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101.
In the Recôncavo of Bahia (located between 12°33′ and 13°10′S and 38°00′and 39°00′W), there are significant discharges of SO2 and NOx due to local, industrial and urban activities. The incoming air masses from the Atlantic Ocean are enriched with seaspray, which neutralizes part of the rain acidity. The extent of seaspray neutralization of rain acidity was quantified in four sites of the region, each with different loads of seaspray. Rain samples were obtained daily at the same time, integrating the precipitation of the previous 24 h, using wet-only collectors and analyzed for pH by potentiometry and for sodium by flame photometry. The amount of rain acidity in Recôncavo neutralized by seaspray ranged from <1% up to 88% and depended on the site. On average, neutralization ranged from 5% to 18%. 相似文献
102.
Ferreira Leide Lene C. Abreu Marina P. Costa Camila B. Leda Paulo O. Behrens Maria Dutra dos Santos Elisabete Pereira 《Food and environmental virology》2022,14(2):120-137
Food and Environmental Virology - The use of natural resources for the prevention and treatment of diseases considered fatal to humanity has evolved. Several medicinal plants have nutritional and... 相似文献
103.
T.G. Soares Neto J.A. Carvalho C.A.G. Veras E.C. Alvarado R. Gielow E.N. Lincoln T.J. Christian R.J. Yokelson J.C. Santos 《Atmospheric environment (Oxford, England : 1994)》2009,43(2):438-446
Biomass consumption and CO2, CO and hydrocarbon gas emissions in an Amazonian forest clearing fire are presented and discussed. The experiment was conducted in the arc of deforestation, near the city of Alta Floresta, state of Mato Grosso, Brazil. The average carbon content of dry biomass was 48% and the estimated average moisture content of fresh biomass was 42% on wet weight basis. The fresh biomass and the amount of carbon on the ground before burning were estimated as 528 t ha?1 and 147 t ha?1, respectively. The overall biomass consumption for the experiment was estimated as 23.9%. A series of experiment in the same region resulted in average efficiency of 40% for areas of same size and 50% for larger areas. The lower efficiency obtained in the burn reported here occurred possibly due to rain before the experiment. Excess mixing ratios were measured for CO2, CO, CH4, C2–C3 aliphatic hydrocarbons, and PM2.5. Excess mixing ratios of CH4 and C2–C3 hydrocarbons were linearly correlated with those of CO. The average emission factors of CO2, CO, CH4, NMHC, and PM2.5 were 1,599, 111.3, 9.2, 5.6, and 4.8 g kg?1 of burned dry biomass, respectively. One hectare of burned forest released about 117,000 kg of CO2, 8100 kg of CO, 675 kg of CH4, 407 kg of NMHC and 354 kg of PM2.5. 相似文献
104.
Paula Paíga Lúcia H. M. L. M. Santos Célia G. Amorim Alberto N. Araújo M. Conceição B. S. M. Montenegro Angelina Pena Cristina Delerue-Matos 《Environmental science and pollution research international》2013,20(4):2410-2420
Ibuprofen is amongst the most worldwide consumed pharmaceuticals. The present work presents the first data in the occurrence of ibuprofen in Portuguese surface waters, focusing in the north area of the country, which is one of the most densely populated areas of Portugal. Analysis of ibuprofen is based on pre-concentration of the analyte with solid phase extraction and subsequent determination with liquid chromatography coupled to fluorescence detection. A total of 42 water samples, including surface waters, landfill leachates, Wastewater Treatment Plant (WWTP), and hospital effluents, were analyzed in order to evaluate the occurrence of ibuprofen in the north of Portugal. In general, the highest concentrations were found in the river mouths and in the estuarine zone. The maximum concentrations found were 48,720 ng?L?1 in the landfill leachate, 3,868 ng?L?1 in hospital effluent, 616 ng?L?1 in WWTP effluent, and 723 ng?L?1 in surface waters (Lima river). Environmental risk assessment was evaluated and at the measured concentrations only landfill leachates reveal potential ecotoxicological risk for aquatic organisms. Owing to a high consumption rate of ibuprofen among Portuguese population, as prescribed and non-prescribed medicine, the importance of hospitals, WWTPs, and landfills as sources of entrance of pharmaceuticals in the environment was pointed out. Landfill leachates showed the highest contribution for ibuprofen mass loading into surface waters. On the basis of our findings, more studies are needed as an attempt to assess more vulnerable areas. 相似文献
105.
106.
Nali C Francini A Lorenzini G 《Environmental pollution (Barking, Essex : 1987)》2009,157(5):1421-1426
Data collected at one site in central Italy using the NC-S/NC-R clover (Trifolium repens) biotype system during 1997-2007 were analysed in order to assess: (a) its performance under Mediterranean conditions; (b) variations of ozone damage linked with meteorological conditions; (c) if critical level approach is a good predictor of ozone risk on vegetation. NC-S dry biomasses were systematically lower than those of NC-R, the mean ratio being 0.7. Relevant relationship between ozone visible injury and cumulated values of AOT40 were also reported. Temperature and number of rainy days were the most important factors associated with ozone presence and, as a consequence, with leaf injury index. Photosynthetic gas exchange properties indicate that NC-S has higher values of stomatal conductance. 相似文献
107.
