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53.
Xianbing Liu Can Wang Tomohiro Shishime Tetsuro Fujitsuka 《Journal of Cleaner Production》2010,18(10-11):1001-1008
This paper develops an analytical framework based on the reasoned action theory and discusses the environmental activism (EA) of residents living close to the polluting companies. The data was collected by a questionnaire survey conducted in August of 2009 in Suzhou city of Jiangsu Province, China, which successfully obtained a total of 343 valid responses. The survey suggests that the residents are reluctant to act against their neighboring polluters. Nearly 10% respondents have never taken any action against the polluters, and the occasional EA participators account for 66.2% of the total. The items of EA, which require the residents to directly communicate with the governments or polluters, achieve very low ratios of participations (with a range of 5–25%). The path analysis confirms that there are large influences of certain attitudinal components on EA involvement. Understanding of corporate environmental information significantly determines the resident’s intention of EA practices. The residents have an obvious tendency to act collectively against the polluters. An essential message of this study is that the strategy of corporate environmental information disclosure may effectively increase the resident’s readiness of EA participation. The government shall responsively support the residents’ EA efforts since successful environmental protests will greatly convince them to jointly act against their neighboring polluters. 相似文献
54.
Brominated flame retardants and heavy metals in automobile shredder residue (ASR) and their behavior in the melting process 总被引:3,自引:3,他引:0
Morihiro Osada Nobuhiro Tanigaki Shin Takahashi Shin-ichi Sakai 《Journal of Material Cycles and Waste Management》2008,10(2):93-101
The End-of-life Vehicles Recycling Act went into effect on January 1, 2005, in Japan and requires the proper treatment of
airbags, chlorofluorocarbons (CFCs), and automobile shredder residue (ASR). The need for optimal treatment and recycling of
ASR, in particular, has been increasing year after year because ASR is regarded as being difficult to treat. Dioxin-related
compounds, brominated flame retardants (BFRs), heavy metals, chlorine and organotin compounds are all present in high concentrations
in ASR. The authors conducted ASR melting treatment tests using a 10-tons/day-scale direct melting system (DMS), which employs
shaft-type gasification and melting technology. The results obtained showed that dioxin-related compounds and BFRs were decomposed
by this melting treatment. The high-temperature reducing atmosphere in the melting furnace moved volatile heavy metals such
as lead and zinc into the fly ash where they were distributed at a rate of more than 90% of the input amount. This treatment
was also found to be effective in the decomposition of organotin, with a rate of decomposition higher than 99.996% of the
input amount. Via the recovery of heavy metals concentrated in the fly ash, all the products discharged from this treatment
system were utilized effectively for the complete realization of an ASR recycling system that requires no final disposal sites. 相似文献
55.
An intercalibration study on organobromine compounds has been conducted to evaluate the accuracy and reliability in the analysis of brominated flame retardants (BFRs) such as polybrominated diphenyl ethers (PBDEs) and their related compounds like polybrominated and monobromo-polychlorinated dibenzodioxins and -furans (PBDDs/DFs, MoBPCDDs/DFs). This paper reports the results for these compounds in 'Mixed Standard Solutions' and 'Air-Dried Sediment'. The relative standard deviations (RSDs) for PBDEs, PBDDs/DFs and MoBPCDDs/DFs in mixed standard solutions ranged from 9% to 24%, 4% to 20% and 8% to 27%, respectively. The results of this study are better than those reported in earlier international interlaboratory studies due to general improvement in analytical methods and an increasing number of available authentic standards, particularly for PBDEs. In the analysis for higher brominated compounds such as octabromodibenzodioxin, the participants were advised to optimize the calibration curves befitting the range of concentrations found in samples because variation of relative response factors was noted. The results for 'Air-Dried Sediment' were also reasonable with RSDs from 10% to 38% for PBDEs, 8% to 38% for PBDDs/DFs and 17% to 36% for MoBPCDDs/DFs. In the sediment sample, possible errors in the sample pretreatment and/or interference by other compounds/impurities were indicated. The concentrations of pentabromodiphenylether, BDE100, varied more than the other PBDE isomers due to its poor separation in some chromatographic conditions. In addition, interference by PBDEs was observed in the analysis for PBDFs. Potential degradation/secondary formulation of PBDEs and PBDFs during the Soxhlet extraction were suggested when copper powder was added into the sediment samples. Inspite of these observations, the results in this study are better than those reported in other interlaboratory studies due to the advice given to participants for improving the results. Compared with the results for PCDDs/DFs (5-23% RSDs) and Co-PCBs (6-24% RSDs), the RSDs for most of the organobromine compounds were high, indicating an immature QA/QC approach for the analysis of PBDEs and related compounds in comparison to common chlorinated dioxins. 相似文献
56.
