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81.
82.
Rodrigues S Antunes SC Brandão FP Castro BB Gonçalves F Nunes B 《Journal of environmental monitoring : JEM》2012,14(6):1638-1644
The presence of pharmaceutical residues in the aquatic environment has recently received great attention, as potential adverse effects may arise from their presence. Inhibition of cholinesterases (ChE) has been widely used as an environmental biomarker of exposure to organophosphates (OP) and carbamate (CB) pesticides. However, other widespread anthropogenic contaminants - including pharmaceutical drugs - can exert toxic effects through ChE inhibition. Studies with aquatic species have shown that inhibition of ChE is associated with behavioral changes. Bearing this in mind, this work aimed to study the effects on individual behavior and acetylcholinesterase (AChE) activity of selected tissues of Lepomis gibbosus, after exposure to the anticholinesterasic drugs neostigmine and pyridostigmine. Results revealed that neostigmine significantly decreased the activity of AChE in the head (LOEC = 100 mg L(-1)), but not in dorsal muscle. On the other hand, pyridostigmine significantly decreased the activity of AChE in both the head (LOEC = 0.001 mg L(-1)) and dorsal muscle homogenates (LOEC = 100 mg L(-1)). The impairment of this enzymatic form was attained at ecologically relevant concentrations (in the case of pyridostigmine, for head AChE), which is an interesting finding, specially considering that these toxic effects occurred for a pharmaceutical compound. Contrarily, there were no significant differences in the behavior of L. gibbosus in any parameter, for neither drug. These results suggest that the behavioral parameters analyzed (scototaxis and lethargy) in L. gibbosus could not be regarded as suitable markers to assess the effects of drugs such as neostigmine and pyridostigmine. In contrast, the pattern of response elicited by cholinesterasic inhibition showed the usefulness of this toxicological parameter for the assessment of pharmaceuticals in the environment, namely anticholinesterasics. 相似文献
83.
Hg transfer from contaminated soils to plants and animals 总被引:1,自引:0,他引:1
S. M. Rodrigues B. Henriques A. T. Reis A. C. Duarte E. Pereira P. F. A. M. R?mkens 《Environmental Chemistry Letters》2012,10(1):61-67
Understanding the transfer of mercury (Hg) from soil to crops is crucial due to Hg toxicity and Hg occurrence in terrestrial
systems. Previous research has shown that available Hg in soils contributes to plant Hg levels. Plant Hg concentrations are
related to soil conditions and plant characteristics. Mechanistic models describing such soil–plant interactions are however
difficult to quantify. Here we performed a field study in agricultural, mining and industrial areas in Portugal to evaluate
potential food chain risks. The uptake of Hg by Italian ryegrass, ryegrass, orchard grass, collard greens and rye was measured
to calculate daily intakes (DI) of Hg for cows and sheep grazing. A total of 136 soil samples and 129 plant samples were analysed.
Results show that total Hg concentrations ranged from 0.01 to 98 mg kg−1 in soils; 0.01–5.4 mg kg−1 in shoots and 0.01–42 mg kg−1 in roots. Calculated DI ranged from 0.18 to 132 mg d−1 for cows, and from 0.028 to 23 mg d−1 for sheep. In 27 grassland sites, daily intakes exceeded the acceptable daily intake of both cows and sheep in view of food
safety considering Hg in animal kidneys evidencing potential risks to human health. The transfer of Hg from soil to crops
was described using empirical Freundlich-type functions. For ryegrass, orchard grass and collard greens, the soil-to-root
or soil-to-shoot transfer of Hg appeared to be controlled by the total soil Hg concentration and levels of Alox and Feox. Empirical functions allowed us to obtain realistic estimates of Hg levels in crops and can be used as an alternative to
mechanistic models when evaluating food chain risks of Hg contamination in agricultural soils. 相似文献
84.
85.
Bigliardi Ana Paula Fernandes Caroline Lopes Feijo Pinto Edlaine Acosta dos Santos Marina Garcia Edariane Menestrino Baisch Paulo Roberto Martins Soares Maria Cristina Flores Muccillo-Baisch Ana Luíza da Silva Júnior Flavio Manoel Rodrigues 《Environmental science and pollution research international》2021,28(2):1409-1416
Environmental Science and Pollution Research - Coal extraction and processing generate environmental contamination, which has several negative impacts on human health. Hematological and biochemical... 相似文献
86.
Pedro Gon?alves Rodrigues Lu��s Moreira Gon?alves Paulo Jorge Magalh?es Jo?o Grosso Pacheco Jos�� Ant��nio Rodrigues Aquiles Ara��jo Barros 《Environmental Chemistry Letters》2011,9(3):405-410
An major research area in environmental chemistry is the development of methods for the analysis of biomarkers. Metallothioneins
are used as biomarkers in studies of heavy metals exposure in water, because metallothioneins are synthesized and accumulated
when organisms are exposed to toxic concentrations of pollutants. In this work, simple and sensitive voltammetric methods
were developed for metallothionein and copper (II) determinations in fish liver Lepomis gibbosus. Both analytical methodologies were optimized and applied to samples extracted from individuals previously submitted to sub-lethal
toxicological trials with copper sulphate (CuSO4) and cadmium chloride (CdCl2). The obtained results showed that both methods are very precise, sensitive, and involve simple sample preparation processes.