José Tomás Albergaria Maria da Conceição M. Alvim-Ferraz Maria Cristina F. Delerue-Matos 《Environmental monitoring and assessment》2010,171(1-4):171-180
The objectives of this work were: (1) to identify an isotherm model to relate the contaminant contents in the gas phase with those in the solid and non-aqueous liquid phases; (2) to develop a methodology for the estimation of the contaminant distribution in the different phases of the soil; and (3) to evaluate the influence of soil water content on the contaminant distribution in soil. For sandy soils with negligible contents of clay and natural organic matter, contaminated with benzene, toluene, ethylbenzene, xylene, trichloroethylene (TCE), and perchloroethylene (PCE), it was concluded that: (1) Freundlich’s model showed to be adequate to relate the contaminant contents in the gas phase with those in the solid and non-aqueous liquid phases; (2) the distribution of the contaminants in the different phases present in the soil could be estimated with differences lower than 10% for 83% of the cases; and (3) an increase of the soil water content led to a decrease of the amount of contaminant in the solid and non-aqueous liquid phases, increasing the amount in the other phases. 相似文献
108.
T. Neuparth R. Capela L. Rey-Salgueiro S.M. Moreira M.M. Santos M.A. Reis-Henriques 《Chemosphere》2013
Despite the extensive maritime transportation of Hazardous and Noxious Substances (HNS), there is a current lack of knowledge on the effects posed by HNS spills on the marine biota. Among the HNS identified as priority, acrylonitrile was selected to conduct ecotoxicological assays. We assessed the acute and subletal effects of acrylonitrile in seabass, followed by a recovery phase to simulate the conditions of a spill incident. The work aimed at testing a broad range of biological responses induced by acrylonitrile. Sublethal exposure to the highest two doses increased the fish mortality rate (8.3% and 25% mortality in 0.75 and 2 mg L−1 acrylonitrile concentrations), whereas no mortality were observed in control and 0.15 mg L−1 treatments. Additionally, important alterations at sub-individual level were observed. Acrylonitrile significantly induced the activities of Catalase– CAT and Glutathione S-Transferase – GST; and the levels of DNA damage were significantly increased. Conversely, Superoxide Dismutase– SOD – activity was found to be significantly inhibited and no effects were found on Lipid Peroxidation– LPO and ethoxyresorufin O-deethylase – EROD – activity. Following a 7 d recovery period, the levels of CAT, GST and EROD fell to levels at or below those in the control. In the 2 mg L−1 group, SOD remained at the levels found during exposure phase. This study has gathered essential information on the acute and subletal toxicity of acrylonitrile to seabass. It also demonstrated that 7 d recovery allowed a return of most endpoints to background levels. These data will be useful to assist relevant bodies in preparedness and response to HNS spills. 相似文献
109.
Régia Maria Avancini Iandara Schettert Silva Ana Cristina Simões Rosa Paula de Novaes Sarcinelli Sueli Alexandra de Mesquita 《Chemosphere》2013,90(9):2408-2413
Organochlorines are highly hydrophobic, synthetic organic pollutants that accumulate in the environment and in food webs. The primary route of human exposure to organochlorines is through food-mainly fat-rich food of animal origin such as meat, fish, and dairy products. Here we determined the presence and concentration of organochlorine residues in pasteurized milk from Mato Grosso do Sul, Brazil, to monitor consumer exposure to these contaminants. Organochlorine pesticides in milk samples were analyzed using solid phase extraction in octadecyl silica-prepacked columns and identified by gas chromatography using an electron capture detector. Of the 100 composite samples analyzed, more than 90% contained residues of organochlorine pesticides: aldrin was present in 44% of the samples, followed by ∑DDT (36%), mirex (34%), endosulfan (32%), chlordane (17%), dicofol (14%), heptachlor (11%) and dieldrin (11%). Compared to the values established by law, the concentration of the compounds in some samples was above the reference values. Given the importance that milk and its products have in the human diet, it is essential to know whether the levels of pesticide residues are kept well below the recommended levels to minimize the risk to human health. 相似文献
110.
This study modeled the impact on freshwater ecosystems of pharmaceuticals detected in biosolids following application on agricultural soils. The detected sulfonamides and hydrochlorothiazide displayed comparatively moderate retention in solid matrices and, therefore, higher transfer fractions from biosolids to the freshwater compartment. However, the residence times of these pharmaceuticals in freshwater were estimated to be short due to abiotic degradation processes. The non-steroidal anti-inflammatory mefenamic acid had the highest environmental impact on aquatic ecosystems and warrants further investigation. The estimation of the solid-water partitioning coefficient was generally the most influential parameter of the probabilistic comparative impact assessment. These results and the modeling approach used in this study serve to prioritize pharmaceuticals in the research effort to assess the risks and the environmental impacts on aquatic biota of these emerging pollutants. 相似文献