石化行业储瓘火灾安全对策研究

针对石化企业储罐消防面临的新形势、新问题,重点分析了中国石化及国内外开展的储罐火灾安全和消防灭火技术的研究工作,通过系统化开展储罐火灾事故研究、消防灭火技术、储罐防火技术等一系统的研究工作形成系统性的解决方案是石化行业储罐火灾与消防技术研究的重点.     

耐盐石油降解菌性能及降解条件优化

从冀东油田钻井废液中筛选分离出耐盐石油降解菌Virgibacillus sp.(简称SJ菌),其在高含盐条件下对石油具有较好的降解效果,高达56.12%左右。考察了pH值、盐度、不同N和P形态等因素对SJ菌降解石油效果的影响。结果表明:SJ菌有较宽的pH值适应范围(pH值为6～10)和较好的耐盐能力(0.5%～20%),在pH值为9及NaCl质量浓度为5%时对石油类降解效果最好,其最佳利用N源和P源分别为(NH2)2CO和KH2PO4,该研究为油田高含盐含油废液处理提供了一条新途径。     

不同富营养状态下沼蛤的存活与行为特性研究

通过设计不同富营养状态下沼蛤的行为特性的控制实验,探讨了不同富营养状态下沼蛤的生存、运动和粘附特性。研究结果为:(1)富营养状态最优(贫营养)水质不适宜沼蛤的粘附,但是适宜其生存,因此移动距离最短,运动能力最差。轻度富营养水质适宜沼蛤的生存。富营养状态最差(重度富营养)不适宜沼蛤的生存,因此移动距离最远,能生存下来的沼蛤运动能力最强。(2)在不同营养盐浓度下的重度富营养状态水质中,沼蛤适宜在营养盐浓度较低的水体中生存,营养盐浓度越高越不适宜沼蛤生存;营养盐浓度越高越不适宜沼蛤粘附,营养盐浓度相对而言较低的水体适宜沼蛤粘附。(3)在不同藻浓度下的重度富营养水质中,沼蛤适宜在藻浓度较低的水体中生存,藻浓度越高越不适宜沼蛤生存;藻浓度越高越不适宜沼蛤粘附,藻浓度相对而言较低的水体适宜沼蛤粘附;低藻浓度水体相对而言更适宜沼蛤生存,因此移动距离最短,运动能力最差,高藻浓度水体不适宜沼蛤生存,因此移动距离最远,能生存下来的沼蛤运动能力最强。富营养状态是影响沼蛤生长、粘附和运动的关键要素,轻度富营养化状态最适宜沼蛤生长和粘附。水体中营养盐浓度和浮游植物浓度也是影响沼蛤生长、粘附和运动的关键要素,重度富营养化状态中营养盐浓度和浮游植物浓度越低,越适宜适宜沼蛤生长和粘附。     

Diffusion of municipal wastewater treatment technologies in China: a collaboration network perspective

The diffusion of municipal wastewater treatment technology is vital for urban environment in developing countries. China has built more than 3000 municipal wastewater treatment plants in the past three decades, which is a good chance to understand how technologies diffused in reality.We used a data-driven approach to explore the relationship between the diffusion of wastewater treatment technologies and collaborations between organizations. A database of 3136 municipal wastewater treatment plants and 4634 collaborating organizations was built and transformed into networks for analysis. We have found that: 1) the diffusion networks are assortative, and the patterns of diffusion vary across technologies; while the collaboration networks are fragmented, and have an assortativity around zero since the 2000s. 2) Important projects in technology diffusion usually involve central organizations in collaboration networks, but organizations become more central in collaboration by doing circumstantial projects in diffusion. 3) The importance of projects in diffusion can be predicted with a Random Forest model at a good accuracy and precision level. Our findings provide a quantitative understanding of the technology diffusion processes, which could be used for waterrelevant policy-making and business decisions.

