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91.
Adeline Jondeau-Cabaton Amélie Soucasse Emilien L. Jamin Nicolas Creusot Marina Grimaldi Isabelle Jouanin Sélim Aït-Aïssa Patrick Balaguer Laurent Debrauwer Daniel Zalko 《Environmental science and pollution research international》2013,20(5):2705-2720
Complex mixtures of contaminants with potential adverse effects on human health and wildlife are found in the environment and in the food chain. These mixtures include numerous anthropogenic compounds of various origins and structures, which may behave as endocrine disruptors. Mixture’s complexity is further enhanced by biotic and abiotic transformations. It is therefore necessary to develop new strategies allowing the identification of the structure of known, as well as unknown, nuclear receptor (NR) ligands present in complex matrices. We explored the possibility to use NR-based affinity columns to characterize the presence of bioactive molecules in environmental complex mixtures. Estrogen receptor α (ERα)-based affinity columns were used to trap and purify estrogenic substances present in surface sediment samples collected in a French river under mixed anthropogenic pressure. We combined biological, biochemical and analytical approaches to characterize the structure of ligands retained on columns and demonstrate the presence of known active molecules such as bisphenol A and octylphenol, but also of unexpected ERα ligands (n-butylparaben, hydroxyl-methyl-benzofuranone). High resolution mass spectrometry results demonstrate that ERα affinity columns can be used for the isolation, purification and identification of known as well as unknown estrogenic contaminants present in complex matrices. 相似文献
92.
Claude Daou Marise Salloum Bernard Legube Amine Kassouf Naïm Ouaini 《Environmental monitoring and assessment》2018,190(8):485
In this work, four major Lebanese rivers were investigated, the Damour, Ibrahim, Kadisha, and Orontes, which are located in South, Central, and North Lebanon and Bekaa Valley, respectively. Five sampling sites were considered from upstream to downstream, and 12 sampling campaigns over four seasons were conducted during 2010–2011. Thirty-seven physicochemical parameters and five microbial tests were evaluated. A principal component analysis (PCA) was used for data evaluation. The first PCA, applied to the matrix-containing data that was acquired on all four rivers, showed that each river was distinct in terms of trophic state and pollution sources. The Ibrahim River was more likely to be polluted with industrial and human discharges, while the Kadisha River was severely polluted with anthropogenic human wastes. The Orontes and Damour rivers seemed to have the lowest rates of water pollution, especially the Orontes, which had the best water quality. PCA was also performed on individual data matrices for each river. In all cases, the results showed that the springs of each river have good water quality and are free from severe contamination. The other monitoring sites on each river were likely exposed to human activities and showed important spatial evolution. Through this work, a spatiotemporal fingerprint was obtained for each studied river, defining a “water mass reference” for each one. This model could be used as a monitoring tool for subsequent water quality surveys to highlight any temporal evolution of water quality. 相似文献
93.
Jeanne Amiel Nadine Gigarel Alexandra Benacki Paule Benit Isabelle Valnot Béatrice Parfait Jurgen-Christoph Von Kleist-Retzow Valérie Raclin Smaïl Hadj-Rabia Yves Dumez Pierre Rustin Jean-Paul Bonnefont Arnold Munnich Agnès Rötig 《黑龙江环境通报》2001,21(7):602-604
Respiratory chain deficiency (RCD) is responsible for a clinically heterogeneous group of early-onset untreatable disorders. Enzymological prenatal diagnosis (PD) can only be offered to a fraction of families. Moreover, due to the two-fold genetic origin of the respiratory chain (nuclear and mitochondrial DNA) and owing to the large number of nuclear genes involved in the respiratory chain assembly, maintenance and functioning, the identification of the disease causing gene in a given family remains challenging. Here, we report on PD of RCD by direct screening of NDUFV1, SDH-Fp, SCO1 and SURF1 mutations in five unrelated families with complex I, II and IV deficiency, respectively. The identification of the disease-causing gene in a given family with RCD is a major issue to provide both adequate genetic counselling and early, reliable PD. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献
94.
de Bonis L Peigné S Likius A Mackaye HT Vignaud P Brunet M 《Die Naturwissenschaften》2007,94(7):575-580
We report on the oldest fox (Canidae) ever found in Africa. It is dated to 7 Ma based on the degree of evolution of the whole
fauna. It belongs to a new species. Its overall size and some morphological characteristics distinguish the Chadian specimen
from all the other foxes. The presence of Vulpes and of the genus Eucyon in slightly younger African locality, as well as in southwestern Europe in the late Miocene, may indicate that canids migrated
in Europe from Africa through a trans-Mediterranean route. 相似文献
95.
