张家口地区土壤硒形态分布及其植物有效性初步研究

分别采集了张家口克山病区非病村4个砂土样品和重病村6个草甸土、褐土样品．用连续提取程序分离出水溶态硒、离子交换态硒、有机态硒、酸溶态硒、硫化物态硒和残余态硒。水溶态硒容易被植物吸收。交换态硒也能被植物吸收，但受到吸附环境和pH值的影响。有机结合态硒只有在碱性条件下其中的富啡酸态硒才能被植物吸收。酸溶态硒是铁锰氧化物和碳酸盐类矿物醚性淋溶作用的结果，酸性条件下硒容易流失，碱性条件下硒被原矿物固定，因此都难被植物吸收利用。硫化物态硒和残余态硒是最难溶的，基本上不被植物吸收。张家口地区重病村土《铁锰氧化物和腐殖质含量高，呈中-微酸性，而非病村正好与之相反。因此，重病村土壤虽然水溶性硒+交换态盾+有机态硒高于非病村，但这三种硒形态所反映的土壤植物有效性反而低于非病村。这可能是病村粮食比非病村低硒的原因。     

Environmental auditing at the crossroads: The environmental auditing roundtable's response to ISO 14000

The Environmental Auditing Roundtable (EAR) is the single largest professional organization in the world, representing over 900 members. Built on a tradition of promoting environmental auditing through openly sharing experiences in the field of safety, health, and environmental auditing, the organization in recent years has significantly expanded its influence on auditing practices both nationally and internationally by monitoring audit activities and participating in the development of audit policy, regulation, standardization, and the certification of environmental auditors. This article describes the origin and evolution of the organization from meeting the needs of the membership to addressing the needs of external national and international stakeholders.     

ESTIMATING DRAINAGE AREA ON STEEP UNIFORM SLOPES1

ABSTRACT: A study was conducted to derive a simple procedure for estimating the tributary drainage area that may potentially develop at the base of a uniformly graded, steep slope. Data were extracted from a nil development flume study in which 112 rills and their tributary drainage areas were documented. The tributary drainage area for each rill was correlated to the slope length and the slope gradient. The findings are considered applicable to planar, convex, and divergent slopes with lengths of up to 130 m. Field verification is needed to extend the applicability of the relation.     

MONITORING OPERATIONS PERFORMANCE IN LARGE-SCALE PUBLIC IRRIGATION SYSTEMS IN INDONESIA1

ABSTRACT: Different allocation and delivery performance ratios are used to assess operations performance in a large scale public irrigation system in Indonesia. Results from this analysis indicate that field management practices deviate substantially from the official operating procedures. The lack of application of a single, standardized procedure for planning water allocations represents a serious constraint to effective monitoring and evaluating system performance. Underestimated and unrealistic planned allocations becomes the justification for overdiversion of water, and has the effect of undermining the resolve of managers to see to it that actual flows meet planned flows. Miscalculating planned allocations, poor matches between planned flows and actual deliveries, overdiversion and misreporting have economic consequences as well. For example, strict adherence to the standard operating rule during the second dry season of 1987 would have resulted in 19,070,000 m³ less water diverted into the irrigation system from the Brantas River or, at a conservative estimate of $1.78 per 100 m³ water, a savings of $339,500. Scope exists for making improvements in management by closer adherence to the standard delivery rule, which will also facilitate proper monitoring and evaluation.     

On-site remediation of PCB contamination using transportable incineration systems

Many Superfund or hazardous waste sites prove to be excellent candidates for remediation using transportable incineration. Transportable incineration has been selected as the alternative of choice to remediate numerous sites throughout the United States. There are a number of firms that provide mobile and transportable incineration equipment and services. A variety of treatment systems are available, including rotary kilns, fluidized beds, and infrared incinerators. Roy F. Weston, Inc., has been instrumental in the development, design, permitting, construction, performance testing, and operation of hazardous and toxic waste thermal treatment systems. Weston owns and operates two high-temperature transportable incineration systems (TISs). The first system is Weston's seven-ton-per-hour (tph) TIS-5. The second is the TIS-20, with a design capacity of up to 30 tph. These units are typical rotary kiln incinerators, the most flexible, adaptable type of incineration unit. This article discusses Weston's use of these incinerators to remediate soils at sites contaminated with polychlorinated biphenyls (PCBs).     

A COMPARISON OF TWO METHODS FOR MULTIOBJECTIVE OPTIMIZATION FOR RESERVOIR OPERATION1

ABSTRACT: Two major objectives in operating the multireservoir system of the Upper Colorado River basin are maximization of hydroelectric power production and maximization of the reliability of annual water supply. These two objectives conflict. Optimal operation of the reservoir system to achieve both is unattainable. This paper seeks the best compromise solution for an aggregated reservoir as a surrogate of the multireservoir system by using two methods: the constraint method and the method of combined stochastic and deterministic modeling. Both methods are used to derive the stationary optimal operating policy for the aggregated reservoir by using stochastic dynamic programming but with different objective functions and minimum monthly release constraints. The resulting operating policies are then used in simulated operation of the reservoir with historical inflow records to evaluate their relative effectiveness. The results show that the policy obtained from the combination method would yield more hydropower production and higher reliability of annual water supply than that from the constraint-method policy.     

