Controlled release, blind test of DNAPL remediation by ethanol flushing

A dense nonaqueous phase liquid (DNAPL) source zone was established within a sheet-pile isolated cell through a controlled release of perchloroethylene (PCE) to evaluate DNAPL remediation by in-situ cosolvent flushing. Ethanol was used as the cosolvent, and the main remedial mechanism was enhanced dissolution based on the phase behavior of the water-ethanol-PCE system. Based on the knowledge of the actual PCE volume introduced into the cell, it was estimated that 83 L of PCE were present at the start of the test. Over a 40-day period, 64% of the PCE was removed by flushing the cell with an alcohol solution of approximately 70% ethanol and 30% water. High removal efficiencies at the end of the test indicated that more PCE could have been removed had it been possible to continue the demonstration. The ethanol solution extracted from the cell was recycled during the test using activated carbon and air stripping treatment. Both of these treatment processes were successful in removing PCE for recycling purposes, with minimal impact on the ethanol content in the treated fluids. Results from pre- and post-flushing partitioning tracer tests overestimated the treatment performance. However, both of these tracer tests missed significant amounts of the PCE present, likely due to inaccessibility of the PCE. The tracer results suggest that some PCE was inaccessible to the ethanol solution which led to the inefficient PCE removal rates observed. The flux-averaged aqueous PCE concentrations measured in the post-flushing tracer test were reduced by a factor of 3 to 4 in the extraction wells that showed the highest PCE removal compared to those concentrations in the pre-flushing tracer test.     

Distribution and fractionation of phosphorus, cadmium, nickel, and lead in calcareous soils amended with composts

Composts improve organic carbon content and nutrients of calcareous soils but the accumulation and distribution of phosphorus and heavy metals among various fractions in soil may vary under the south Florida conditions. The accumulation of P, Cd, Ni, and Pb with depth and the distribution of water soluble, exchangeable, carbonate, Fe-Mn oxides, organic and residual forms of each element were investigated in soils amended with municipal solid waste (MSW) compost, co-compost and biosolids compost and inorganic fertilizer (as control). Total concentrations of P, Cd, Ni, and Pb were higher in the 0-22 cm soil layers and decreased considerably in the rock layers. These elements were in the decreasing order of P > Pb > Ni > Cd. Amounts of water soluble and exchangeable forms of P, Cd, Ni and Pb were negligible at 0-22 cm soil depths except for Cd in the 10-22 cm depth. Amending calcareous soil with either organic or inorganic amendments rendered phosphorus, nickle and lead in the residual form followed by Fe-Mn oxides form in the 0-10 and 10-22 cm soil layers. Cadmium was predominantly in the Fe-Mn oxides fraction followed by the residual and carbonate forms in both soil layers. A significant positive correlation was found between various organic carbon fractions and organic forms of P, Cd and Pb in the surface soil layer. Soil amended with MSW compost had higher concentration of Cd in the organic fraction whereas, co-compost and MSW compost amended soil had higher concentrations of organic Ni fraction in the 0-10 cm soil layer.     

Removal of nickel (II) from aqueous solutions using marine macroalgae as the sorbing biomass

In the present study biosorption technique, the passive accumulation of metals by biomass, is used for the removal of nickel from aqueous medium. The brown algae, Sargassum sp., in its natural and acid treated forms are used as a low cost sorbent. The adsorption characteristics of nickel on Sargassum sp. are evaluated as a function of time, pH, adsorbent dosage and initial concentration of nickel. The equilibrium adsorption data are fitted to Freundlich and Langmuir adsorption isotherm models and the model parameters are evaluated. Both the models represent the experimental data satisfactorily. The adsorption follows Lagergren first order kinetic model. The monolayer adsorption capacities of natural and acid treated forms of algae as obtained from Langmuir adsorption model are found to be 181 and 250mg g(-1) respectively.     

Phosphorus fate and transport in soil columns loaded intermittently with influent of high phosphorus concentrations.

In this study, several columns of different lengths were filled with composite soils sampled from the field at corresponding depths and then loaded intermittently with influent of a high phosphorus concentration to evaluate phosphorus fate and transport in soil. The results indicate that the height of the mass transfer zone, solvent pore velocity, and soil's life expectancy for phosphorus removal increased with depth, while the retained phosphorus per kilogram of soil and the linear adsorption equilibrium coefficient, R, decreased with depth. An equation was developed to link liquid-phase phosphorus with solvent traveling time and soil depth. The results of X-ray diffraction and washout tests indicate that calcium-phosphorus precipitation and/or crystal growth occurred in the columns. The new protocol is useful for evaluation of phosphorus fate and transport in other subsurface systems, because it allows flexible adjustments in hydraulic loadings, feed solution, and sampling schemes.     

