A Pt/WO3/TiO2 catalyst for propane oxidation was prepared by a stepwise wet impregnation method, and was aged at 800℃ for 5 hr. Compared to the sulfate-derived titania supported catalyst, the introduction of tungsten oxide as stable Bronsted acid sites led to the formation of more metallic platinum active sites at the Pt/WO3 interface. The dissociation of surface intermediates for propane oxidation was promoted on the WO3-modified catalyst. This, as well as the inhibition effects of tungsten oxide on the sintering of anatase and the phase transformation to rutile, resulting in a high activity and thermal stability for the Pt/WO3/TiO2 catalyst. 相似文献
This study screened out eluants for efficiently desorbing metal nanoparticles from plant root surface, and distinguished the proportions of CuO-nanoparticles uptake and adsorption. 相似文献
Adsorption of arsenic (V) by natural zeolitic tuff, modified with iron (III), was investigated. Also, the iron (III) adsorption
characteristics by natural zeolitic tuff was evaluated. It was determined that iron (III) adsorption by starting zeolitic
tuff was best represented by the Freundlich type of isotherm, having correlation coefficient (r2) of 0.990. Arsenic (V) adsorption by iron (III)-modified zeolitic tuff followed a nonlinear type of isotherm. The best fit
of the experimental data was obtained using the Langmuir–Freundlich model (r2 = 0.99), with the estimated maximum of arsenic (V) adsorption to iron (III)-modified zeolitic tuff of 1.55 mg/g. 相似文献
This article investigates the relationship of local air pollution pattern with urban land use and with urban thermal landscape
using a GIS approach. Ambient air quality measurements for sulfur dioxide, nitrogen oxide, carbon monoxide, total suspended
particles, and dust level were obtained for Guangzhou City in South China between 1981 and 2000. Landsat TM images and aerial
photo derived maps were used to examine city's land use and land cover at different times and changes. Landsat thermal infrared
data were employed to compute land surface temperatures and to assess urban thermal patterns. Relationships among the spatial
patterns of air pollution, land use, and thermal landscape were sought through GIS and correlation analyses. Results show
that the spatial patterns of air pollutants probed were positively correlated with urban built-up density, and with satellite
derived land surface temperature values, particularly with measurements taken during the summer. It is suggested that further
studies investigate the mechanisms of this linkage, and that remote sensing of air pollution delves into how the energy interacts
with the atmosphere and the environment and how sensors see pollutants. Thermal infrared imagery could play a unique role
in monitoring and modeling atmospheric pollution. 相似文献
Studying the modes of selenium occurrence in high-Se soils and its behaviors can improve understanding and evaluating its cycling, flux, and balance in geo-ecosystems and its influence on health. In this paper, using a modified sequential chemical extraction technique, seven operationally defined selenium fractions and Se valence distribution were determined about five soils in which paddy was planted (W1, W2, W3, W4, W5) and five soils in which maize was planted (H1, H2, H3, H4, H5) around the selenium-rich core, Ziyang County, Shaanxi Province, China. The results show that selenium fractions in the soils mainly include sulfide/selenide and base-soluble Se, and ligand-exchangeable Se is also high for five soils in which paddy was planted. For water-soluble Se, Se (IV) is main Se valence and almost no Se (VI) was determined about five soils in which paddy was planted, while almost 1:1 of Se (IV) and Se (VI) coexist about five soils in which maize was planted. For exchangeable Se, similar results were found. For the first time, two typical high-Se soils (W1 soil and H1 soil) were chosen to measure the pH-dependent solid-solution distribution of selenite in the pH range 3–9, and the results were explained using LCD (ligand and charge distribution) adsorption modeling. The desorbed selenite concentrations from the two soils are in general underestimated by the model due to a comparable binding affinity of phosphate and selenite on goethite and much lower amount of total selenite than total reactively adsorbed phosphate. The pH dependency of adsorption of selenite added to the soil can be successfully described with the LCD model for W1 soil. Whereas considering the influence of Al-oxides, by lowering selenite adsorption affinity constant K of Se adsorption on goethite by 16 times, the LCD model can describe the adsorption much better. The results can help to understand selenium cycling, flux, and balance in typical high-Se soils.