Quality assessment of various bottled waters marketed in Saudi Arabia

This study focuses on the chemical analysis of the available brands of domestic bottled water in Riyadh City, Saudi Arabia. The distribution of the chemical constituents (major, minor, and trace elements) is determined and compared with the chemical content labeled on the bottles and with drinking water standards of Saudi Arabian, World Health Organization, and U.S. Environmental Protection Agency. The obtained results indicated that except for fluoride and bromate, the concentrations of dissolved salts, soluble cations and anions, nitrate, and trace elements of most bottled waters on sale were within the permissible limits set by standards used. On the other hand, the comparison between determined and reported label values recorded a substantial variation in some parameter values. Results indicated that more than 18 % of the sampled bottled waters exceeded the allowable limits for drinking water. Generated Piper diagrams revealed that the majority of investigated waters were sodium chloride–sulfate type; however, the hydrochemical modeling indicated that all water samples were undersaturated for anhydrite, gypsum, and halite.     

A novel method for the preparation of silver/chitosan-O-methoxy polyethylene glycol core shell nanoparticles

Uniformly sized silver/chitosan-O-methoxy polyethylene glycol (chitosan-O-MPEG) core shell nanoparticles with different degree of substitution were synthesized. Thus, N-phthaloyl chitosan is reacted with polyethylene glycol monomethyl ether iodide in the presence of silver oxide by the following steps. At first, amino groups of chitosan are protected by fourfold excess of phthalic anhydride. Then N-phthaloyl chitosan is reacted with an appropriate amount of monomethyl ether iodide in the presence of silver oxide and lastly N-phthaloyl groups are removed to yield silver/chitosan-O-MPEG core shell nanoparticles. Structure of prepared silver/chitosan-O-MPEG core shell nanoparticles have been characterized by UV/Vis spectroscopy, transmission electron microscopy (TEM), Fourier transform infrared (FT-IR), X-ray diffraction, and scan electron microscopy (SEM-EDX). Experimental results revealed that the prepared silver core particles had the size 18?±?2?nm. Core shell structure with chitosan-O-MPEG-coating had the size 40?±?2?nm.     

Synthesis of Chitosan@activated Carbon Beads with Abundant Amino Groups for Capture of Cu(II) and Cd(II) from Aqueous Solutions

In this study, chitosan and bio-based activated carbon obtained from sugarcane bagasse biowaste were used for the synthesis of efficient sorbent for Cu(II) and Cd(II) ion via precipitation method. The prepared material was enriched with amino groups through grafting tetraethylenepentamine and tested for heavy metal remediation from water samples. The influence of pH was investigated showing optimum sorption at pH 6 for Cu(II) and Cd(II). Sorption tests, explained by means of the most common sorption models, evidenced that the best performances were reached pointing out the promising application of the prepared sorbent for water purification treatments: Uptake kinetics are relatively fast: the equilibrium was reached within 140 min; and the kinetic profiles were preferentially fitted by the pseudo-second order rate equation. Sorption isotherms are fitted by Langmuir equation. The sorbent showed high metal ion sorption capacity with negligible influence of ion strength. The maximum sorption capacities reached 3.44 and 2.38 mmol g^??1 for Cu(II) and Cd(II), respectively at 298 K. Thermodynamic parameters were evaluated through variation of temperature. The sorption is unfavorable at elevated temperatures. Metal ions were successfully desorbed using 1 M HNO₃ solution.     

EDTA-enhanced phytoremediation of lead-contaminated soil by the halophyte Sesuvium portulacastrum

The low bioavailability of Pb and low number of Pb-tolerant plant species represent an important limitation for Pb phytoextraction. It was recently suggested that halophyte plant species may be a promising material for this purpose, especially in polluted salt areas while Pb mobility may be improved by synthetic chelating agents. This study aims to evaluate Pb extraction by the halophyte Sesuvium portulacastrum in relation to the impact of EDTA application. Seedling were cultivated during 60 days on Pb artificially contaminated soil (200, 400, and 800 ppm Pb) in the presence or in the absence of EDTA (3 g kg^?1 soil). Results showed that upon to 400 ppm, Pb had no impact on plant growth. However, exogenous Pb induce a decrease in shoot K⁺ while it increased shoot Mg²⁺ and had no impact on shoot Ca²⁺ concentrations. Lead concentration in the shoots increased with increasing external Pb doses reaching 1,390 ppm in the presence of 800 ppm lead in soil. EDTA addition had no effect on plant growth but strongly increased Pb accumulation in the shoot which increased from 1,390 ppm in the absence of EDTA to 3,772 ppm in EDTA-amended plants exposed to 800 ppm exogenous Pb. Both Pb absorption and translocation from roots to shoots were significantly enhanced by EDTA application, leading to an increase in the total amounts of extracted Pb per plant. These data suggest that S. portulacastrum is very promising species for decontamination of Pb²⁺-contaminated soil and that its phytoextraction potential was significantly enhanced by addition of EDTA to the polluted soil.     

