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951.
Dioxins,chlorophenols and other chlorinated organic pollutants in colloidal and water fractions of groundwater from a contaminated sawmill site 总被引:1,自引:1,他引:0
Persson Y Shchukarev A Oberg L Tysklind M 《Environmental science and pollution research international》2008,15(6):463-471
BACKGROUND, AIM, AND SCOPE: The distribution of chlorinated organic contaminants in groundwater and the importance of colloids were studied in groundwater from a sawmill site contaminated by chlorophenol preservatives. MATERIALS AND METHODS: The groundwater was fractionated into three different size ranges: (1) >0.7 mum, (2) 0.4-0.7 mum and (3) 0.2-0.4 mum and the filtered water phase. The concentrations of chlorophenols (CP), chlorinated phenoxy phenols (PCPP), chlorinated diphenyl ethers (PCDE), chlorinated dibenzofurans (PCDF) and chlorinated dibenzo-p-dioxins (PCDD) were determined in each fraction. The colloids were characterised regarding the chemical composition using X-ray photoelectron spectroscopy (XPS). RESULTS: Chlorophenols were mostly found in the water fraction and PCDD/Fs were found almost exclusively in the particulate fractions. For example, the filtered water phase contained 2,100 mug l(-1) and 0.72 ng l(-1) for CPs and PCDD/Fs, respectively, and the particulate fractions contained 27 mug l(-1) and 32 ng l(-1) for CPs and PCDD/Fs, respectively. XPS evaluation of the particulate phases showed no correlation between the surface chemistry of the particle properties and the distribution of chlorinated compounds. DISCUSSION: The results suggest that groundwater transport of CPs, PCPPs, PCDEs and PCDD/Fs may occur from contaminated sawmill sites and that the colloid-facilitated transport, especially of PCDD/Fs, is substantial. The results correlated well with previous studies of compounds sorbed to dissolved organic carbon, which indicate that dissolved and colloidal organic carbon facilitated the transport of PCDEs, PCDFs and PCDDs particularly. CONCLUSIONS: Several classes of chlorinated compounds were readily detected in the groundwater samples. Due to the differences in their physicochemical properties, CPs, PCPPs, PCDEs and PCDD/Fs vary in their partitioning between colloidal fractions and the filtered groundwater. The proportion of the bound fraction increased with an increasing hydrophobicity of the chlorinated compounds. The groundwater transport of colloid-associated pollutants from the site may be significant. RECOMMENDATIONS AND PERSPECTIVES: The results imply that colloidal particles <0.7 mum are freely mobile in groundwater from this site. The groundwater transport of colloid-associated pollutants may be significant. However, the extent of the problem is not yet known and, thus, further research is needed to evaluate the impact of colloidal transport of hydrophobic organic contaminants. In Sweden alone, 400 to 500 sawmill sites are estimated to be contaminated with PCDD/Fs as a result of the former use of CP-based wood preservatives. The widespread use of CP mixtures for a variety of applications, including wood preservation, indicates that potential colloidal transport will be an issue of concern in many countries. 相似文献
952.
This article describes the history of the Coachella Valley Multiple Species Habitat Conservation Plan (CVMSHCP), in the Riverside
County region of Southern California. When this collaborative biodiversity conservation planning process began, in 1994, local
participants and supporters had numerous factors working in their favor. Yet, as of April 2007, nearly 13 years had passed
without an approved plan. This is a common problem. Many multiple species habitat conservation plans now take more than a
decade to complete, and the long duration of these processes often results in negative consequences. The CVMSHCP process became
bogged down—despite strong scientific input and many political advantages—due to problematic relationships between the Plan’s
local supporters, its municipal signatory parties, and officials from the state and federal wildlife agencies, particularly
the regional office of the US Fish and Wildlife Service. This case study demonstrates the crucial importance of institutional
structures and relationships, process management, and timeliness in habitat conservation planning. We conclude by offering
several related recommendations for future HCP processes. 相似文献
953.