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聚乙烯/CaO复合材料在堆肥条件下的降解性能初探

以光钙型环境友好塑料——聚乙烯(PE)/CaO复合材料作为研究对象,通过自制的污泥堆肥与材料老化综合反应器,利用扫描电镜(SEM)与傅立叶红外光谱(FTIR)分析仪对比研究了其在高温好氧堆肥条件下的降解情况。结果表明,PE/CaO复合材料在受控高温好氧堆肥条件下,具有比纯PE材料更优的可堆肥性能。PE/CaO复合材料的CaO颗粒能吸收堆肥环境中的H2O和CO2而生成相应的产物Ca(OH)2或CaCO3,发生涨大与脱落,从而使复合材料的表面产生孔洞,而这些孔洞不仅增大了材料与环境的接触面积,同时更为降解细菌进入材料内部提供了通道,大大加速了材料的降解速度。     

A new strain for recovering precious metals from waste printed circuit boards

A new strain, Pseudomonas Chlororaphis (PC), was found for dissolving gold, silver, and copper from the metallic particles of crushed waste printed circuit boards (PCBs). The optimized conditions that greatly improved the ability of producing CN^? (for dissolving metals) were obtained. Dissolving experiments of pure gold, silver, and copper showed that the metals could be changed into Au⁺, Ag⁺, and Cu²⁺. PC cells and their secreta would adsorb metallic ions. Meanwhile, metallic ions destroyed the growth of PC. Dissolving experiments of metallic particles from crushed waste PCBs were performed by PC. The results indicated that 8.2% of the gold, 12.1% silver, and 52.3% copper were dissolved into solution. This paper contributed significance information to recovering precious metals from waste PCBs by bioleaching.     

SMBBR预处理发酵类制药废水

采用高活性反硝化菌DNF409作为菌种,以SDC-03型生物载体作为填料,通过特异性移动床生物膜反应器预处理发酵类制药废水。实验结果表明:在反应温度为22~26℃、DO为2~4 mg/L、污泥质量浓度为2 000 mg/L、水力停留时间为16 h的条件下,COD,NH3-N,TN,TP的平均去除率分别为72.45%,27.72%,18.54%,84.58%,BOD5/COD由0.17提高到0.38,废水的可生化性得到提高;出水经后续生化处理达到GB 21903—2008《发酵类制药工业水污染物排放标准》的排放要求。     

Effect of flue gas recirculation on nitric oxide (NO) emissions during the coal grate-fired process

Flue gas recirculation (FGR) is a low nitrogen oxide (NO_X) combustion technology. The present study used standard gas to simulate the cycle gas (the main ingredients of which are oxygen (O₂), nitrogen (N₂), and carbon dioxide (CO₂)). The coal grate-fired process was divided into three zones, namely (1) volatilization zone, (2) main combustion zone, and (3) char combustion and burn-out zone. The effects of FGR on coal combustion and NO emissions were investigated in these zones of a unit-boiler experimental system. An industrial test was then conducted on a chain boiler that previously used FGR. Data showed that if the cycle gas was directed into the furnace from the volatilization zone, the curve of the coal surface temperature moved backwards, the temperature peak increased, and coal ignition was delayed. When the FGR rate was 20%, NO emissions/g coal was 41.8% less than in the absence of FGR, in the overall combustion process except for the volatilization zone. An industrial test demonstrated that FGR decreased the NO emissions and incomplete-combustion loss of gas. NO and carbon monoxide (CO) emissions were reduced by 26.9 and 38%, respectively. These observations may prove to be beneficial in reducing ambient air pollution and saving energy.     

初始温度对人粪便好氧堆肥过程的影响

温度是好氧堆肥过程中需要控制的一个重要因素。不同的初始温度直接影响了堆肥过程中微生物活性及有机物的降解。为了研究初始温度对粪便好氧堆肥过程的影响,采用序批式好氧堆肥反应器,以新鲜锯末为载体,控制含水率在55%~60%的范围左右并强制通风的好氧条件下,进行了初始温度分别为25、35、45和55℃,20 d为一个周期好氧堆肥实验,研究了不同初始温度条件下堆肥过程有机物降解、氮的迁移转化及种子发芽指数的变化。结果表明,初始的高温度会抑制堆肥反应的进行,但初始温度越高,水解效果越显著;初始的高温有利于COD的去除,最终COD的去除率分别为88.2%、89.3%、92.0%和89.9%。初始高温对种子发芽率有抑制作用,同时延迟了堆肥的腐熟期。