The availability of copper in soils historically amended with sewage sludge, manure, and compost

Metals in soils amended with sewage sludge are typically less available compared with those in soils spiked with soluble metal salts. However, it is unclear if this difference remains in the long term. A survey of copper (Cu) availability was made in soils amended with sewage sludge, manure, and compost, collectively named organic amendments. Paired sets of amended and control soils were collected from 22 field trials where the organic amendments had aged up to 112 yr. Amended soils had higher total Cu concentrations (range, 2-220 mg Cu kg; median, 15 mg Cu kg) and organic C (range, 1-16 g kg; median, 4 g kg) than control soils. All samples were freshly spiked with CuCl, and the toxicity of added Cu to barley was compared between amended and control soils. The toxicity of added Cu was significantly lower in amended soils than in control soil in 15 sets by, on average, a factor of 1.4, suggesting that aged amendments do not largely increase Cu binding sites. The fraction of added Cu that is isotopic exchangeable Cu (labile Cu) was compared between control soils freshly spiked with CuCl and amended soils with both soils at identical total Cu concentrations. Copper derived from amendments was significantly less labile (on average 5.9-fold) than freshly added Cu in 18 sets of soils. This study shows that Cu availability after long-term applications of organic amendments is lower than that of freshly added Cu salts, mainly because of its lower availability in the original matrix and ageing reactions than because of increased metal binding sites in soil.     

Domestic sampling: exposure assessment to moth repellent products using ultrasonic extraction and capillary GC-MS

Moth repellent agents are considered major contributors to indoor air pollution. In this study, the chemical contamination of clothes due to their direct or indirect exposure to moth repellent agents such as p-dichlorobenzene, naphthalene and camphor were investigated. Cotton cloths were used as clothing simulant. They were analyzed using ultrasonic extraction followed by GC-MS analysis. Extrapolated results indicate that a regular cotton shirt indirectly exposed to these chemicals in a storage cabinet can contain up to 7, 3 and 7.5mg of p-dichlorobenzene, naphthalene and camphor, respectively, even after one-hour of airing. Passive sorptive sampling using polydimethylsiloxane-coated stir-bars and ultrasonic extraction followed by GC-MS analysis was used to monitor the concentration distribution in a wardrobe.     

Digital technology and human development: A charter for nature conservation

The application of digital technology in conservation holds much potential for advancing the understanding of, and facilitating interaction with, the natural world. In other sectors, digital technology has long been used to engage communities and share information. Human development—which holds parallels with the nature conservation sector—has seen a proliferation of innovation in technological development. Throughout this Perspective, we consider what nature conservation can learn from the introduction of digital technology in human development. From this, we derive a charter to be used before and throughout project development, in order to help reduce replication and failure of digital innovation in nature conservation projects. We argue that the proposed charter will promote collaboration with the development of digital tools and ensure that nature conservation projects progress appropriately with the development of new digital technologies.     

Solving mercury (Hg) speciation in soil samples by synchrotron X-ray microspectroscopic techniques

Direct mercury (Hg) speciation was assessed for soil samples with a Hg concentration ranging from 7 up to 240 mg kg⁻¹. Hg chemical forms were identified and quantified by sequential extractions and bulk- and micro-analytical techniques exploiting synchrotron generated X-rays. In particular, microspectroscopic techniques such as μ-XRF, μ-XRD and μ-XANES were necessary to solve bulk Hg speciation, in both soil fractions <2 mm and <2 μm. The main Hg-species found in the soil samples were metacinnabar (β-HgS), cinnabar (α-HgS), corderoite (Hg₃S₂Cl₂), and an amorphous phase containing Hg bound to chlorine and sulfur. The amount of metacinnabar and amorphous phases increased in the fraction <2 μm. No interaction among Hg-species and soil components was observed. All the observed Hg-species originated from the slow weathering of an inert Hg-containing waste material (K106, U.S. EPA) dumped in the area several years ago, which is changing into a relatively more dangerous source of pollution.     

