Effects of burnings of wax apple stubble and rice straw on polychlorinated dibenzo-p-dioxin and dibenzofuran concentrations in air and soil

Measurements of the concentrations of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) were made in ambient air, ash, and soil impacted by the open burning of wax apple and rice straw residues. Measurements showed that the mean PCDD/F concentration (0.458 pg I-TEQ/Nm3; international toxicity equivalence) in air at two wax apple orchards during open burning increased markedly, -8.1 times higher than that (0.057 pg I-TEQ/Nm3); before open burning. In addition, the mean PCDD/F concentration (0.409 pg I-TEQ/Nm3) in ambient air at a rice straw field was 4.6 times higher than that (0.089 pg I-TEQ/Nm3) before open burning. After burning the residues of wax apple stubble and rice straw, the contents of PCDD/F in ashes were 1.393 and 1.568 ng I-TEQ/kg-ash, respectively, and the contents of PCDD/F in soil were 2.258 and 2.890 ng I-TEQ/kg-soil, respectively. Therefore, the turnover of soil with the ash after open burning over years will result in the accumulation of PCDD/Fs in farm soils.     

Assessment model for equipment risk management: Petrochemical industry cases

This study presents an assessment model that examines quantity and quality factors for equipment risk management in the petrochemical industry. The proposed model has five dimensions—financial performance, logistical support, service level, learning and innovation, and risk control. This evaluation model uses 13 strategy subjects and 78 performance-measurement indicators. Performance assessment indicators are initially established and revised based on expert opinions collected via a questionnaire. Further, the analytical network process (ANP) is utilized to calculate the weights of indicators in each layer and to construct assessment models with applicable and valuable references. To determine model practicability, this study assesses four subsidiaries of the case company. Each subsidiary has a capitalization exceeding TWD 50 billion. In addition to evaluating company performance in terms of each dimension and indicator, the proposed model provides a valuable reference for decision-making in equipment risk management.     

Free tropospheric ozone production after deep convection of dispersing tropical urban plumes

Ozone generation is computed in a one-dimensional photochemistry code following convective redistribution of tropical urban effluent into the free troposphere. Simulations are run at several stages of pollutant dilution by surrounding surface air. A threshold boundary layer NO_x concentration of 300 pptv is established for significant production enhancements at upper levels. Areas defined by the 300 pptv level are examined in the Gaussian dispersion framework based on a wet season plume event observed in Amazonia. Pollution travels slowly in the sluggish winds of the equatorial trough. Daily storms are likely to interrupt the effluent while coverages are still on the order of few thousand square kilometers and NO_x concentrations are above the threshold. Dry season plume sizes are difficult to assess because local concentration data are scarce, but it is conceivable that the faster trade winds lead to a several fold extension.     

Shortest service location model for planning waste pickup locations

A municipal solid waste (MSW) and recycled material curbside pickup bus system was recently initiated in a Taiwan city to improve collection service. For such an MSW pickup system, selecting appropriate collection stops critically affects hauling costs and service efficiency. Conventionally, MSW collection points are heuristically and manually chosen, resulting in a hauling system that is not as effective as intended in terms of location suitability and the number of collection points. The Shortest Service Location (SSL) model, which minimizes the sum of service distances, was therefore proposed in this study. The SSL model was compared with two other models for a local MSW pickup system problem. Using georeferenced graphs generated by a geographical information system (GIS) and related programs, the performance of the three models was compared according to walking distance to a service stop, the coverage of a service stop, and the number of service stops. The results show that the SSL solution can shorten walking distances by approximately 10% and reduce the overlap of service areas covered.     

AN ECONOMIC EVALUATION OF TWO WATERSHED MANAGEMENT PRACTICES IN TAIWAN1

ABSTRACT: The main purpose of this study is to evaluate the management practice effects on Ming-Hu and Ming-Tan reservoir watersheds during the past 15 years. It is difficult to economically evaluate a watershed project consisting of a number of multisectoral and long term management practices and regulations. However, the reservoirs’ hydropower operations and their associated benefits and costs are highlighted in this study. The estimated management practice value (net present value) of 351 million NT (New Taiwan) dollars and a benefit-cost ratio of 1.189 are obtained for the Ming-Hu subwatershed. Because the Ming-Tan hydropower station only began commercial operation in 1992 the estimated management practice value is negative 103 million NT dollars (net present value) and the benefit-cost ratio is 0.653 in the Ming-Tan subwatershed. If the analysis period is contained to the year 2010, the benefit-cost ratio of Ming-Tan reservoir subwatershed becomes 1.103. Ming-Hu and Ming-Tan subwatersheds together share the benefit-cost ratio of 1.182 and the net present value of 1,589 million NT dollars. The results of the analyses indicate that the Taiwan Power Company, the watershed management agency, has implemented economically efficient watershed practices and regulations in Ming-Hu and Ming-Tan reservoir watersheds and the watershed management practices are worthwhile and should be sustained.     