Qinhua Fang Luoping Zhang Huasheng Hong Liyu Zhang Frances Bristow 《Environment, Development and Sustainability》2008,10(1):41-49
Environmental planning at different levels has been called for by environmental departments in China during last years to
integrate environment consideration to economic development. Based on the accomplished environmental planning practice in
Xiamen China, the paper suggests a general environmental planning process with ecological function zoning as its key steps,
at the same time an effective method for ecological function zoning was formulated. The case studies of Dongfu suburban town
environmental planning and Xiamen eco-city conceptual planning indicate that scientifically sound results of ecological function
zoning can contribute to improving not only the adaptability and acceptability of environmental planning, also the environmental
management and the decision-making. The experience shows that the ecological function zoning methods should be applied according
to the principles of adaptive management, resource-based and community-based, so that it can integrate science into decision-making
process, avoiding both narrow-minded viewpoints of planners and natural resource use conflicts among variety of stakeholders.
Problems to be resolved in the future are also pointed out in the ending part. 相似文献
954.
Carlos Navarro Florentino de Lope Anders Pape Møller 《Behavioral ecology and sociobiology》2007,61(8):1161-1168
Homeobox genes regulate development of digits, and it has been suggested that the ratio of length of second to length of fourth
digit reflects such genetic effects in a sex-specific manner. We show that digit ratios in the sexually dichromatic house
sparrow Passer domesticus differ between sexes, with males having higher ratios than females, and that individuals produce consistent ratios on the
two feet. If Homeobox or other genes had pleiotropic effects on development of digits, behavior, and physiology of males and
females, we would expect secondary sexual characters and immunity to be related to digit ratio in a sex-specific manner. The
size of the visible part of the black badge in February (a secondary sexual character), but not total badge size, was positively
correlated with digit ratios, suggesting that males with more male-like digit ratios had larger visible badges. Because of
sex-specific effects of development on secondary sexual characters and immunity, we predicted sex-specific differences in
immune response to be related to digit ratio. House sparrows with large digit ratios had weaker T cell-mediated immune response
than individuals with small digit ratios, particularly in females, implying that females with more male-like digit ratios
had weak immune responses. These findings are consistent with the hypothesis that early development, as reflected by digit
ratios, and genetics affect the expression of adult characters that are supposedly strongly contributing to fitness. 相似文献
955.
Richard A. Holland 《Behavioral ecology and sociobiology》2007,61(5):653-660
Bats have been extensively studied with regard to their ability to orient, navigate and hunt prey by means of echolocation,
but almost nothing is known about how they orient and navigate in situations such as migration and homing outside the range
of their echolocation system. As volant animals, bats face many of the same problems and challenges as birds. Migrating bats
must relocate summer and winter home ranges over distances as far as 2,000 km. Foraging bats must be able to relocate their
home roost if they range beyond a familiar area, and indeed circumstantial evidence suggests that these animals can home from
more than 600 km. However, an extensive research program on homing and navigation in bats halted in the early 1970s. The field
of bird navigation has advanced greatly since that time and many of the mechanisms that birds are known to use for navigation
were not known or widely accepted at this time. In this paper I discuss what is known about orientation and navigation in
bats and use bird navigation as a model for future research in bat navigation. Technology is advancing such that previous
difficulties in studying orientation in bats in the field can be overcome and so that the mechanisms of navigation in this
highly mobile animal can finally be elucidated. 相似文献
956.
Determining the scale of larval dispersal and population connectivity in demersal fishes is a major challenge in marine ecology.
Historically, considerations of larval dispersal have ignored the possible contributions of larval behaviour, but we show
here that even young, small larvae have swimming, orientation and vertical positioning capabilities that can strongly influence
dispersal outcomes. Using young (11–15 days), relatively poorly developed (8–10 mm), larvae of the pomacentrid damselfish,
Amblyglyphidodon curacao (identified using mitochondrial DNA), we studied behaviour relevant to dispersal in the laboratory and sea on windward and
leeward sides of Lizard Island, Great Barrier Reef. Behaviour varied little with size over the narrow size range examined.
