High velocity fabric filtration for control of coal-fired boilers

As a follow-up to a pilot study, a full scale investigation of applying high velocity fabric filtration to coal-fired boiler fly ash control was conducted. Two filter systems were separately applied to two 60,000 lb/h coal-fired boilers. Performance evaluations conducted over the course of a year included total mass removal efficiency and fractional efficiencies. One filtration system employed Teflon felt as the filter media while the second system employed Gore-Tex, a Polytetrofluorethylene (PTFE) laminate on PTFE woven backing. During the course of the year, a limited number of glass felt and woven glass bags were introduced into the house containing Gore-Tex. As a separate option, the second system was outfitted entirely with woven glass bags. Preliminary results indicate acceptable performance at air-to-cloth ratio of 6 to 1. Future plans call for utilizing one of the baghouse systems for SO₂ removal.     

Confined placental mosaicism for trisomy 14 and maternal uniparental disomy in association with elevated second trimester maternal serum human chorionic gonadotrophin and third trimester fetal growth restriction

A case of confined placental mosaicism (CPM) and maternal uniparental isodisomy 14 identified after placental karyotype revealed trisomy 14 in a newborn with intrauterine growth restriction (IUGR) and minor dysmorphic features is reported. During the second trimester of the pregnancy, multiple marker screening revealed an increased risk for Down syndrome of >1 in 10. The maternal serum human chorionic gonadotrophin (MShCG) was markedly elevated at 4.19 MoM. Amniocentesis revealed a normal 46,XX karyotype. Fetal growth restriction has been associated with elevated MShCG and placental aneuploidy with CPM for chromosomes 2, 7, 9 and 16. The present case of CPM for chromosome 14 was also associated with fetal growth restriction and elevated second trimester MShCG, suggesting a common link. Further studies need to be done to determine if indeed elevation of second trimester MShCG is associated with increased risk of CPM. The present case again demonstrates the need to perform placental karyotype in unexplained fetal growth restriction. Copyright © 2001 John Wiley & Sons, Ltd.     

WATER PROBLEMS IN THE INDUS FOOD MACHINE1

ABSTRACT: Examples are drawn from the Indus Basin to explain why on-farm water management problems restrict the output of agricultural products in many LDC's. Data is presented to illustrate the low level of water management knowledge of both the farmers and the current extension agents. Examples of the level of corruption and its effect on the operating system are illustrated. Several requirements that must be met before a large-scale irrigation scheme will actually increase the welfare of LDC's farmers are presented.     

Prediction of minimum ignition energy of aerosols using flame kernel modeling combined with flame front propagation theory

Flammable aerosols have created many fire and explosion hazards in the process industry, but the flammability of aerosols has not been fully understood. The minimum ignition energy has been widely used as an indicator for flammability of combustible mixtures, but the amount of experimental data on the minimum ignition energy of aerosols is very limited. In this work, the minimum ignition energy of tetralin aerosols is predicted using an integrated model. The model applies the flame front propagation theory in aerosol systems to the growth of the flame kernel, which was created during the spark discharge in the ignition process. The aerosol minimum ignition energy was defined as the minimum level of energy in the initial flame kernel to maintain the kernel temperature above the minimum ignition temperature of 1073 K specific for tetralin aerosols during the kernel growth. The minimum ignition energy obtained in the model is influenced by the fuel-air equivalence ratio and the size of the aerosol droplets. For tetralin aerosols of 40 μm diameter, E_min decreases significantly from 0.32 mJ to 4.3 × 10 e⁻³ mJ when the equivalence ratio rises from 0.57 to 1.0. For tetralin aerosols of 0.57 equivalence ratio, E_min increases from as 0.09 mJ to 0.32 mJ when the droplet diameter rises from 10 μm to 60 μm. The trends are in agreement with previous experimental observations. The method used in current work has the potential to prediction of the minimum ignition energy of aerosol.     

A simplified steady-state model for air,water and steam curtains

Curtain mitigation systems are modeled here since they have experimentally shown their efficiency in reducing the concentration of certain toxic gases within dense gas clouds. Air, water and steam are analyzed in a model as the physical barriers to decrease the gas concentration. The model, developed for a steady-state mitigation process, is based on the mass, energy and momentum conservation laws. Concentration estimations during the dispersion before and after the mitigation are performed with a SLAB type model. A sensitivity analysis for each model is given to detect which variables have bigger effects. A release of chlorine is used as an example and the results are calculated in a prototype developed in Visual C++, where the model is solved using the Runge–Kutta 4th order method. The results include the effects of composition, speed, temperature and height of the releasing point as well as a comparison with CFD simulations. The proposed model is simplified and it cannot reproduce eddy effects but it is fast and robust enough. The model provides a set of equations that can be used in numerical problems where explicit derivatives are required, e.g. optimizations procedures.     

Inherently safer reactors: Improved efficiency of 3-picoline N-oxidation in the temperature range 110–125 °C

Alkylpyridine N-oxides are important intermediates in the pharmaceutical and agrochemicals industries. The N-oxides are produced via the homogeneously catalyzed oxidation of the respective alkylpyridines using a 50% excess of hydrogen peroxide. The competitive hydrogen peroxide decomposition produces oxygen in the flammable environment of alkylpyridines and thus forms a key hazard for this reaction. In this work, the N-oxidation was performed under pressure in the temperature range of 110–125 °C with different catalyst concentrations. It was shown that temperature had an undisputable positive effect on the N-oxidation efficiency. The accurate measurement of the pressure rise due to decomposition was difficult. However, only 5% of the added H₂O₂ decomposed when stoichiometric quantities were employed, even in the temperature of 110 °C. The N-oxidation was very efficient, even when the lowest concentration of catalyst employed in this study was used.