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21.
The contamination and distribution of organochlorinated compounds were considered in three crustacean species (edible crab, Cancer pagurus; spider crab, Maja brachydactyla; velvet swimming crab, Necora puber) from five sites along the coasts of Brittany and Normandy (Western and North-Western France). PCBs (16 single congeners), pp'-DDE and HCB were measured in hepatopancreas, gonads and muscle: in all, 175 samples were analysed. The spider crab was the only species found in the five sampling sites, thus enabling comparison between areas. Specimens from Antifer were much more contaminated (summation operator 16 PCBs in hepatopancreas=2000-4000 ng g(-1) dry weight) than those from other sites (50-1000 ng g(-1) d.w.). Among all the three species, the spider crab appeared more contaminated by PCBs than the edible crab, by a factor 2-3, probably in relation with specific differences in their life cycle. There was no difference due to the gender of the species. Within the different analysed tissues, contamination levels increased from muscle to gonads and hepatopancreas in relation with the fat content. A very similar PCB composition was observed in all samples, PCB fingerprints being characterised by the relative importance of the more persistent PCB congeners: CB153, 138, 180, 187, and 118. Finally, these results were compared to recent food regulations first of maximum marker PCB intake and secondly of maximum dioxin-like PCB intake. By considering the muscle, all samples were far below the regulatory limits; for hepatopancreas and gonads, however, some samples were unfit for human consumption. 相似文献
22.
In studies of occupational risks, severity, which is a component of the estimation of every risk, appears as a multifaceted entity assessable according to numerous criteria. A method of measuring the degree of severity of the consequences of potentially dangerous events would be of undeniable value to organisations seeking to improve their understanding of the complexity of such events. The need to control severity is highlighted by scientifically acquired improvements in the understanding of occupational risks, by certain new regulatory obligations in Europe, and by some requirements in the financial management of organisations. We put forward a statistical way of integrating several constituent elements of severity and hence of determining a relevant, synthetic, one-dimensional index. This is achieved by means of principal component analysis (PCA), which is used here to calculate a resultant severity, as in some physical measurements. We also investigate how severity may be statistically modelled, with the aim of contributing to the quantitative assessment of occupational risks. The choice of parametric models is detailed and illustrated by the search for a suitable model for workplace accidents in an organisational setting. The practical value of modelling severity is two-fold. First, one is able to study the distribution of the numerical values of severity over a continuum (a theoretically infinite numerical set) rather than through a limited number of arbitrarily defined categories. Second, with a generally applicable parametric model, one can estimate the law of probability of a measurement of severity in a particular situation, notably recent or new. Lastly, the statistical concept of risk curve is defined and discussed. The goal is to incorporate the severity component into the risk assessment in the form of a probability law, thus circumventing the difficulties associated with an analysis of scenarios. 相似文献
23.
Yield and arsenate uptake of arbuscular mycorrhizal tomato colonized by Glomus mosseae BEG167 in As spiked soil under glasshouse conditions 总被引:1,自引:0,他引:1
A glasshouse pot experiment was conducted to study the effect of arbuscular mycorrhizal (AM) colonization by Glomus mosseae BEG167 on the yield and arsenate uptake of tomato plants in soil experimentally contaminated with five As levels (0, 25, 50, 75 and 150 mg kg(-1)). Mycorrhizal colonization (50-70% of root length) was little affected by As application and declined only in soil amended with 150 mg As kg(-1). Mycorrhizal colonization increased plant biomass at As application rates of 25, 50 and 75 mg kg(-1). Shoot As concentration increased with increasing As addition up to 50 mg kg(-1) but decreased with mycorrhizal colonization at As addition rates of 75 and 150 mg kg(-1). Shoot As uptake increased with mycorrhizal colonization at most As addition levels studied, but tended to decrease with addition of 150 mg As kg(-1). Total P uptake by mycorrhizal plants was elevated at As rates of 25, 50 and 75 mg kg(-1), and more P was allocated to the roots of mycorrhizal plants. Mycorrhizal plants had higher shoot and root P/As ratios at higher As application rates than did non-mycorrhizal controls. The soil of inoculated treatments had higher available As than uninoculated controls, and higher pH values at As addition levels of 25, 50 and 75 mg kg(-1). Mycorrhizal colonization may have increased plant resistance to potential As toxicity at the highest level of As contamination studied. Mycorrhizal tomato plants may have potential for phytoextraction of As from moderately contaminated soils or phytostabilization of more highly polluted sites. 相似文献
24.