Jean R. Gnepe Satinder K. Brar José R. Valéro Rao Y. Surampalli 《Journal of environmental science and health. Part. B》2013,48(11):889-896
Biopesticides are usually sprayed on forests by using planes made up of aluminum alloy. Bioval derived from starch industry wastewater (SIW) in suspension form was developed as stable anticorrosive biopesticide formulation. In this context, various anticorrosion agents such as activated charcoal, glycerin, ethylene glycol, phytic acid, castor oil and potassium silicate were tested as anticorrosive agents. There was no corrosion found in Bioval formulation where potassium silicate (0.5% w/v) was added and compared with Foray 76 B, as an industrial standard, when stored over 6 months. In relation to other parameters, the anticorrosion formulation of Bioval+buffer+KSi reported excellent zeta potential (?33.19 ± 4 mV) and the viscosity (319.13 ± 32 mPa.s) proving it's stability over 6 months, compared to the standard biopesticide Foray 76 B (?36.62 ± 4 mV potential zeta, pH 4.14 ± 0.1 and 206 ± 21 mPa.s viscosity). Metal analysis of the different biopesticides showed that Bioval+buffer+KSi has no corrosion (5.11 ± 0.5 mg kg?1 of Al and 13.53 ± 1.5 mg kg?1 of Fe) on the aluminum alloy due to the contribution of sodium acetate buffer at pH 5. The bioassays reported excellent results for Bioval+Buffer+KSi (2.95 ± 0.3 × 109 CFU mL?1 spores and 26.6 ± 2.7 × 109 IU L?1 Tx) compared with initial Bioval (2.46 ± 0.3 × 109 CFU mL?1 spores and 23.09 ± 3 × 109 IU L?1 Tx) and Foray 76 B (2.3 ± 0.2 × 109 CFU mL?1 spores and 19.950 ± 2.1 UI L?1 Tx) which was due to the break-up of the external chitinous membrane due to abrasive action of potassium silicate after ingestion by insects. The contribution of sodium acetate buffer and potassium silicate (0.5% and at pH = 5) as anticorrosion agent in the Bioval allowed production of an efficient biopesticide with a reduced viscosity and favorable pH as compared to Foray 76 B which enhanced the entomotoxic potential against spruce budworm (SB) larvae (Lepidoptera: Choristoneura fumiferana). 相似文献
96.
97.
Anne Pinton Julia Boubnova François Becmeur Pierre Kuhn Marie-Victoire Senat Julien Stirnemann Marianne Capelle Jonathan Rosenblatt Jérôme Massardier Pascal Vaast Gwenaelle Le Bouar Amélie Desrumaux Laure Connant Laetitia Begue Benoit Parmentier Franck Perrotin Alain Diguet Guillaume Benoist Charles Muszynski Aurélien Scalabre Norbert Winer Jean-Luc Michel Florence Casagrandre-Magne Jean-Marie Jouannic Denis Gallot Perrine Coste Mazeau Emmanuel Sapin Alexis Maatouk Anne-Hélène Saliou Loïc Sentilhes Florence Biquard Nicolas Mottet Romain Favre Alexandra Benachi Nicolas Sananès 《黑龙江环境通报》2020,40(8):949-957
98.
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100.
The spatial and temporal dynamics in the stream water NO(3)-N concentrations in a major European river-system, the Garonne (62,700 km(2)), are described and related to variations in climate, land management, and effluent point-sources using multivariate statistics. Building on this, the Hydrologiska Byr?ns Vattenbalansavdelning (HBV) rainfall-runoff model and the Integrated Catchment Model of Nitrogen (INCA-N) are applied to simulate the observed flow and N dynamics. This is done to help us to understand which factors and processes control the flow and N dynamics in different climate zones and to assess the relative inputs from diffuse and point sources across the catchment. This is the first application of the linked HBV and INCA-N models to a major European river system commensurate with the largest basins to be managed under the Water Framework Directive. The simulations suggest that in the lowlands, seasonal patterns in the stream water NO(3)-N concentrations emerge and are dominated by diffuse agricultural inputs, with an estimated 75% of the river load in the lowlands derived from arable farming. The results confirm earlier European catchment studies. Namely, current semi-distributed catchment-scale dynamic models, which integrate variations in land cover, climate, and a simple representation of the terrestrial and in-stream N cycle, are able to simulate seasonal NO(3)-N patterns at large spatial (>300 km(2)) and temporal (> or = monthly) scales using available national datasets. 相似文献