional study elucidated people's perceptions of the underlying causes of human-induced climate change in coastal communities in Cambodia and Tanzania. The multinomial logistic regression model was based on a geographically and demographically stratified national sample of 3,706 individuals conducted between March and September 2013. The distribution of the fundamental causes of anthropogenic climate change in the pooled sample was deforestation (29%), overpopulation – births and immigration (18%), greenhouse gas emissions (12%), illegal resource extraction (14%), and God's will and transgressing cultural norms (26%). Few people in both countries believed that, the usual suspect, greenhouse gas emission was the fundamental cause of anthropogenic climate change. The number of poor rural residents who indicated that deforestation was the major underlying cause of climate change was approximately three times more than members of the same sub-group who noted that greenhouse gas emissions were the underlying cause of climate change. People who had tertiary education were less likely to consider God's will and transgressing cultural norms as the underlying cause of anthropogenic climate change rather than attributing it to greenhouse gas emissions. Therefore, it is imperative to mainstream climate change into educational curricula in both countries.     

An Evaluation of the LPG Vehicles Program in the Metropolitan Area of Mexico City

ABSTRACT

The environmental agency in the metropolitan area of Mexico City has launched a program to introduce more energy-efficient modes of transport, one of which is the use of alternative and less polluting fuels. With that perspective in mind, a liquefied petroleum gas (LPG) fleet of vehicles is exempt of the mandatory "one day without a car" program if the emission of pollutants is below the standard authorized for that specific purpose. Today, about 28,000 light-duty vehicles and heavy-duty trucks circulate in the area, most of them as aftermarket converted vehicles. In this work, we evaluated regulated exhaust emission and other parameters on 134 representative vehicles of that fleet. From the data obtained, an estimate of emission factors and their contribution to the global emission in the metropolitan area is provided. It is concluded that more than 95% of the in-use vehicles using LPG presented regulated emissions which exceeded in one or more the environmental regulations values required for certification. The poor maintenance of the vehicles and the type of conversion kit installed could be the culprits of the results obtained.     

Assessing the spatial distribution of nitrogen dioxide in London,Ontario

Land use regression (LUR) models have been widely used to characterize the spatial distribution of urban air pollution and estimate exposure in epidemiologic studies. However, spatial patterns of air pollution vary greatly between cities due to local source type and distribution. London, Ontario, Canada, is a medium-sized city with relatively few and isolated industrial point sources, which allowed the study to focus on the contribution of different transportation sectors to urban air pollution. This study used LUR models to estimate the spatial distribution of nitrogen dioxide (NO₂) and to identify local sources influencing NO₂ concentrations in London, ON. Passive air sampling was conducted at 50 locations throughout London over a 2-week period in May–June 2010. NO₂ concentrations at the monitored locations ranged from 2.8 to 8.9 ppb, with a median of 5.2 ppb. Industrial land use, dwelling density, distance to highway, traffic density, and length of railways were significant predictors of NO₂ concentrations in the final LUR model, which explained 78% of NO₂ variability in London. Traffic and dwelling density explained most of the variation in NO₂ concentrations, which is consistent with LUR models developed in other Canadian cities. We also observed the importance of local characteristics. Specifically, 17% of the variation was explained by distance to highways, which included the impacts of heavily traveled corridors transecting the southern periphery of the city. Two large railway yards and railway lines throughout central areas of the city explained 9% of NO₂ variability. These results confirm the importance of traditional LUR variables and highlight the importance of including a broader array of local sources in LUR modeling. Finally, future analyses will use the model developed in this study to investigate the association between ambient air pollution and cardiovascular disease outcomes, including plaque burden, cholesterol, and hypertension.

Implications: Monitoring and modeling of NO₂ throughout the city of London represents an important step toward assessing air pollution health effects in a mid-sized Canadian city. The study supports the introduction of railways to LUR modeling of NO₂. Railways explained approximately 9% of the variability in ambient NO₂ concentrations in London, which suggests that local sources captured by land-use indicators may contribute to the efficacy of LUR models. These findings provide insights relevant to other medium and smaller sized cities with similar land use and transportation infrastructure. Furthermore, London is a central hub for medical research and treatment in southwestern Ontario, with facilities such as the Robarts Research Institute, London Regional Cancer Program (LRCP), and Stroke Prevention & Atherosclerosis Research Centre (SPARC). The models developed in this study will provide estimates of exposure for future analyses examining air pollution health effects in this data-rich population.     

Photocatalytic ozonation of terephthalic acid: a by-product-oriented decomposition study

Terephthalic acid (TA) is considered as a refractory model compound. For this reason, the TA degradation usually requires a prolonged reaction time to achieve mineralization. In this study, vanadium oxide (V_xO_y) supported on titanium oxide (TiO₂) served as a photocatalyst in the ozonation of the TA with light-emitting diodes (LEDs), having a bandwidth centered at 452 nm. The modified catalyst (V_xO_y/TiO₂) in combination with ozone and LEDs improved the TA degradation and its by-products. The results obtained by this system were compared with photolysis, single ozonation, catalytic ozonation, and photocatalytic ozonation of V_xO_y/TiO₂ with UV lamp. The LED-based photocatalytic ozonation showed almost the same decomposition efficiency of the TA, but it was better in comparison with the use of UV lamp. The oxalic acid accumulation, as the final product of the TA decomposition, was directly influenced by either the presence of V_xO_y or/and the LED irradiation. Several by-products formed during the TA degradation, such as muconic, fumaric, and oxalic acids, were identified. Besides, two unidentified by-products were completely removed during the observed time (60 min). It was proposed that the TA elimination in the presence of V_xO_y/TiO₂ as catalyst was carried out by the combination of different mechanisms: molecular ozone reaction, indirect mechanism conducted by ·OH, and the surface complex formation.