Critical speed was 27.5 ± 1.0 cm s−1 (30.9 BL s−1), and in situ speed was 13.6 ± 0.6 cm s−1. Fastest individuals were 44.6 and 25.0 cm s−1, for critical and in situ speeds, respectively. In situ speed was about 50% of critical speed and equalled mean current speed.
Unfed larvae swam 172 ± 29 h at 8–10 cm s−1 (52.0 ± 8.6 km), and lost 25% wet weight over that time. Vertical distribution differed between locations: modal depth was
2.5–5.0 and 10.0–12.5 m at leeward and windward sites, respectively. Over 80% of 71 larvae observed in situ had directional
swimming trajectories. Larvae avoided NW bearings, with an overall mean SE swimming direction, regardless of the direction
to nearest settlement habitat. Larvae made smaller changes between sequential bearings of swimming direction when swimming
SE than in other directions, making it more likely they would continue to swim SE. When swimming NW, 62% of turns were left
(more than in other directions), which would quickly result in swimming direction changing away from NW. This demonstrates
the larvae knew the direction in which they were swimming and provides insight into how they achieved SE swimming direction.
Although the cues used for orientation are unclear, some possibilities seemingly can be eliminated. Thus, A. curacao larvae near Lizard Island, on average swam into the average current at a speed equivalent to it, could do this for many hours,
and chose different depths in different locations. These behaviours will strongly influence dispersal, and are similar to
behaviour of other settlement-stage pomacentrid larvae that are older and larger. 相似文献
957.
Catch and acoustic telemetry data were used to test three predictions of lekking behaviour in Atlantic cod (Gadus morhua L.) at a small-scale spawning ground (∼25 km2) in Placentia Bay, Newfoundland: (1) that cod form male-skewed aggregations during spawning; (2) spawning arenas occur at consistent sites; and (3) on the arenas, there will be higher proportions of spawning fish. Forty-two fishing sets from 1998 to 2003 indicated male-skewed sets early in the spawning season (April) in 5 of 6 survey years. Male-skewed sets were consistently distributed at depths < 50 m and mostly in one part of the ground. The proportions of spawning females and spent males were significantly higher in male-skewed sets, whereas sets with equal sex ratios had significantly higher proportions of immature males and spent females. In addition, cod of both sexes were significantly larger in male-skewed sets. Telemetric tracking of 25 cod in 2002 and 2003 (12 males, 13 females) indicated that both males and females were highly mobile while present on the spawning ground. Overall, our results add support to the hypothesis that cod employ a lekking mating system. 相似文献
958.
Characteristics of aerosol types during large-scale transport of air pollution over the Yellow Sea region and at Cheongwon,Korea, in 2008 总被引:1,自引:0,他引:1
Episodes of large-scale transport of airborne dust and anthropogenic pollutant particles from different sources in the East
Asian continent in 2008 were identified by National Oceanic and Atmospheric Administration satellite RGB (red, green, and
blue)-composite images and the mass concentrations of ground level particulate matter. These particles were divided into dust,
sea salt, smoke plume, and sulfate by an aerosol classification algorithm. To analyze the aerosol size distribution during
large-scale transport of atmospheric aerosols, aerosol optical depth (AOD) and fine aerosol weighting (FW) of moderate imaging
spectroradiometer aerosol products were used over the East Asian region. Six episodes of massive airborne dust particles,
originating from sandstorms in northern China, Mongolia, and the Loess Plateau of China, were observed at Cheongwon. Classified
dust aerosol types were distributed on a large-scale over the Yellow Sea region. The average PM10 and PM2.5 ratio to the total
mass concentration TSP were 70% and 15%, respectively. However, the mass concentration of PM2.5 among TSP increased to as
high as 23% in an episode where dust traveled in by way of an industrial area in eastern China. In the other five episodes
of anthropogenic pollutant particles that flowed into the Korean Peninsula from eastern China, the anthropogenic pollutant
particles were largely detected in the form of smoke over the Yellow Sea region. The average PM10 and PM2.5 ratios to TSP
were 82% and 65%, respectively. The ratio of PM2.5 mass concentrations among TSP varied significantly depending on the origin
and pathway of the airborne dust particles. The average AOD for the large-scale transport of anthropogenic pollutant particles
in the East Asian region was measured to be 0.42 ± 0.17, which is higher in terms of the rate against atmospheric aerosols
as compared with the AOD (0.36 ± 0.13) for airborne dust particles with sandstorms. In particular, the region ranging from
eastern China, the Yellow Sea, and the Korean Peninsula to the Korea East Sea was characterized by high AOD distributions.
