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401.
Poliana Cardoso-Gustavson Francine Faia Fernandes Edenise Segala Alves Mariana Pereira Victorio Barbara Baesso Moura Marisa Domingos Caroline Albuquerque Rodrigues Andreza Portella Ribeiro Catarina Carvalho Nievola Ana Maria G Figueiredo 《Environmental science and pollution research international》2016,23(2):1779-1788
402.
Götz Schroth Edenise Garcia Bronson Winthrop Griscom Wenceslau Geraldes Teixeira Lucyana Pereira Barros 《Sustainability Science》2016,11(2):277-293
The increasing demand for agricultural commodities is a major cause of tropical deforestation. However, pressure is increasing for greater sustainability of commodity value chains. This includes the demand to establish new crop plantations and pasture areas on already deforested land so that new forest clearing for agriculture is minimized. Where tree crops are planted as part of agroforestry systems on deforested land, this amounts to a form of re-agro-forestation which can generate environmental benefits in addition to crop production. Here, we discuss a case where agroforestry systems based on cocoa (Theobroma cacao) are being established on crop and pasture land in the south of Pará state, Brazilian Amazon. The adoption of cocoa by farmers and ranchers of the region is stimulated by the coincidence of (1) favorable prospects for cocoa on the national and international markets including the expectation of a global cocoa supply gap; (2) environmental policies obliging land owners to reforest excess cleared land with native trees, with agroforests based on the native cocoa tree being an economically attractive option; and (3) biophysical conditions (especially soil fertility) favorable for growing cocoa in part of the region. We show that in the state of Pará at least 1.26 million hectares of naturally high-fertility soils in deforested areas outside legally protected and indigenous lands are potentially suitable for cocoa production with low agrochemical inputs, sufficient to make a significant contribution to closing the predicted supply gap. Their actual suitability depends on their state of degradation after years of pasture use and the availability of technologies and finance to convert them into tree crop agroforests. We discuss the significant environmental benefits of pasture re-agro-forestation with cocoa-based systems, including reduced emissions of up to 135 Mg of carbon per hectare compared to the historically common scenario of planting cocoa after forest clearing. We identify important research questions related to the scaling up of this practice and the maximization of its environmental benefits. We conclude that the coincidence of the afore-mentioned factors could drive a re-agro-forestation frontier in this part of the Amazon, with potential for positive outcomes in terms of commodity production while generating social and environmental benefits. 相似文献
403.
David Hernández-Moreno Francisco Soler-Rodríguez M. Prado Míguez-Santiyán Marcos Pérez-López 《Journal of environmental science and health. Part. B》2013,48(5):395-404
The effect of a long-term exposure of tenchs to different concentrations (10 and 100 μ g/L) of the pesticide carbofuran has been evaluated. Microsomal hepatic cytochrome P450 subfamily 1A (CYP1A) and 3A (CYP3A) activities, as well as the phase II enzyme uridine diphospho-glucuronosyltransferase (UDPGT) activity were evaluated as adequate biomarkers of fish exposure to environmentally relevant concentrations of the pesticide carbofuran in freshwater ecosystems. A clear time-dependent inhibition of both CYP1A and UDPGT activities was observed in fish exposed to the highest dose of carbofuran with respect to controls, whereas in the case of CYP3A activity, values of exposed animals did not show a clear pattern of alteration during the experiment. The results of the present study demonstrated that hepatic CYP1A and UDPGT activities from tench could be considered as sensitive biomarkers for carbamate pesticides in polluted water, thus allowing future and ecologically relevant biomonitoring studies with this species. 相似文献
404.
Marina Pereira Dore Cássia Farias Cláudia Hamacher 《Environmental monitoring and assessment》2017,189(1):44
The exploration and production of oil and gas reserves often result to drill cutting accumulations on the seafloor adjacent to drill locations. In this study, the detection of drilling influence on marine sediments was performed by meta-analytical comparison between data from pre- and post-drilling surveys undertaken in offshore Campos Basin, southeast of Brazil. Besides this overall appraisal on the geochemical variables, a multivariate assessment, considering only the post-drilling data, was performed. Among the variables, fines content, carbonates, total organic carbon, barium, chromium, copper, iron, manganese, nickel, lead, vanadium, zinc, and total petroleum hydrocarbons, only barium, copper, and hydrocarbons were related to drilling impacts. In relation to the point of discharge, relative elevated levels in the post-drilling campaigns were observed preferentially up to 500 m in the northeast and southwest directions, associated to the Brazil Current-predominant direction. Other distributed concentrations in the surroundings seem to indicate the dilution and dispersion of drilling waste promoted by meteoceanographic factors. 相似文献
405.
Naser A. Anjum Armando C. Duarte Eduarda Pereira Iqbal Ahmad 《Environmental science and pollution research international》2014,21(10):6652-6661
This study assessed the oxidative stress status, antioxidant metabolism and polypeptide patterns in salt marsh macrophyte Juncus maritimus shoots exhibiting differential mercury burdens in Ria de Aveiro coastal lagoon at reference and the sites with highest, moderate and the lowest mercury contamination. In order to achieve these goals, shoot-mercury burden and the responses of representative oxidative stress indices, and the components of both non-glutathione- and glutathione-based H2O2-metabolizing systems were analyzed and cross-talked with shoot-polypeptide patterns. Compared to the reference site, significant elevations in J. maritimus shoot mercury and the oxidative stress indices such as H2O2, lipid peroxidation, electrolyte leakage and reactive carbonyls were maximum at the site with highest followed by moderate and the lowest mercury contamination. Significantly elevated activity of non-glutathione-based H2O2-metabolizing enzymes such as ascorbate peroxidase and catalase accompanied the studied damage-endpoint responses, whereas the activity of glutathione-based H2O2-scavenging enzymes glutathione peroxidase and glutathione sulfo-transferase was inhibited. Concomitantly, significantly enhanced glutathione reductase activity and the contents of both reduced and oxidized glutathione were perceptible in high mercury-exhibiting shoots. It is inferred that high mercury-accrued elevations in oxidative stress indices were obvious, where non-glutathione-based H2O2-decomposing enzyme system was dominant over the glutathione-based H2O2-scavenging enzyme system. In particular, the glutathione-based H2O2-scavenging system failed to coordinate with elevated glutathione reductase which in turn resulted into increased pool of oxidized glutathione and the ratio of oxidized glutathione-to-reduced glutathione. The substantiation of the studied oxidative stress indices and antioxidant metabolism with approximately 53-kDa polypeptide warrants further studies. 相似文献
406.