Leaching characteristics of polybrominated diphenyl ethers (PBDEs) from flame-retardant plastics 总被引:1,自引:0,他引:1
To investigate the effect of leachant on the leachability of polybrominated diphenyl ethers (PBDEs), we determined the leaching concentrations of PBDEs from flame-retardant plastic samples (TV housings and raw materials before molding processing) that are regarded as a source of PBDEs in landfill sites. The leachants used were distilled water, 20% methanol solution, and dissolved humic solution (DHS) of 1000 mg/l based on organic carbon. The leaching test conditions were a liquid-to-solid ratio of 100:1, and a contact period of five days, with twice-daily agitation in a temperature-controlled room of 30 degrees C without pH or ionic strength control. The leaching concentrations of PBDEs increased with increased content, and were found to be remarkably enhanced when methanol and DHS were used instead of distilled water. The enhancement of leachability in the presence of the latter was attributed to the cosolvency effect, and complex formations between the PBDEs and dissolved humic matter (DHM). PBDE concentrations in the leachate obtained from the leaching test and an actual landfill site revealed a significant presence of congeners below heptabromodiphenyl ethers (H7BDEs), detected in the leachate of the actual landfill, while significant amounts of nonabromodiphenyl ethers (N9BDEs) and decabromodiphenyl ether (D10BDE) were detected in the leachate of the leaching test. 相似文献
57.
Strong adsorption of DNA molecules on humic acids 总被引:1,自引:0,他引:1
Kazutoshi Saeki Yasutaka Ihyo Masao Sakai Takashi Kunito 《Environmental Chemistry Letters》2011,9(4):505-509
Analysing soil microbial communities is often hampered by DNA adsorption on soil organic compounds such as humic acids. However
the role of humic acids in DNA adsorption and stability in soils remains controversial. To characterize DNA–humic acid interactions,
we studied DNA adsorption on two commercially available humic acids and a soil humic acid extracted from an Andosol. Desorption
of the adsorbed DNA using 4 different solutions—distilled water, 0.1 M NaCl, 0.1 M sodium phosphate buffer (pH 6.0), and 1%
sodium dodecyl sulfate solution—was also studied to understand the mechanism of DNA adsorption on humic acids. Here, we show
that humic acids play an important role in DNA adsorption to soils. DNA molecules were adsorbed on the humic acids, with adsorption
increasing proportionally with the DNA concentrations in the solution. The adsorption on all humic acid samples was fitted
with Freundlich equation, and the parameters obtained from the equation indicated a high affinity between the humic acids
and DNA molecules. The total amount of DNA desorbed by the 4 solutions was less than 2% of the total DNA adsorbed on all the
humic acids. The results demonstrate that DNA molecules are able to bind strongly to humic acids by ligand binding, hydrophobic
interaction, aggregation, or precipitation. 相似文献
58.