In the episode of anthropogenic polluted aerosols, FW averaged 0.63 ± 0.16, a value higher than that in the episode of airborne
dust particles (0.52 ± 0.13) with sandstorms, showing that fine anthropogenic pollutant particles contribute greatly to atmospheric
aerosols in East Asia. 相似文献
959.
Ghumman AR Ahmad MM Hashmi HN Kamal MA 《Environmental monitoring and assessment》2012,184(5):3153-3163
Hill torrents cause a lot of environmental and property damage in Pakistan every year. Proper assessment of direct runoff in the form of hill torrents is essential for protection of environment, property, and human life. In this paper, direct surface runoff hydrograph (DSRH) was derived for a large catchment using the geomorphologic instantaneous unit hydrograph concept. The catchment with hill torrent flows in semi-arid region of Pakistan was selected for this study. It was divided into series of linear cascades and hydrologic parameters required for Nash's conceptual model, and were estimated using geomorphology of the basin. Geomorphologic parameters were derived from satellite images of the basin and ERDAS and ArcGIS were used for data processing. Computer program was developed to systematically estimate the dynamic velocity, its related parameters by optimization and thereby to simulate the DSRH. The data regarding rainfall-runoff and satellite images were collected from Punjab Irrigation and Power Department, Pakistan. Model calibration and validation was made for 15 rainfall-runoff events. Ten events were used for calibration and five for validation. Model efficiency was found to be more than 90% and root mean square error to be about 5%. Impact of variation in model parameters (shape parameter and storage coefficient) on DSRH was investigated. For shape parameter, the number of linear cascades varied from 1 to 3 and it was found that the shaper parameter value of 3 produced the best DSRH. Various values of storage coefficient were used and it was observed that the value determined from geomorphology and the dynamic velocity produced the best results. 相似文献
960.
Montes AM González-Farias FA Botello AV 《Environmental monitoring and assessment》2012,184(3):1359-1369
The lagoon system of Navachiste-Macapule is located in northern Mexico, in the state of Sinaloa, with an area of 24,000 ha.
The main economic activity in the area is agriculture, and the lagoon lies next to the irrigation district ID-063 which covers
116,615 ha. The purpose of this study is to evaluate the levels of pollution generated by organochlorine pesticides (OC) in
the surface sediments of the lagoon and in the agricultural drains of the ID-063 that are supposedly transported into the
system as a result of agricultural activities and runoff from adjacent land. For this, between 2006 and 2007, 45 surface sediment
samples were collected (warm dry, rainy and cold dry) from 15 sampling sites, during the three climatic seasons. Of these,
eight were located inside the lagoon in marine conditions (salinity >31 PSU) and seven in the agricultural drains of the ID-063
in freshwater conditions (salinity <5 PSU). The average concentration of the OC in the sediments was 44.75 ng g − 1, among which the group of the alicyclic compounds presented the greatest concentrations. The average value of the total organic
carbon (TOC) in the sediments of the system was 0.90%. The sediments collected inside the lagoon had an average OC concentration
of 18.97 ng g − 1, and the predominant type of sediment was fine to very fine sand. The average OC concentration in the sediments collected
in the agricultural drains was 75.69 ng g − 1, where fine sediments (silt) were predominant. The presence of methoxychlor, endrin and heptachlor suggested that these compounds
were continuously used in the system, even though their use is forbidden in Mexico. 相似文献