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11.
Nada Horvatinčić José Luis Briansó Bogomil Obelić Jadranka Barešić Ines Krajcar Bronić 《Water, Air, & Soil Pollution: Focus》2006,6(5-6):475-485
The process of eutrophication in form of intense plant growth has been observed in some lakes and water streams at the Plitvice
Lakes National Park in central Croatia. Here we investigate whether this phenomenon is a consequence of anthropogenic pollution
or due to naturally produced organic matter in the lakes. We applied chemical analysis of water at two springs and four lakes
(nutrients, dissolved organic carbon (DOC), trace elements) and measurements of surface lake sediments (mineral and organic
fraction analyses, trace elements) in four different lakes/five sites. The chemical composition of water does not indicate
recent anthropogenic pollution of water because the concentrations of most trace elements are below detection limits. The
concentrations of DOC and nutrients are slightly higher in the area of increased eutrophication-plant growth. Also the content
of organic matter in the sediment is at the highest level in areas with highest C/N ratio indicating that the organic fraction of this sediment is mainly of terrestrial origin. There is no significant difference
among the trace element concentration in the upper segment of all cores, deposited approximately during last 50 years when
higher anthropogenic influence is expected due to development and touristic activity, and the lower part of the cores, corresponding
to the period approximately 100–200 years before present. The content of trace elements and organic matter in sediments decreases
from the uppermost lake downstream. According to our results there is no indication of recent anthropogenic pollution in water
and sediment. Higher concentrations of DOC in water as well as phosphorus and some other elements in the lake sediment can
be a consequence of input of natural organic matter to the lake water. 相似文献
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Miroslav Kukučka Nikoleta Kukučka Mirna Habuda-Stanić 《Environmental science and pollution research international》2016,23(18):17919-17927
The aim of this study was to investigate the performances of polyamide nanofiltration membranes during water reclamation. The study was conducted using nanofiltration concentrates obtained from two different nanofiltration drinking water treatment plants placed in the northern part of Serbia (Kikinda and Zrenjanin). Used nanofiltration concentrates contained high concentrations of arsenic (45 and 451 μg/L) and natural organic matter (43.1 and 224.40 mgKMnO4/L). Performances of polyamide nanofiltration membranes during water reclamation were investigated under various fluxes and transmembrane pressures in order to obtain drinking water from nanofiltration concentrates and, therefore, reduce the amount of produced concentrates and minimize the waste that has to be discharged in the environment. Applied polyamide nanofiltration membranes showed better removal efficiency during water reclamation when the concentrate with higher content of arsenic and natural organic matter was used while the obtained permeates were in accordance with European regulations. This study showed that total concentrate yield can be reduced to ~5 % of the optimum flux value, in both experiments. The obtained result for concentrate yield under the optimum flux presents considerable amount of reclaimed drinking water and valuable reduced quantity of produced wastewater. 相似文献
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Dragun Zrinka Filipović Marijić Vlatka Krasnići Nesrete Ramani Sheriban Valić Damir Rebok Katerina Kostov Vasil Jordanova Maja Erk Marijana 《Environmental science and pollution research international》2017,24(20):16917-16926
Environmental Science and Pollution Research - A lipid peroxidation product, malondialdehyde (MDA), was studied in Vardar chub (Squalius vardarensis Karaman) as an indicator of oxidative stress,... 相似文献
17.
Sorption-desorption behavior of imidacloprid in six soils collected from five coastal regions in Croatia at 20, 30 and 40°C was investigated using batch equilibrium technique. Isothermal data were applied to Freundlich, Langmuir and Temkin equations, and the thermodynamic parameters ΔH°, ΔG°, ΔS° were calculated. The sorption isotherm curves were non-linear and may be classified as L-type, suggesting a relatively high sorption capacity for imidacloprid. Our results showed that the K( sor ) ( F ) values decreased for all the tested soils as the temperature increased, indicating that the temperature strongly influences the sorption. Values of ΔG° were negative (-4.65 to -2.00 kJ/mol) indicating that at all experimental temperatures the interactions of imidacloprid with soils were spontaneous processes. The negative and small ΔH° values (-19.79 to -8.89 kJ/mol) were in the range of weak forces, such as H-bonds, consistent with interactions and partitioning of the imidacloprid molecules into soil organic matter. The ΔS° values followed the range of -57.12 to -14.51 J/molK, suggesting that imidacloprid molecules lose entropy during transition from the solution phase to soil surface. It was found that imidacloprid desorption from soil was concentration and temperature-dependent, i.e. at lower imidacloprid concentrations and temperature, lower desorption percentage occurred. Desorption studies revealed that hysteretic behavior under different temperature treatments existed, and it was more pronounced at 20°C in the soils with higher OC content. The study results emphasize the importance of thermodynamic parameters in controlling soil pesticide mobility in different geographical locations, seasons and greenhouse conditions. 相似文献
18.
