加油站分散式油气回收工艺的研究

针对加油站油品蒸发损耗及降耗工艺应用问题,提出新的油库与加油站＂分散式油气回收工艺＂,建立了其经济模型,推导出系统的计算公式,并就某城市加油站分散式油气回收系统进行了具体的经济评价计算。并将计算结果同传统的加油站油气回收系统的经济计算结果进行了比较,比较结果表明：分散式油气回收工艺较传统的加油站油气回收系统具有更好的经...     

一种计量青鳉鱼胸鳍和尾鳍摆动频率和幅值的计算机视觉算法

青鳉鱼在饮用水安全领域具有很高的应用价值,其鱼鳍的活动状态可以反映水质的污染状况。但由于技术条件的限制,传统的方法无法实时而有效地提取到这些特征。针对这个问题,提出了一种可以高效识别并测量青鳉鱼胸、尾鳍摆动频率和幅值的计算机视觉算法。其中,为了快速地提取到这2个细节,自动阈值分割、帧差法、背景差分法、重心法、图像卷积和骨架细化等耗时极短的图像处理方法被应用到这项研究当中。初步试验显示这种算法在应用过程中是高效而可行的。它可以被广泛地应用到水环境监测领域,如研究有毒物质对青鳉鱼行为特性的影响和评估水环境的危险程度。     

基于有机污染物生物有效性的土壤环境质量基准的探讨

我国的土壤污染日益严重,由于污染物对土壤生物产生的毒性效应与其生物有效态含量相关,以污染物总量为指标的土壤环境质量标准已无法满足当前土壤管理的需求,亟需开展以生物有效性为基础的土壤环境质量基准的研究工作。目前对土壤中重金属的生物有效性的研究较为深入,但是针对有机污染物的土壤生物有效性研究相对匮乏。本研究综述了有机污染物在土壤中的结构形态、吸附吸收和迁移转化,以及影响土壤中有机污染物生物有效性的关键因素。从我国有机污染物的污染现状、土壤类型分布情况,以及物种选择3个方面对基于生物有效性的土壤环境质量标准/基准的制定进行探讨,以期为我国根据国情制定适合本土特征的生态安全土壤质量标准提供借鉴。     

Nanostructured semiconducting materials for efficient hydrogen generation

Massive production of hydrogen by water decomposition triggered by a solar light active photocatalyst is a major objective in chemistry and a promising avenue to overcome the global energy crisis. The development of efficient, stable, economically viable and eco-friendly photocatalysts for hydrogen production is a challenging task. This article reviews the use of nanocomposite in three combinations: metal oxide–metal oxide semiconductor, metal–metal oxide semiconductor and metal chalcogenide–metal oxide core–shell nanostructures. These core–shell structures occur in two forms: a simple form where the photocatalyst is either in the core or the shell or in a more complex system where the core–shell structure comprises a co-catalyst deposited on a semiconducting material. We discuss the design, synthesis and development of semiconductor-based nanocomposite photocatalysts for hydrogen production. The major points are the role of catalytic active sites, the chemical nature of sacrificial agents, the effect of light sources, the variable light intensity and the energy efficiency calculation. For TiO₂-based nanocomposites, the metal oxide or metal co-catalyst loading of 1.0–3.0 wt% was optimal. TiO₂ nanotube–CuO hybrid nanocomposites produce 1,14,000 µmol h^?1 \({\text{g}}^{ - 1}_{\text{cat}}\), whereas TiO₂/Au nanocomposites display 1,60,000 µmol h^?1 \({\text{g}}^{ - 1}_{\text{cat}}\). For core–shell catalysts, a shell thickness of 2–20 nm was found for the best activity, and its performance is as follows: (a) CdS–NiO system produces around 19,949 µmol h^?1 \({\text{g}}^{ - 1}_{\text{cat}}\) and (b) CuO–Cr₂O₃ as co-catalyst immobilized on TiO₂ system produces around 82,390 µmol h^?1 \({\text{g}}^{ - 1}_{\text{cat}}\).     

稀土湿法冶炼废水处理与资源化研究

对某稀土湿法冶炼工艺进行了以清洁生产为核心的技改方案研究,在清洁工艺设计的基础上,通过工艺原理分析和试验,说明其革新工艺的经济有效性;从酸浸废液中年回收硫酸亚铁３０００ｔ,从碱转废液中年回收硫酸钠３０００ｔ;从废水回收冰晶石,氟回收８６％;     

Studies on degradation of 14C-chlorpyrifos in the marine environment.

Degradation of 14C-chlorpyrifos was studied in a marine ecosystem for 60 days and in marine sediment under moist and flooded conditions using a continuous flow system allowing a total 14C-mass balance for a period of 40 days. In the marine ecosystem, 14C-chlorpyrifos underwent rapid degradation and very little (1-2%) 14C-residues of the applied activity were detected after two months in sediments. Clams were major component of the ecosystem and played a significant role in degradation of the insecticide. In the continuous flow system chlorpyrifos did not undergo substantial mineralization. Volatilization accounted for 0.8-1% loss during first ten days of application. The amounts of extractable 14C-activity were higher in flooded sediments than in moist sediment. More bound residues were formed under moist conditions. TCP (3,5,6-trichloro-2-pyridinol) was the major degradation product formed under both moist and flooded conditions, its formation being higher in the latter conditions. These studies underline the role of clams in degradation of chlorpyrifos and lack of microbial degradation. In absence of clams, chlorpyrifos underwent abiotic degradation in marine sediment with formation of bound residues.     

芳香族化合物的生物降解途径

分析了以苯、甲苯、萘和联苯为代表的芳香族化合物的生物降解途径,发现其共同点都是经过两步加氧酶作用生成二醇,最后再开环;介绍了苯、甲苯、萘和联苯这几种芳香族化合物分解酶的组分、相对分子质量及其辅基。     

14C-生物碱在模拟水环境中暴露行为的研究

本文采用同位素示踪技术和室内模拟微生境研究了“C-盐酸脱廷胡索碱在好氧、厌氧水环境中的行为;对水、绿藻、溞及底泥中的残留量进行了分析:并用TLC分离出了水体及底泥中的转化产物,结果表明,该生物碱进入水环境后向底泥相转移是其主要迁移途径,最终在底泥上的残留量占85％以上,光及底泥微生物对该生物碱的转化起了一定作用。     

我国生态保护与建设支出账户框架构建研究

生态保护与建设是我国生态文明建设的重要任务,生态保护与建设支出账户核算是环境经济核算的重要内容,但我国目前尚未开展系统的生态保护与建设支出核算。本文首先梳理了生态保护与建设支出核算的国际经验,指出我国生态保护与建设支出账户核算面临统计口径不完善、统计体系尚未建立、统计主体和对象仍不完整、统计数据呈部门化和分散化等问题。在此基础上,本文从生态保护与建设支出主体、支出分类、支出资金来源等方面初步构建了支出账户核算体系,并以2013年为例进行了初步估算。结果表明,我国财政资金用于生态保护与建设的支出总量不足,仅占当年GDP的0.25%。为推动生态保护与建设支出账户核算工作,建议应从预算科目、统计口径、统计主体、统计对象等方面不断完善生态保护与建设统计体系,加快推进生态保护与建设支出账户的构建与核算,并争取尽快纳入国民经济核算体系,以推进生态文明体制改革与制度建设的进程,促进我国生态保护与经济社会的协调发展。