GARCH modelling in association with FFT–ARIMA to forecast ozone episodes

In operational forecasting of the surface O₃ by statistical modelling, it is customary to assume the O₃ time series to be generated through a homoskedastic process. In the present work, we’ve taken heteroskedasticity of the O₃ time series explicitly into account and have shown how it resulted in O₃ forecasts with improved forecast confidence intervals. Moreover, it also enabled us to make more accurate probability forecasts of ozone episodes in the urban areas. The study has been conducted on daily maximum O₃ time series for four urban sites of two major European cities, Brussels and London. The sites are: Brussels (Molenbeek) (B1), Brussels (PARL.EUROPE) (B2), London (Brent) (L1) and London (Bloomsbury) (L2). Fast Fourier Transform (FFT) has been used to model the periodicities (annual periodicity is especially distinct) exhibited by the time series. The residuals of “actual data subtracted with their corresponding FFT component” exhibited stationarity and have been modelled using ARIMA (Autoregressive Integrated Moving Average) process. The MAPEs (Mean absolute percentage errors) using FFT–ARIMA for one day ahead 100 out of sample forecasts, were obtained as follows: 20%, 17.8%, 19.7% and 23.6% at the sites B1, B2, L1 and L2. The residuals obtained through FFT–ARIMA have been modelled using GARCH (Generalized Autoregressive Conditional Heteroskedastic) process. The conditional standard deviations obtained using GARCH have been used to estimate the improved forecast confidence intervals and to make probability forecasts of ozone episodes. At the sites B1, B2, L1 and L2, 91.3%, 90%, 70.6% and 53.8% of the times probability forecasts of ozone episodes (for one day ahead 30 out of sample) have correctly been made using GARCH as against 82.6%, 80%, 58.8% and 38.4% without GARCH. The incorporation of GARCH also significantly reduced the no. of false alarms raised by the models.     

Air-quality modelling in the Lake Baikal region

In this paper, we assess the status of the air quality in the Lake Baikal region which is strongly influenced by the presence of anthropogenic pollution sources. We combined the local data, with global databases, remote sensing imagery and modelling tools. This approach allows to inventorise the air-polluting sources and to quantify the air-quality concentration levels in the Lake Baikal region to a reasonable level, despite the fact that local data are scarcely available. In the simulations, we focus on the month of July 2003, as for this period, validation data are available for a number of ground-based measurement stations within the Lake Baikal region.     

Assessment of the overall resource consumption of germanium wafer production for high concentration photovoltaics

The overall resource requirements for the production of germanium wafers for III–V multi-junction solar cells applied in concentrator photovoltaics have been assessed based on up to date process information. By employing the cumulative energy demand (CED) method and the cumulative exergy extraction from the natural environment (CEENE) method the following resources have been included in the assessment: fossil resources, nuclear resources, renewable resources, land resources, atmospheric resources, metal resources, mineral resources and water resources. The CED has been determined as 216 MJ and the CEENE has been determined as 258 MJ_ex. In addition partial energy and exergy payback times have been calculated for the base case, which entails the installation of the high concentration photovoltaics (HCPVs) in the Southwestern USA, resulting in payback times of around 4 days for the germanium wafer production. Due to applying concentration technology the germanium wafer accounts for only 3% of the overall resource consumption of an HCPV system. A scenario analysis on the electricity input to the wafer production and on the country of installation of the HCPV has been performed, showing the importance of these factors on the cumulative resource consumption of the wafer production and the partial payback times.     

Multi-generation toxicity of zinc, cadmium, copper and lead to the potworm Enchytraeus albidus

In standard chronic terrestrial toxicity tests with invertebrates, adult organisms are exposed to the contaminants and the number of offspring is quantified. These procedures do not allow the assessment of possible effects on all life stages of the organism, which may lead to an underestimation of the toxicity of the test substance. To evaluate the importance of this issue, the potworm Enchytraeus albidus was exposed to zinc, cadmium, copper and lead for two subsequent generations. Juvenile production was assessed for both generations. Considering the variability of metal toxicity data reported in the literature, it is concluded that the two generation assay did not markedly increase the sensitivity of the standard E. albidus test for the tested metals. Therefore, toxicity data obtained with the proposed test guideline with E. albidus are protective for all life stages.     

Historical processes constrain patterns in global diatom diversity

There is a long-standing belief that microbial organisms have unlimited dispersal capabilities, are therefore ubiquitous, and show weak or absent latitudinal diversity gradients. In contrast, using a global freshwater diatom data set, we show that latitudinal gradients in local and regional genus richness are present and highly asymmetric between both hemispheres. Patterns in regional richness are explained by the degree of isolation of lake districts, while the number of locally coexisting diatom genera is highly constrained by the size of the regional diatom pool, habitat availability, and the connectivity between habitats within lake districts. At regional to global scales, historical factors explain significantly more of the observed geographic patterns in genus richness than do contemporary environmental conditions. Together, these results stress the importance of dispersal and migration in structuring diatom communities at regional to global scales. Our results are consistent with predictions from the theory of island biogeography and metacommunity concepts and likely underlie the strong provinciality and endemism observed in the relatively isolated diatom floras in the Southern Hemisphere.