DEFINING REGIONAL POPULATIONS OF LAKES FOR THE ASSESSMENT OF SURFACE WATER QUALITY1

ABSTRACT: Topographic maps are commonly used to define populations of lakes in regional surveys of surface water quality. To illustrate the effect of different maps on that process, we compared the lakes represented on the 1:250,000-scale maps used for the Northeast Region of the Eastern Lake Survey—Phase I (ELS-I) to the lakes on a sample of large-scale maps (1:24,000 or 1:62,500). Lake areas at or near the lower limit of representation delimited “smallest-lake” values for the compared 1:250,000-scale maps. The regional median for these values was 4.5 hectares (ha) and ranged from 0.6 to 24.8 ha. Lake representation is influenced by cartographic limitations such as map scale, age, and complexity as well as the inherent variability of waterbodies (e.g., water level fluctuations or the creation of reservoirs, beaver impoundments, and oxbows). The total number of lakes on large-scale maps increased markedly as lake area decreased. Approximately 15,700 of the estimated 29,000 lakes in the EPA's Northeast Region were 1 to 4 ha in area. Because maps affect the size distribution of lakes included in a regional survey and because lake areas are thought to modify lake chemistry, maps ultimately affect the estimates of regional surface water quality.     

Accumulation of 14C-trinitrotoluene and related nonextractable (bound) residues in Eisenia fetida

To determine if trinitrotoluene (TNT) forms nonextractable residues in earthworms and to measure the relative degree of accumulation as compared to TNT and its deaminated metabolites, Eisenia fetida was exposed to ¹⁴C-TNT using dermal contact to filter paper or exposure to soil. Nonextractable residues made up 32-68% of total body burden depending on exposure media and depuration time. Parent TNT accounted for less than 3% of radioactivity, while ADNTs accounted for 7-38%. Elimination half-lives were 61-120 h for TNT, ADNTs, and DANTs, which was significantly lower than the half-lives found for nonextractable residues, 201-240 h. However, over 80% of the nonextractable residue was solubilized using weak acid (pH 2). Based on our findings that TNT accumulation occurs primarily as nonextractable residues, which have a longer half-life, and that nonextractable residues can be solubilized, we propose that nonextractable residues could be used as a selective biomarker for assessing TNT contamination.     

Evaporative mass transfer behavior of a complex immiscible liquid

A series of laboratory experiments was conducted with a multiple-component immiscible liquid, collected from the Picillo Farm Superfund Site in Rhode Island, to examine liquid-vapor mass-transfer behavior. The immiscible liquid, which comprises solvents, oils, pesticides, PCBs, paint sludges, explosives, and other compounds, was characterized using gas chromatography and gas chromatography/mass spectrometry to determine mole fractions of selected constituents. Batch experiments were conducted to evaluate equilibrium phase-partitioning behavior. Two sets of air-stripping column studies were conducted to examine the mass-transfer dynamics of five selected target compounds present in the immiscible-liquid mixture. One set of column experiments was designed to represent a system with free-phase immiscible liquid present; the other was designed to represent a system with a residual phase of immiscible liquid. Initial elution behavior of all target components generally appeared to be ideal for both systems, as the initial vapor-phase concentrations were similar to vapor-phase concentrations measured for the batch experiment and those estimated using Raoult's law (incorporating the immiscible-liquid composition data). Later-stage removal of 1,2-dichlorobenzene appeared to be rate limited for the columns containing free-phase immiscible liquid and no porous medium. Conversely, evaporative mass transfer appeared to be ideal throughout the experiment conducted with immiscible liquid distributed relatively uniformly as a residual phase within a sandy porous medium.     

An Urban Diffusion Simulation Model For Carbon Monoxide

A relatively simple Gaussian-type diffusion simulation model for calculating urban carbon monoxide (CO) concentrations as a function of local meteorology and the distribution of traffic is described. The model can be used in two ways: (1) in the synoptic mode, in which hourly concentrations at one or many receptor points are calculated from historical or forecast traffic and meteorological data; and (2) in the climatological mode, in which concentration frequency distributions are calculated on the basis of long-term sequences of input data. For model evaluation purposes, an extensive field study involving meteorological and air-quality measurements was conducted during November-December 1970 in San Jose, Calif., which has an automated network to provide traffic data throughout the central business district. Model refinements made on the basis of the data from this experimental program include the addition of a street-canyon submodel to compensate for the important aerodynamic effects of buildings on CO concentrations at streetside receptors. The magnitude of these effects was underscored by the concentrations measured on opposite sides of the street in San Jose, which frequently differed by a factor of two or more. Evaluation of the revised model has shown that calculated and observed concentration frequency distributions for street-canyon sites are in good agreement. Hour-average predictions are well correlated with observations (correlation coefficient of about 0.6 to 0.7), and about 80 percent of the calculated values are within 3 ppm of the observed hour-average concentrations, which ranged as high as 16 ppm.