金属负载型催化剂对烟气脱硫性能的影响

介绍了国内外烟气脱硫催化剂的研究现状,研究了金属氧化物负载型催化剂对烟气脱硫性能的影响。以活性炭(AC)为载体,选用8种不同的金属硝酸盐作为浸渍液,采用等体积浸渍法制备金属氧化物负载型催化剂。以脱硫效果较好的Fe2O3/AC为例,研究了不同焙烧温度、金属负载量以及焙烧时间对催化剂脱硫性能的影响。实验结果表明,Fe2O3/AC催化剂脱硫率随着金属负载量的增加呈递增趋势,最优金属负载量为10.0%(质量分数);脱硫率随着焙烧温度的增加显著提高,最优焙烧温度为350℃;脱硫率随着焙烧时间的增加而提高,最优焙烧时间为3.0h。     

Sorption kinetic characteristics of polybrominated diphenyl ethers on natural soils

Sorption kinetic characteristics of BDE-28 and BDE-47 on five natural soils with different organic carbon fractions were investigated, and could be satisfactorily described by a two (fast and slow)-compartment first-order model with the ratio of rate constants ranged from 9 to 94 times. The fast compartment made a dominant contribution (71% ∼ 94%) to the total sorption amount in the whole process, and accounted for over 90% of the increase in the total sorption amount at initial 5 h. The influence of the slow compartment on the increase in the total sorption amount became principal (above 90%) in the subsequent stage approximately from 9 h or 25 h to the apparent equilibrium at 265 h. The results proposed the different sorption behaviors of the mathematically classified compartments for BDE-28 and BDE-47, which may correspond to the different soil components, such as soil organic fractions with amorphous and condensed structures, respectively.     

城市水资源供需经济分析与对策

本文通过对水价与需求关系的探讨,推导出水价与需求的理想公式,并就该公式进行了分析,提出了解决城市水资源供需矛盾的经济对策。     

Fault-dynamic modelling of a phthalic anhydride reactor

A new methodology, fault-dynamic modelling, has been developed for analysis of potentially hazardous situations in the process industries. Traditional fault-tree analysis is used to determine the combinations of component failure that can lead to a particular process upset condition. Realistic dynamic modelling is then used to calculate the time available for corrective action once the upset has started. The method is applied to a phthalic anhydride reactor. The results of the analysis identify three process upsets that can lead to catastrophic failure in 2–5 min if left uncorrected. Other process upsets lead to safe conditions.     

剥壳机系统噪声控制技术

剥壳机生产系统将胡豆打碎和去壳时发出严重的扰民噪声,对产生噪声的设备和管道采用隔声和吸声控制措施。结果表明,效果十分明显,达到了国家环境噪声排放标准。     

四川彭县银厂沟峡谷自然景观成因初探

四川省彭县银厂沟峡谷全长21公里,峡谷和原始森林保存完整。时隐时现的“彩虹”出现于峡谷两岸的瀑布上。区内自然景观丰富多彩。本文根据旅游地质调查工作成果,对自然景观的成因作了初步探讨。     

高黎贡山自然保护区的鱼类

高黎贡山自然保护区位于怒江水系和伊洛瓦底江水系之间。据调查,共有鱼类47种。鱼类组成特点:北部多为中亚高山区种类,属华西区;南部以南亚类群占优势,属华南区。     

新型电极及其电解阳离子染料染色模拟液研究

本文研制了一种可用于废水处理的新型阳极和阴极，研制电极电解处理离子染料色模拟液时，分解电压低，脱色率高，电能消耗少。     

Biodegradable plastic made from soybean products. II. Effects of cross-linking and cellulose incorporation on mechanical properties and water absorption

Soy isolate was treated with formaldehyde and glyoxal at 1.0, 2.5, and 5.0% (w/w isolate) and with adipic and acetic anhydrides. The materials were then compression-molded into plastic tensile bars and tested for tensile and yield strength, percentage elongation, Young's modulus, and water absorption. Treatment with 5% formaldehyde increased the tensile strength significantly, to 4.9 kg/mm², compared with the untreated sample (3.7 kg/mm²). The yield strength increased slightly, to 0.68 kg/mm². Elongation was significantly less after treatment with formaldehyde. Young's modulus increased after treatment and leveled off at 174 kg/mm². Water absorption decreased as the formaldehyde concentration increased. Treatment with either glyoxal or adipic/acetic anhydride had a detrimental effect on the mechanical properties of the plastic specimens. Water absorption was decreased by glyoxal treatment but was not affected by adipic/acetic anhydride treatment. Long-fiber (lf), short-fiber (sf), and microcrystalline (mc) cellulose were incorporated into soy isolate at various levels. Cellulose addition decreased the percentage elongation and increased the rigidity of the plastic. All three cellulose additions increased Young's modulus. The tensile strength increased with the addition of sf-cellulose to soy isolate; lf-cellulose decreased the tensile strength, whereas the incorporation of mc-cellulose did not have a significant effect. The yield strength increased slightly with the addition of sf-cellulose and was less affected by the addition of lf- or mc-cellulose. All three types of cellulose slightly decreased water absorption at ca. 15% content.Journal Paper No. J-15563 of the Iowa Agriculture and Home Economics Experiment Station, Ames; Project No. 2863.