Development of composting process of oil palm industrial wastes by multi-enzymatic fungal system

There is an increased interest in composting as an effective means of handling large amounts of organic wastes generated by oil palm industries in Malaysia. However, very few studies have been conducted to develop an effective composting process using the multi-enzymatic system. This study demonstrates an effective composting process of EFB (empty fruit bunch) with POME (palm oil mill effluent), using the optimized process parameters and compatible multi-enzymatic fungal system. A higher decrease (3 %) of organic matter was achieved in the fungal treated system, almost double that of the control (without inoculum). The lowest C/N ratio and soluble protein content recorded were about 17 and 128.82 g/kg, respectively. The maximum germination index obtained was 116 % at day 50 of treatment, which is considered high compared to the control (uninoculated). Furthermore, the maximum activity of ligninase enzyme was found to be 25.95 U/g and the highest cellulase activity was recorded at 0.975 U/g.     

The Impact of Projected Climate Change Scenarios on Nitrogen Yield at a Regional Scale for the Contiguous United States

Improved understanding of the potential regional impacts of projected climatic changes on nitrogen yield is needed to inform water resources management throughout the United States (U.S.). The objective of this research is to look broadly at watersheds in the contiguous U.S. to assess the potential regional impact of changes in precipitation (P) and air temperature (T) on nitrogen yield. The SPAtially Referenced Regression On Watershed attributes model and downscaled P and T outputs from 14 general circulation models were used to explore impacts on nitrogen yield. Results of the analysis suggest that projected changes in P and T will decrease nitrogen yield for the majority of the contiguous U.S., including the watersheds of the Chesapeake Bay and Gulf of Mexico. Some regions, however, such as the Pacific Northwest and Northern California, are projected to face climatic conditions that, according to the model results, may increase nitrogen yield. Combining the projections of climate‐driven changes in nitrogen yield with projected changes in watershed nitrogen inputs could help water resource managers develop regionally specific, long‐term strategies to mitigate nitrogen pollution.     

A reassessment of energy and GDP relationship: the case of Australia

This paper investigates the long- and short-run relationships between energy consumption and economic growth in Australia using the bound testing and the ARDL approach. The analytical framework utilized in this paper includes both production and demand side models and a unified model comprising both production and demand side variables. The energy–GDP relationships are investigated at aggregate as well as several disaggregated energy categories, such as coal, oil, gas and electricity. The possibilities of one or more structural break(s) in the data series are examined by applying the recent advances in techniques. We find that the results of the cointegration tests could be affected by the structural break(s) in the data. It is, therefore, crucial to incorporate the information on structural break(s) in the subsequent modelling and inferences. Moreover, neither the production side nor the demand side framework alone can provide sufficient information to draw an ultimate conclusion on the cointegration and causal direction between energy and output. When alternative frameworks and structural break(s) in time series are explored properly, strong evidence of a bidirectional relationship between energy and output can be observed. The finding is true at both the aggregate and the disaggregate levels of energy consumption.     

Bubble size distribution in a laboratory-scale electroflotation study

The performance of electroflotation (EF) is strongly influenced by the size of O₂ and H₂ bubbles. Therefore, in this study, the bubble sizes are measured in a lab-scale EF cell using a high-speed camera. The mean bubble size is found to vary in the range of 32.7–68.6 μm under different operating conditions. This study shows that the electrode material, current density, water pH, ionic strength, and frother (Tennafroth 250) concentration are important factors in controlling the bubble size. Furthermore, four mathematical distributions (normal, log-normal, Weibull, and gamma distributions) are fitted to the experimental data, among which the log-normal distribution is found to be the best fit based on the lower Anderson-Darling (AD) value.     

Development of novel absorbents for CO2 capture from blast furnace gas

In order to establish energy-saving technology for CO₂ capture from blast furnace gas, novel absorbents were developed in the laboratory and evaluated at a 1 t_CO2/d test plant. At first, CO₂ absorption and desorption behaviors of single-component amine solvents for simulated blast furnace gas (CO₂/N₂ = 20%/80%) were investigated through a screening test using a small scrubbing bottle. These amine solvents were additionally analyzed using nuclear magnetic resonance (¹³C NMR) spectroscopy and reaction calorimetry. The results of the laboratory experiments showed that there was a trade-off between absorption rate and enthalpy of absorption but some absorbents had unique features. For example, 2-isopropylaminoethanol (IPAE) had high absorption rate and small enthalpy of absorption. Then, new IPAE-based amine solvents (RITE solvents: RITE-A and RITE-B) were formulated and evaluated at the 1 t_CO2/d test plant. CO₂ regeneration energies of the RITE solvents were 3.3 and 3.1 GJ/t_CO2, respectively. With certain process conditions and plant specifications optimized, RITE-B was estimated to have the potential to achieve 2.5 GJ/t_CO2.     