407.
Susana L. H. Rebelo A. Melo R. Coimbra M. Emília Azenha Mariette M. Pereira Hugh D. Burrows Mohamed Sarakha 《Environmental Chemistry Letters》2007,5(1):29-33
The photodegradation of the herbicides atrazine and ametryn with visible light in aerated neutral aqueous solutions and 5,
10, 15, 20-tetrakis (2,6-dichloro-3-sulfophenyl) porphyrin or 5, 10, 15, 20-tetrakis (4-sulfophenyl) porphyrin as sensitizers
are reported for the first time. Our findings show that the degradation percentage reached 30% for atrazine and 63% for ametryn.
The final photoproducts were characterized as dealkylated s-triazines. Photolysis of the pesticides in the presence of a singlet oxygen quencher showed only a minor contribution of
this type of mechanism, while a bimolecular quenching reaction between the triplet state of the sensitizer and the pesticides
is excluded by flash photolysis studies. It is proposed that the mechanism may involve the formation of a superoxide radical
anion from the triplet state of the sensitizer and molecular oxygen, followed by a radical decomposition pathway.
Selected article from 1st International Meeting on Photochemistry, Photocatalysis and Environmental Applications, Agadir,
2006, organised by Prof. Dr. Ait Ichou, University Ibn Zohr, Agadir, Morocco 相似文献
408.
Organic compounds derived from coal-tar wastes in a contaminated aquifer in St. Louis Park, Minnesota, were identified, and their partition coefficients between the tar phase and aqueous phase were determined and compared with the corresponding n-octanol/water partition coefficients. Coal tar contains numerous polycyclic aromatic compounds, many of which are suspected carcinogens or mutagens. Groundwater contamination by these toxic compounds may pose an environmental health hazard in nearby public water-supply wells. Fluid samples from this aquifer developed two phases upon settling: an upper aqueous phase, and a lower oily-tar phase. After separating the phases, polycyclic aromatic compounds in each phase were isolated using complexation with N-methyl-2-pyrrolidone and identified by fused-silica capillary gas chromatography/mass spectrometry. Thirty-one of the polycyclic aromatic compounds were chosen for further study from four different classes: 12 polycyclic aromatic hydrocarbons, 10 nitrogen heterocycles, 5 sulfur heterocycles, and 4 oxygen heterocycles. Within each compound class, the tar/water partition coefficients of these compounds were reasonably comparable with the respective n-octanol/water partition coefficient. 相似文献
409.
Fabíola Maria N. Nunes M.C.C. Veloso P.A. de P. Pereira J.B. de Andrade 《Atmospheric environment (Oxford, England : 1994)》2005,39(40):927
Biogenic emissions of volatile organic compounds (VOCs) play a fundamental role in atmospheric chemistry. Vegetation is the most abundant natural source of VOCs, while terpenoids, as limonene, α and β pinene and mircene, top the plants emission list. Much interest has been demonstrated in oxidation and photooxidation reactions of VOCs, particularly of monoterpenoids, owing to their diversity and to uncertainties regarding their mechanism of reaction. Quantification of primary carbonylic compounds, as well as of biradical reaction components, is highly relevant to the understanding of the major reactions. In this context, taking into account both structural factors and the fact that these compounds are found in the essential oils of plants typically found in Brazil and that they may be present in the atmosphere from emission by the plants, the monoterpenoids (S)-(+)-carvone, (R)-(−)-carvone, (−)-carveol, geraniol and citral (a mixture of the isomers geranial and neral) were selected for this study.The ozonolysis reactions of the monoterpenoids were carried out under dark conditions for all experiments, due to their photochemical reactivity. The analysis of the results lets us propose a mechanism by which these reactions occur. The observed results of the ozonolysis of S and R carvone suggest that the stereochemistry of asymmetric carbon does not affect either in the yields of both formaldehyde and of OH radicals produced in the reaction, or in the reactivity of these compounds, for which the rate constants were in the scale of 10−6 s−1.We found that, in the (−)-carveol's cis and trans mixture, even though the hydroxyl in the axial position—in the case of trans-(C) and cis-(D′) isomers—favors the attack by the ozone molecule on the external double bond, thus increasing the mixture's reactivity , it affects the average production of formaldehyde. The presence of geraniol and citral led to the production of formaldehyde, propanone, glyoxal, methyl–glyoxal and cyclohexanone (OH radicals) as reaction products. The influence of an electron attractor group bonded to the carbon of the double bond, on the reactivity of the double bond, could not be observed in the case of citral, due to strong interference occurring in the instrument in all experiments with this monoterpenoid. For this reason, only the kinetics of geraniol was monitored . 相似文献
410.
Jörg Römbke Bernhard Förster Stephan Jänsch Adam Scheffczyk Marcos Garcia 《Environmental Sciences Europe》2005,17(2):85-93