Moreover, metallothioneins showed better correlation with the toxic exposure than Cu2+. To the best of our knowledge, this is the first time that hepatic metallothioneins and Cu2+ contents are voltammetrically determined in order to be compared in their function as heavy metal biological indicators. 相似文献
87.
da Silveira RP Rodrigues AP Santelli RE Cordeiro RC Bidone ED 《Environmental monitoring and assessment》2011,181(1-4):165-173
This study addressed the identification and monitoring of pollution sources of terrestrial origin in rivers (domestic sewage and industrial effluents) and critical fluvial segments in highly polluted environments under tidal influence (mixing marine and continental sources) from Guanabara Bay Basin, Rio de Janeiro, Brazil. The mass balance of contaminants was determined in conditions of continuous flow (low tide) during dry season (lower dilution capability). The results allowed the evaluation of the potential of contaminant mass generation by the different river segments and the estimation of their natural and anthropogenic components. The water quality of Igua?ú and Sarapuí Rivers were evaluated for metals and biochemical oxygen demand. The method gave an excellent response, including the possibility of sources identification and contaminated river segments ranking. The approach also offers fast execution and data interpretation, being highly efficient. 相似文献
88.
Nogueira L Rodrigues AC Trídico CP Fossa CE de Almeida EA 《Environmental monitoring and assessment》2011,180(1-4):243-255
Considering that diesel oil is one of the most common aquatic contaminants, we compare the oxidative stress between two species of fish with different habitats (Pterygoplichthys anisitsi, benthic and Oreochromis niloticus, nektonic) exposed to diesel oil. Malondialdehyde concentrations (MDA) and the activities of ethoxyresorufin-O-deethylase (EROD), glutathione S-transferase (GST), catalase (CAT), superoxide dismutase (SOD), and glutathione peroxidase were all analyzed in the fishes' livers and gills after 2 and 7 days of exposure to different concentrations of diesel (0.1 and 0.5 mL/L). In the tilapia, MDA levels and the activities of EROD and GST activity in the liver, as well as MDA levels and the activities of GST and SOD in the gill had statistically significant differences between the treatments and between the times of exposure. For the catfish, the same occurred in the case of MDA, EROD, and SOD in the liver and in CAT and SOD in the gills. There were significant differences in the enzyme activity and lipid peroxidation between the species. Although the activity of most enzymes seemed to be more expressive and responsive to diesel in O. niloticus, diesel oil also caused significant effects on oxidative stress parameters in P. anisitsi, even though this species is benthic and thus has less access to insoluble fractions of diesel oil. Therefore, both species can be used as sentinel organisms in environmental biomonitoring of diesel contamination. 相似文献
89.
Distinct symbiont lineages in three thyasirid species (Bivalvia: Thyasiridae) from the eastern Atlantic and Mediterranean Sea 总被引:1,自引:1,他引:0
Thyasiridae are one of the less studied groups of chemosymbiotic bivalves. Here, we investigated symbioses in three different
thyasirid species collected at three cold seeps from the Atlantic and Mediterranean. Phylogenetic analysis of bacterial 16S
ribosomal RNA gene sequences demonstrated that each thyasirid species harbours a single phylotype of symbiont that belongs
to a distinct lineage of putative sulphur-oxidizing Gammaproteobacteria. This result is confirmed by other marker genes (encoding 23S rRNA and APS reductase) and fluorescence in situ hybridization.
This work highlights the diversity of bacteria involved in symbiosis with thyasirids and underlines the relevance of this
group as a target for future symbiosis studies. 相似文献
90.
Jonatas S. RomanoMariane S. Miranda Meiri B.R. OliveiraFlávio A. Rodrigues 《Journal of Cleaner Production》2011,19(11):1224-1228
Metals can be stabilized into cement matrix by solidification/stabilization process. Rice hull is an agricultural residue containing about 10-20% (weight) of silica. It can be used to synthesize β-Ca2SiO4, an important component of Portland cement. Furthermore it is possible to prepare β-Ca2SiO4 doped with heavy metals. Here we describe the synthesis of β-Ca2SiO4 doped with zinc and the behavior of mortars prepared using this material. Products were analyzed by X-ray diffraction, differential thermal analysis and scanning electron microscopy coupled to energy-dispersive spectroscopy. The maximum amount of zinc that can be inserted into β-Ca2SiO4, without affecting the crystalline structure, is limited to 2% (molar basis). In comparison with conventional mortars, zinc-modified mortars show a similar behavior, regarding porosity, resistance to acidic attack and compressive strength. The synthesis of β-Ca2SiO4 doped with zinc presents a new possibility for safety enhancement in solidification/stabilization processes. 相似文献