The activities of calcium-activated ATPase (Ca2+-ATPase) and calcium magnesium-activated ATPase (Ca2+-Mg2+-ATPase) in the shell gland, and concentrations of 17beta-estradiol (E2) and progesterone in serum were monitored, respectively, from hens orally dosed with tri-o-cresyl phosphate (TOCP) (750 mg/kg). Treated birds were monitored daily for laying and development of delayed neurotoxicity, and activities of Ca2+-ATPase and Ca2+-Mg2+-ATPase were measured at 7 and 10 days after dosing. TOCP-treated birds manifested motor deficit by 7-9 days postdosing, while hens administered vehicle exhibited no signs of delayed neurotoxicity. Ca2+-ATPase and Ca2+-Mg2+-ATPase activities of shell glands from TOCP-dosed hens were not significantly affected (P > 0.05). The serum E2 concentration was significantly reduced in TOCP-treated hens (P < 0.01); however, progesterone levels were unaffected. 相似文献
25.
Replacement of H2O2 by O2 in Fenton and photo-Fenton reactions 总被引:8,自引:0,他引:8
The consumption of oxygen during the degradation of aniline by Fenton and photo-Fenton reactions is studied. The effect that parameters like aniline, Fe(II) and H2O2 initial concentration, pH, temperature and O2 flow rate have on the ratio O2 consumed/H2O2 consumed is examined. The determination of those combinations of experimental conditions for which an effective partial replacement of H2O2 by O2 as electron acceptor takes place is investigated. The results show that this replacement takes place in a variable extent, but the presence of H2O2 is necessary along the reaction, and the maximum consumption of O2 only takes place when the ratio amount of aniline mineralized vs. initial aniline concentration is minimal. 相似文献
26.
27.
Experimental results from an isothermal laminar flow reactor at atmospheric pressure are presented on the chemical composition in the post-oxidative region of two sooting fuel-rich pre-mixed mixtures diluted in nitrogen. A base case composed of n-heptane and O2 in N2 at 1425 K with a C/O of 2.85 was perturbed by substituting 10% of the carbon in n-heptane with carbon as CH4. While these changes would intuitively reduce aromatics and soot formation by increasing H2 and decreasing C2H2 concentrations, we observe the opposite. The concentrations of individual aromatic species are observed to actually increase by up to 50% and the soot yield increases by 80%. 相似文献
28.
Mlynek Franz Himmelsbach Markus Buchberger Wolfgang Klampfl Christian W. 《Environmental science and pollution research international》2021,28(42):59382-59390
Environmental Science and Pollution Research - The aim of this study was to investigate the uptake of four beta-blockers by the model plant Lepidium sativum (garden cress) and their possible... 相似文献
29.
Nguyen Quoc Hung Tran Anh T. K. Hoang Nhung T. T. Tran Yen T. H. Nguyen Phu X. Pham Thi Thuy Nguyen Manh Khai Van der Bruggen Bart 《Environmental science and pollution research international》2022,29(28):42074-42089
Environmental Science and Pollution Research - Single-use plastic waste is gradually considered a potential material for circular economy. Ion exchange resin obtained from polystyrene waste by... 相似文献
30.
Perennial ryegrass plants (Lolium perenne L.) were exposed in "Closed-Top Chambers" to different ozone concentrations and to charcoal filtered ambient air to study the effect of ozone on the development of pollen. Ozone at ambient (65 nl l(-1), 8h) and elevated (110 nl l(-1), 4h) concentrations affected the maturing of pollen by inhibiting starch accumulation in pollen throughout the anther. Affected pollen persisted in the vacuolated state while normal pollen in the same anther were filled with amyloplasts. The percentage of underdeveloped pollen-determined in transversal sections-was significantly higher in exposed plants than in plants grown in filtered air. Results indicate that ozone stress was responsible for the disrupted development of pollen in L. perenne. 相似文献