Ivan S. Ristić Ljiljana Tanasić Ljubiša B. Nikolić Suzana M. Cakić Olivera Z. Ilić Radmila Ž. Radičević Jaroslava K. Budinski-Simendić 《Journal of Polymers and the Environment》2011,19(2):419-430
Different synthesis methods were applied to determine optimal conditions for polymerization of (3S)-cis-3,6-dimethyl-1,4-dioxane-2,5-dione (l-lactide), in order to obtain poly(l-lactide) (PLLA). Bulk polymerizations (in vacuum sealed vessel, high pressure reactor and in microwave field) were performed
with tin(II) 2-ethylhexanoate as the initiator. Synthesis in the vacuum sealed vessel was carried out at the temperature of
150 °C. To reduce the reaction time second polymerization process was carried out in the high pressure reactor at 100 °C and
at the pressure of 138 kPa. The third type of rapid synthesis was done in the microwave reactor at 100 °C, using frequency
of 2.45 GHz and power of 150 W at the temperature of 100 °C. The temperature in this method was controlled via infrared system
for in-bulk measuring. The solution polymerization (with trifluoromethanesulfonic acid as initiator) was possible even at
the temperature of 40 °C, yielding PLLA with narrow molecular weight distribution in a very short period of time (less than
6 h). The obtained polymers had the number-average molecular weights ranging from 43,000 to 178,000 g mol−1 (polydispersity index ranging from 1 to 3) according to the gel permeation chromatography measurements. The polymer structure
was characterized by Fourier transform infrared and NMR spectroscopy. Thermal properties of the obtained polymers were investigated
using thermogravimetry and differential scanning calorimetry. 相似文献
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Ester Heath Marjeta Česen Noelia Negreira Miren Lopez de Alda Laura Ferrando-Climent Lucie Blahova Tung Viet Nguyen Mohamed Adahchour Achim Ruebel Neville Llewellyn Janez Ščančar Srdjan Novaković Vesna Mislej Marjeta Stražar Damià Barceló Tina Kosjek 《Environmental science and pollution research international》2016,23(15):14692-14704
The results of an inter-laboratory comparison exercise to determine cytostatic anticancer drug residues in surface water, hospital wastewater and wastewater treatment plant effluent are reported. To obtain a critical number of participants, an invitation was sent out to potential laboratories identified to have the necessary knowledge and instrumentation. Nine laboratories worldwide confirmed their participation in the exercise. The compounds selected (based on the extent of use and laboratories capabilities) included cyclophosphamide, ifosfamide, 5-fluorouracil, gemcitabine, etoposide, methotrexate and cisplatinum. Samples of spiked waste (hospital and wastewater treatment plant effluent) and surface water, and additional non-spiked hospital wastewater, were prepared by the organising laboratory (Jo?ef Stefan Institute) and sent out to each participant partner for analysis. All analytical methods included solid phase extraction (SPE) and the use of surrogate/internal standards for quantification. Chemical analysis was performed using either liquid or gas chromatography mass (MS) or tandem mass (MS/MS) spectrometry. Cisplatinum was determined using inductively coupled plasma mass spectrometry (ICP-MS). A required minimum contribution of five laboratories meant that only cyclophosphamide, ifosfamide, methotrexate and etoposide could be included in the statistical evaluation. z-score and Q test revealed 3 and 4 outliers using classical and robust approach, respectively. The smallest absolute differences between the spiked values and the measured values were observed in the surface water matrix. The highest within-laboratory repeatability was observed for methotrexate in all three matrices (CV?≤?12 %). Overall, inter-laboratory reproducibility was poor for all compounds and matrices (CV 27–143 %) with the only exception being methotrexate measured in the spiked hospital wastewater (CV?=?8 %). Random and total errors were identified by means of Youden plots. 相似文献