Mifuyu Ogawa Yuichi Yamaura Shin Abe Daisuke Hoshino Kazuhiko Hoshizaki Shigeo Iida Toshio Katsuki Takashi Masaki Kaoru Niiyama Satoshi Saito Takeshi Sakai Hisashi Sugita Hiroyuki Tanouchi Tatsuya Amano Hisatomo Taki Kimiko Okabe 《Environmental monitoring and assessment》2011,177(1-4):85-94
An alkaline comet assay and a micronucleus test were carried out on erythrocytes of the European chub, Squalius cephalus L., collected in spring and autumn in 2005 and 2006 at three sampling sites in River Sava, near Zagreb, Croatia. The results of comet assay showed the lowest genotoxic influence at the least polluted site, while higher DNA damage was observed at the polluted sites. Although the basal levels of DNA damage were elevated, a clear gradation of DNA damage was found due to pollution intensity in all sampling periods. The lowest cytogenetic damage as revealed by the micronucleus test (MNT) was observed as well at the least polluted site. High variations in MN frequency were observed between sampling periods, although the number of micronucleated erythrocytes was consistently the highest one at the polluted site. The comet assay as a biomarker of genotoxic effect exhibited higher sensitivity in discriminating the genotoxic capacity of studied polluted sites while the MNT was less sensitive. However, both tests should be used together in biomonitoring studies because they can reveal different aspects of DNA damage; comet assay, the early event of genotoxic exposure, and MNT, its final result as a mutagenic potential. 相似文献
59.
Effects of Long-Term Ungulate Exclusion and Recent Alien Species Control on the Preservation and Restoration of a Hawaiian Tropical Dry Forest 总被引:3,自引:0,他引:3
Robert J. Cabin Stephen G. Weller † David H. Lorence ‡ Tim W. Flynn ‡ Ann K. Sakai † Darren Sandquist § and Lisa J. Hadway‡ 《Conservation biology》2000,14(2):439-453
Abstract: Although the destruction of tropical rain forests receives much attention, tropical dry forests are in general far more threatened and endangered. Eliminating grazing ungulates is often considered a key first step toward protecting these ecosystems, but few studies have investigated the long-term effects of this technique. We examined the effects of ungulate exclusion from a 2.3-ha native dry-forest preserve on the island of Hawaii by comparing its present flora to the flora of an adjacent area subjected to continuous grazing since the preserve was fenced over 40 years ago. Relative to this adjacent area, the fenced preserve contained a more diverse flora with substantially greater coverage of native overstory and understory species. Until recently, however, regeneration of native canopy trees within the preserve appears to have been thwarted by a dominant herbaceous cover of alien fountain grass ( Pennisetum setaceum ) and predation by alien rodent species. Our results indicate that although ungulate exclusion may be a necessary and critical first step, it is not sufficient to adequately preserve and maintain Hawaii's remaining tropical dry forest remnants. Our recent efforts to control the dominant alien species within the fenced preserve suggest that this practice may facilitate both the regeneration of native species and the colonization and potential invasion of new alien plants. Comparisons of seedlings of the dominant native canopy tree Diospyros sandwicensis growing in sites both dominated by and free of fountain grass suggested that fountain grass inhibits Diospyros seedling growth and photosynthesis but may increase survival if seedlings are protected from ungulates. 相似文献
60.
Spatiotemporal recruitment patterns of scleractinian corals were investigated around Iriomote Island, Ryukyu Archipelago,
Japan, in relation to adult coral cover in 2005 and 2006. Although almost all corals were broadcasting spawners, the relationship
between recruitment and adult coral cover differed among coral families (Acroporidae, Poritidae, and Pocilloporidae), likely
due to differences in embryonic development time. For spawning pocilloporid corals, whose larvae develop relatively more rapidly,
recruitment was higher at sites where adult coral cover was higher. In contrast, recruitment was not related to adult coral
cover in acroporid and poritid corals, whose embryonic development times were relatively slow. Moreover, recruitment of acroporid
corals varied between years, and recruitment was greater at leeward compared to windward reefs for a few days after spawning.
These results suggest that embryonic development time and wind-driven surface currents affect larval dispersal and subsequent
recruitment patterns at a local scale. Based on embryonic development time, some spawning corals are more likely to have higher
rates of self-seeding than others. Our results predict that among spawning corals, local populations of acroporid and poritid
corals, whose larvae potentially disperse over long distances and recruit in neighboring reefs, are more resilient to local
disturbances than those of pocilloporid corals, whose recruitment relies upon local stock. 相似文献