AQUIFER SALINIZATION IN THE YUN‐LIN COASTAL AREA,TAIWAN1

ABSTRACT: This study analyzes possible causes of shallow ground water salinization in the coastal area of Yun‐Lin. The local hydro‐geologic setting is determined from geological drilling data and sea floor topography. Three possible causes (sea water intrusion, salt water percolation through wells, and infiltration of salty water from fish ponds) are evaluated. Chloride concentration is used as an index to measure ground water salinization. Sea water intrusion is modeled by the advective/dispersive equation, and salt water infiltration from wells and fish ponds is calculated by estimating the amount of water percolated. The determined local hydrogeologic setting suggests that the shallow aquifer may be connected to the sea water, resulting in salt water intrusion as a large amount of shallow ground water is withdrawn. The percent contributions of sea water intrusion, percolation through wells, and infiltration of water from fish ponds, to the salinization of the shallow aquifer at Ko‐Hu in the Yun‐Lin coastal area are approximately 27 percent, less than 1 percent and 73 percent, respectively. The results suggest that the vertical infiltration of salt water from fish ponds is the major cause of shallow ground water salinization in the coastal area of Yun‐Lin.     

Assessing and simulating the major pathway and hydrogeochemical transport of arsenic in the Beitou–Guandu area,Taiwan

This study involved assessing and simulating the probable major pathways (surface and subsurface flow) and hydrogeochemical transport of arsenic (As) in the Beitou–Guandu area, Taiwan. A one-dimensional (1-D) generic, reactive, chemical transport model (PHREEQC) was adopted. The calibrated model showed that As transported to the downstream Guandu plain and Tan Shui river mouth accounted for 50.7 and approximately 100 % of the As in the subsurface flow pathway, respectively, suggesting that subsurface flow constituted a major As pathway. The highest As water concentration occurred near the Beitou geothermal valley because of the low pH and high redox potential in both the surface and subsurface pathways. However, As may be scavenged by aqueous Fe(II) in a reducing environment. The As concentrations in the downstream Guandu plain and Guandu wetland decreased as the simulated time increased, resulting in the adsorption of As on the surface of Fe oxydroxides and limiting the mobility of As in the surface flow pathway. The major retardation mechanism of As mobility in the subsurface flow pathway of the Guandu plain and Guandu wetland was governed by the adsorption reactions of iron-oxide and iron-sulfide minerals. The 1-D transport model was applied to predict the evolution of As in the subsurface flow pathway from 2013 to 2020. The results indicated that the As concentrations in all cells gradually increased. The geochemical redox reactions of As in the subsurface pathway subsequently led to the oxidization of As-bearing sulfides, causing As concentrations to rise substantially in the hillside area.

     

L-谷氨酸改性氧化石墨烯对Cu2+的吸附

采用L-谷氨酸（L-Glu）改性氧化石墨烯（GO）制备吸附剂L-Glu/GO,并进行了XRD、FTIR和SEM表征。考察了不同因素对L-Glu/GO吸附Cu²⁺的影响,并对L-Glu/GO的吸附-解吸能力进行了研究。实验结果表明：L-Glu/GO对Cu²⁺的吸附在10 min内就可达到吸附平衡;在Cu²⁺初始质量浓度为70 mg/L、初始pH为5、L-Glu/GO投加量为0.200 g/L、吸附时间为120 min、吸附温度为30 ℃的条件下,L-Glu/GO的最大吸附量可达292.460 mg/g。准二级动力学和Langmuir模型能很好地拟合此吸附过程,且显示该吸附过程可促进L-Glu/GO对Cu²⁺的吸附。热力学研究结果表明该吸附过程是一个自发的放热过程。经过5次吸附-解吸循环后,L-Glu/GO对Cu²⁺的吸附率仍在92%以上,表明该吸附剂再生性好,可重复使用。