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581.
Dissolved organic matter effects on the performance of a barrier to polycyclic aromatic hydrocarbon transport by groundwater 总被引:6,自引:0,他引:6
In order to contain the movement of organic contaminants in groundwater, a subsurface sorption barrier consisting of sand or clay minerals coated with a cationic surfactant has been proposed. The effectiveness of such a sorption barrier might be affected by the presence of dissolved organic matter (DOM) in the groundwater. To study the impact of DOM on barrier performance, a series of batch experiments were performed by measuring naphthalene and phenanthrene sorption onto sand coated with cetylpyridinium chloride (CPC) and bentonite coated with hexadecyltrimethylammonium bromide (HDTMA) in the presence of various concentrations of DOM. The overall soil-water distribution coefficient (K*) of naphthalene and phenanthrene onto CPC-coated sand decreased with increasing DOM concentration, whereas the K* of the compounds onto HDTMA-coated bentonite slightly increased with increasing DOM concentration. To describe the overall distribution of polycyclic aromatic hydrocarbons (PAHs) in the systems, a competitive multiphase sorption (CMS) model was developed and compared with an overall mechanistic sorption (OMS) model. The modeling studies showed that while the OMS model did not explain the CPC-coated sand experimental results, a model that included competitive sorption between DOM and PAH did. The experimental results and the modeling study indicated that there was no apparent competition between DOM and PAH in the HDTMA-coated bentonite system, and indicated that in groundwater systems with high DOM, a barrier using HDTMA-coated bentonite might be more effective. 相似文献
582.
583.
584.
Background monitoring and long-range transport of atmospheric CFC-11 and CFC-12 at Kosan, Korea 总被引:3,自引:0,他引:3
Kim J Oh SN Cho HM Park MK Kim KR Elkins JW 《Environmental monitoring and assessment》2001,70(1-2):47-56
The background concentrations of atmospheric CFC-11 and CFC-12were monitored to assess their impact on stratospheric ozone depletion and global warming from September 1995 to March 1999 at Kosan, Korea, located at eastern margin of the Asian Continent. The concentrations of atmospheric CFC-11 at Kosan have decreased slightly, at a rate of –2.5 pptv yr-1, over the period in response to the Montreal Protocol. The CFC-12 mixing ratio at Kosan continues to increase in the atmosphere at a rate of 5.7 pptv yr-1 despite international regulations, because of its extreme atmosphere persistence. Recent trends ofthese two chlorofluorocarbons at Kosan, Korea were concordant with those of the northern hemispheric background monitored unitat Mauna Loa, Hawaii. The maximum seasonal mean mixing ratios of CFC-11 and CFC-12 at Kosan, Korea, were 270±4 pptv inthe spring and 538±9 pptv in the winter, and the corresponding seasonal minima were 267±7 and 529±12 pptv. This occurred in the summer and was due to southeasterlywinds from the northwestern Pacific Ocean. By performing a three-day isentropic backward trajectory analysis, it was shownthat air masses at Kosan, and with the exception of summer, mainly originated from central and northern China. In particular, the mixing ratios of these two contaminant speciesare closely related with their air mass trajectories. 相似文献
585.
Study on Size Distribution of Total Aerosol and Water-Soluble Ions During an Asian Dust Storm Event at Jeju Island, Korea 总被引:3,自引:0,他引:3
Soil dust particles transported from loess regions of the Asian continent, called Asian dust, highly influences the air quality of north-eastern Asia and the northern Pacific Ocean. In order to investigate the effects of these dust storms on the chemical composition of atmospheric aerosol particles with different size, measurements of size distributions of total aerosol and major ion species were carried out on Jeju Island, Korea during April 2001. Juju Island was chosen for the study because the levels of emissions of anthropogenic air pollutants are very low. A 5-stage cascade impactor was used to sample size-fractionated aerosol particles. Samples were analyzed for major water-soluble ions using Dionex DX-120 ion chromatograph. The average mass concentration of total aerosol was found to be 24.4 and 108.3 microg m(-3) for non-Asian dust and Asian dust periods, respectively. The total aerosol size distribution, measured during the non-Asian dust period, was bimodal, whereas the coarse particles dominated the size distribution of total aerosol during the Asian dust period. It was found that SO4(2-), NH4+ and K+ were mainly distributed in fine particles, while Cl-, NO3-, Na+, Mg2+ and Ca2+ were in coarse particles. Although SO4(2-) was mainly distributed in fine particles, during the Asian dust period, the concentrations in coarse particles were significantly increased. This indicates heterogeneous oxidation of SO2 on wet surfaces of basic soil dust particles. The NH4+ was found to exist as (NH4)2SO4 in fine particles, with a molar ratio of NH4+ to SO4(2-) of 2.37 and 1.52 for non-Asian dust and Asian dust periods, respectively. Taking into account the proximity of the sampling site to the sea, and the observed chloride depletion, coarse mode nitrate, during the non-Asian dust period, is assumed to originate from the reaction of nitric acid with sodium chloride on the surfaces of sea-salt particles although the chloride depletion was not shown to be large enough to prove this assumption. During the Asian dust period, however, chloride depletion was much smaller, indicating coarse nitrate particles were mainly produced by the reaction of nitric acid with surfaces of basic soil particles. Most chloride and sodium components were shown to originate from sea-salt particles. Asian dust aerosols, arriving at Jeju Island, contained considerable amounts of sea-salt particles as they passed over the Yellow Sea. Ca2+ was shown to be the most abundant species in Asian dust particles. 相似文献
586.