Response of lake sediments to changes in trace metal emission from the smelters at Sudbury, Ontario

Historical records preserved in sediments show that the lakes are extremely sensitive to metal emissions from the smelters in the Sudbury basin. From the observed quick response, a strong capacity for rapid recovery (deacidification) of acid-stressed lakes in the area is deduced. The study thus emphasises the need for curtailing the emissions of acidic and acidifying substances as a critical step in reducing lake acidification as well as in rehabilitating many of the afflicted lakes.     

Studies on water hyacinth as a biological filtre for treating contaminants from agricultural wastes and industrial effluents

The aquatic weed--water hyacinth [Eichhornia crassipes (Mart) Solms] showed a remarkable capacity to withstand the effects of pH changes ranging from 5 to 8 in the aquatic environment. Growth continued to be normal except when placed for longer periods in medium containing iron ions at pH 3.3. The ability of this plant to neutralize some very acid solutions of heavy metals such as salts of copper, cadmium and zinc individually and in combinations, is being reported. Plants placed in pure acid and alkali solutions were also able to neutralize the medium. Calcium appears to play an important role in the mechanism involved in the adaptability of these plants to such environments.     

Mercury induced alterations in the intestinal,absorption of nutrients in the fresh water murrel, Channapunctatus

The effect of five concentrations (10 mM, 1 mM, 0.1 mM, 0.01 mM and 0.001 mM) of mercury on the rate of absorption of glucose, fructose, glycine and tryptophan by the intestine of the fresh water murrel $\text{Channa}$$\text{punctatus}$ has been studied. Intestinal absorption of these nutrients was also examined in fish exposed to a sublethal concentration (3 μg/l) of mercury for 15 and 30 days. Significant decrease was recorded in the rate of intestinal absorption of all the four nutrients with higher concentrations (10 mM, 1 mM and 0.1 mM) of mercury. 0.01 mM and 0.001 mM of mercury also reduced the transport rate but it was insignificant, except in case of tryptophan, where 0.01 mM of mercury also produced significant decrease. Exposure of fish by bath to mercury also resulted in significant decrease in the intestinal transport rate of all the four nutrients after 30 days.     

Nanomaterials for environmental burden reduction, waste treatment, and nonpoint source pollution control: a review

Nanomaterials are applicable in the areas of reduction of environmental burden, reduction/treatment of industrial and agricultural wastes, and nonpoint source (NPS) pollution control. First, environmental burden reduction involves green process and engineering, emissions control, desulfurization/denitrification of nonrenewable energy sources, and improvement of agriculture and food systems. Second, reduction/treatment of industrial and agricultural wastes involves converting wastes into products, groundwater remediation, adsorption, delaying photocatalysis, and nanomembranes. Third, NPS pollution control involves controlling water pollution. Nanomaterials alter physical properties on a nanoscale due to their high specific surface area to volume ratio. They are used as catalysts, adsorbents, membranes, and additives to increase activity and capability due to their high specific surface areas and nano-sized effects. Thus, nanomaterials are more effective at treating environmental wastes because they reduce the amount of material needed.     

盐度对污水硝化过程中N_2O产量的影响

采用调节盐度(7.5 g/L)和未调节盐度(0.1 g/L)实际生活污水驯化的活性污泥,分别考察了其相应硝化过程中N2O的产量和转化率.结果表明,盐度7.5 g/L生活污水硝化过程中N2O产量是未调节盐度N2O产量的2.85倍.考察其他盐度下污水硝化过程中N2O产量与转化率的结果表明,盐度从7.5 g/L降低到5.0、2.5 g/L后,N2O产量变化不大,但系统比氨氧化速率随着盐度的下降有所增加;当盐度从7.5 g/L急剧增加到10 g/L后,硝化过程中N2O产量和转化率均有大幅升高,产量达到7.5 g/L时的2.2倍,比氨氧化速率大幅下降.因此处理含盐污水时,应尽量避免盐度的过高波动,防止污水硝化过程中N2O产量和转化率大幅地升高.