Development, validation, and uncertainty measurement of multi-residue analysis of organochlorine and organophosphorus pesticides using pressurized liquid extraction and dispersive-SPE techniques

Increased water use associated with rapid growth in the Las Vegas Valley has inadvertently led to the creation of unique wetland systems in Southern Nevada with an abundance of biological diversity. Constructed and naturally created wetlands in the Las Vegas Valley watershed were studied to characterize and understand their potential role for improving ecosystem services (i.e., water purification). Nutrient and metal removal was assessed at four sites including a natural urban runoff wetland, a constructed urban runoff wetland, a constructed wastewater wetland, and a natural urban runoff/wastewater wetland. Plant nutrient uptake was dependent on ambient nutrient concentrations in water and sediments of specific wetlands, irrespective of the type of plants present. Phosphorus was mostly concentrated in below-ground plant parts whereas nitrogen was concentrated in above-ground parts. As for metalloids, bulrushes were more efficient than cattails at taking up arsenic and selenium. Averaging all the wetland sites and plant species, total nitrogen, phosphorus, arsenic and selenium removal was 924.2, 61.5, 0.30, and 0.38 kg/ha/year, respectively. Our findings suggest that natural and created wetland systems can improve water quality in the Las Vegas Valley watershed for some common pollutants, however, other measures are still needed to improve water quality below regulatory thresholds.     

Experimental study of cross-flow wet electrostatic precipitator

This paper reports development and testing of a novel cross-flow wet electrostatic precipitator (WESP), recently patented at Ohio University, that utilizes vertical columns of permeable material in the form of polypropylene ropes placed in a cross-flow configuration within a flue gas stream. The cross-flow design has large surface area, which provides scrubbing action; therefore, it has the potential for removing multiple pollutants, including particulates, gases, vapors, and mists. In this new method, the ropes are kept wet by the liquid (water) introduced from the top of the cells running downward on the ropes by capillary action, making the permeable materials act as the ground electrode for capturing particles from the flue gas. Preliminary testing has shown an efficiency of well above 80% using two cells and three sets of discharge electrodes. Since the material of construction is primarily corrosion-resistant polymeric material, both weight and cost reductions are expected from this new design.

Implications: The newly invented cross-flow WESP exhibit particulate collection efficiency of well above 80% when introduced in particulate-laden exhaust flow. This value was obtained using a two cells and three discharge electrodes configuration. The electric field strength has a substantial effect on the collection efficiency. Also, the pressure drop test results indicate that there is a potential to increase the collection area, which, in turn, will increase the collection efficiency further.     

Gasification applicability study of polyurethane solid refuse fuel fabricated from electric waste by measuring syngas and nitrogenous pollutant gases

To recycle polyurethane foam waste generated from electric appliance recycling centers for use as fuel in a gasification process, polyurethane solid refuse fuel fabricated as pellets was analyzed for the characteristics of elemental composition, proximate analysis, heating value, and thermo-gravimetric testing. It has a high heating value of 29.06 MJ/kg with a high content of combustibles, which could be feasibly used in any thermal process. However, the nitrogen content, of up to 7 %, was comparably higher than for other fuels such as coal, biomass, and refuse-derived fuel, and may result in the emission of nitrogenous pollutant gases of HCN and NH₃. By conducting gasification experiments on polyurethane solid refuse fuel in a fixed-bed reactor, a syngas with a heating value of 9.76 kJ/m³ and high content of both H₂ and CO were produced with good gasification efficiency; carbon conversion 54 %, and cold gas efficiency 60 %. The nitrogenous pollutant gases in syngas were measured at the concentrations of 160 ppm hydrogen cyanide and 40 ppm ammonia, which may have to be reduced using proper cleaning technologies prior to the commercialization of gasification technology for polyurethane waste.