Comparison of seven indicator PCBs and three coplanar PCBs in beef, pork, and chicken fat 总被引:2,自引:0,他引:2
The risk assessment of polychlorinated biphenyls (PCBs) is difficult since complex congeners were used in many industrial applications for a long period of time and the residue monitoring in foods of animal origin and the environment were not established in comparable systems. The relationships of determined concentrations in indicator PCB congeners (mono- and di-ortho PCBs) and coplanar PCB congeners (non-ortho PCBs) in livestock products are presented in this study. The concentrations of seven indicator PCBs were compared with three coplanar PCBs in beef, pork, and chicken fat. Distributions of concentration for the indicator PCBs in three different animal species were similar except for that of PCB-118 (2,3',4,4',5-pentachlorobiphenyl) in pork fat. The congeners with the highest concentration were PCB-138 (2,2',3,4,4',5'-hexachlorobiphenyl) in beef and pork fat and PCB-28 (2,4,4'-trichlorobiphenyl) in chicken fat. The bioaccumulation and metabolism of PCBs in animal species represent different congener profiles in livestock products. The percentage of the total concentration of three coplanar PCBs was about 2% of the total concentration of the seven indicator PCBs. Relatively high concentration of mono-ortho and di-ortho PCBs in fat samples of livestock products may be calculated with the concentration of coplanar PCBs that can be usually determined on a sequential procedure with dioxin analysis. Therefore, the relationship of the amounts between seven indicator PCBs and three coplanar PCBs may be useful to derive the composition and level of contaminants in beef, pork, and chicken. 相似文献
587.
Nonylphenols were determined from the water, suspended particle, and sediment samples taken from the Lake Shihwa in Korea and its surrounding creeks flowing through municipal and industrial areas, and into the lake. The nonylphenols were detected at the concentration ranges of 0.0-41.3 microg/l, 0.0-116.6 and 0.3-31.7 mg/kg in water, suspended particle and sediment samples respectively. The contamination levels of nonylphenols were increased along the down stream. Considerably high levels of nonylphenols were found at the industrial area compared to the municipal area. No remarkable differences were found between the isomer patterns of nonylphenols for the sample matrices of each sampling site, i.e. water, suspended solids and sediment. Strong correlations between water and sediment with 10(5.2) of the mean partition coefficient (Koc ) were observed. These indicate that most of nonylphenols came from industrial wastewater at high level. It is thought that the water quality of the Lake Shihwa is affected greatly by industrial environments surrounding. 相似文献
588.
Partitioning of naphthalene to anionic surfactants adsorbed on alumina in the aqueous phase was studied for immobilization of the contaminant in the subsurface. Three anionic surfactants with different molecular structures were used: a conventional (sodium dodecylbenzene sulfonate, SDDBS), a gemini (dialkylated disulfonated diphenyl oxide with alkyl chain length of 12, DADS-C12), and a dianionic (monoalkylated disulfonated diphenyl oxide with alkyl chain length of 12, MADS-C12). Sorption of the surfactants onto alumina was studied in a series of batch experiments and the effectiveness of the adsorbed surfactants onto aluminum oxide as a sorptive phase for naphthalene was compared. 相似文献
589.
Adsorption of a gemini surfactant that has two monomers and a spacer in a molecule (dialkylated disulfonated diphenyl oxide with alkyl chain lengths of twelve, DADS-C12) onto positively-charged aluminum oxide in water was studied and compared with a single-monomer anionic surfactant (sodium dodecylbenzene sulfonate, SDDBS). More mass of the gemini surfactant was adsorbed than the conventional single-monomer SDDBS. Fewer moles of the first were bound to the substrate than the second indicating that larger molecular structure of the gemini surfactant does not hinder the sorption. Both surfactants followed similar sorption mechanisms, however, stronger hydrophobic interactions were shown in the bilayer formation of the adsorbed gemini surfactant. 相似文献
590.
Chung Yong-Seung Kim Hak-Sung Park Kie-Hyon Dulam Jugder Gao Tao 《Water, Air, & Soil Pollution: Focus》2005,5(3-6):15-35
A joint monitoring of dust-storms that occurred in East Asia from March until May 2003 has been carried. Our discussions include
dust-storm observations in the source areas of China and Mongolia, and measurements with satellites and ground monitors in
central Korea. Differences were found in the definition and measurement of dust-storms. Over the source area of Mongolia there
were 6 dusty days in March, 18 days in April, and 10 dusty days in May. In Inner Mongolia of northern China there were 4 dust-storms
with 14 dusty days observed over the three months. In central Korea, a sink area, there were 4 cases of weak dust-storm and
17 dusty days in the spring of 2003. The highest PM10 value was 607 μgm−3 and PM 2.3 was 149 μgm−3, respectively. These observations identify the growing need for further universal observation practices and dust-storm reporting
in future.
Observations indicated that snow covered the central part of the Gobi Desert, near the boundary of China and Mongolia, from
December until mid-March. This is in contrast to other years when the Gobi was relatively wet, producing unfavourable conditions
for the formation of intense dust-storms. In addition, the very strong winds associated with intense cyclones and anticyclones
were not apparent and the systems shifted northward during the spring. As a result, the frequency and intensity of observed
dust-storms in 2003 in this region were very low. This confirms that there is variability in the frequency of dust-storm formation
due to the current process of desertification and climate change. 相似文献