Isolation of petroleum and chlorinated hydrocarbons from the same extract

Sequential analysis is an extremely powerful technique for complex samples analysis. For determination of petroleum and chlorinated hydrocarbons, the same sample is divided into two parts. One part is utilized to extract the petroleum hydrocarbons and the second part is used to extract the organochlorine compounds because petroleum hydrocarbons usually appear in higher concentrations and interfering with organochlorine compounds. This analysis method required more solvent, time, and more sample volume. The analytical strategy, in this paper, involves the use of effective and efficient but simple techniques for petroleum hydrocarbons and chlorinated hydrocarbons separation. A clean‐up procedure is presented, by which these compounds are isolated from aliphatic as well as polyaromatic hydrocarbons through a combination of HPLC and adsorption chromatography on a florisil microcolumn. Mass spectrometric identification was used as confirmation method. GLC equipped with ECD and FID for organochlorine and petroleum compounds analysis, respectively.     

The dynamic causal links between CO2 emissions from transport,real GDP,energy use and international tourism

This study examines the dynamic causality relationship between international tourism and carbon dioxide (CO₂) emissions from transport, real gross domestic product and energy use. The vector error correction model and Granger causality test approach have been used to investigate these relationships for the top ten international tourism destinations spanning the period 1995–2013. Results reveal a unidirectional causality running from CO₂ emissions to economic growth without feedback; a bidirectional causality between economic growth and energy use; a bidirectional causality between international tourism and economic growth; and a bidirectional causality between international tourism and energy use. They also suggest that energy use and international tourism both contribute to the decrease of emissions level coming from transport sector, while economic growth leads to the increase of CO₂ emissions. This study can be used in policy recommendations by encouraging countries to use clean energy and to stimulate tourism sector for combating global warming.     

WATERSHED MODELS AND THEIR APPLICABILITY TO CONJUNCTIVE USE MANAGEMENT1

ABSTRACT: Techniques employed to simulate infiltration and subsurface ground-water flow were examined for a number of available watershed models. The large number of processes that these models simulate prohibits detailed analysis of subsurface flow, due to excessive computer and data requirements. Such models emphasize surface flow and include only that portion of water lost to the subsurface and the portion returned to the stream as baseflow. Problems were examined in adopting conjunctive use models, which allow the coordinated exploitation and management of both surface and ground-water resources. The application of conjunctive use models in water resources management is expected to increase dramatically over the next decade.     

Effects of Rainfall and Ground‐Water Pumping on Streamflow in Mākaha,O’ahu,Hawai’i1

Abstract: Land‐use/land‐cover changes in Mākaha valley have included the development of agriculture, residential dwellings, golf courses, potable water supply facilities, and the introduction of alien species. The impact of these changes on surface water and ground water resources in the valley is of concern. In this study, streamflow, rainfall, and ground‐water pumping data for the upper part of the Mākaha valley watershed were evaluated to identify corresponding trends and relationships. The results of this study indicate that streamflow declined during the ground‐water pumping period. Mean and median annual streamflow have declined by 42% (135 mm) and 56% (175 mm), respectively, and the mean number of dry stream days per year has increased from 8 to 125. Rainfall across the study area appears to have also declined though it is not clear whether the reduction in rainfall is responsible for all or part of the observed streamflow decline. Mean annual rainfall at one location in the study area declined by 14% (179 mm) and increased by 2% (48 mm) at a second location. Further study is needed to assess the effect of ground‐water pumping and to characterize the hydrologic cycle with respect to rainfall, infiltration, ground‐water recharge and flow in the study area, and stream base flow and storm flow.     

Estimating Hydraulic Properties of Volcanic Aquifers Using Constant‐Rate and Variable‐Rate Aquifer Tests1

Abstract: In recent years the ground‐water demand of the population of the island of Maui, Hawaii, has significantly increased. To ensure prudent management of the ground‐water resources, an improved understanding of ground‐water flow systems is needed. At present, large‐scale estimations of aquifer properties are lacking for Maui. Seven analytical methods using constant‐rate and variable‐rate withdrawals for single wells provide an estimate of hydraulic conductivity and transmissivity for 103 wells in central Maui. Methods based on constant‐rate tests, although not widely used on Maui, offer reasonable estimates. Step‐drawdown tests, which are more abundantly used than other tests, provide similar estimates as constant‐rate tests. A numerical model validates the suitability of analytical solutions for step‐drawdown tests and additionally provides an estimate of storage parameters. The results show that hydraulic conductivity is log‐normally distributed and that for dike‐free volcanic rocks it ranges over several orders of magnitude from 1 to 2,500 m/d. The arithmetic mean, geometric mean, and median values of hydraulic conductivity are respectively 520, 280, and 370 m/d for basalt and 80, 50, and 30 m/d for sediment. A geostatistical approach using ordinary kriging yields a prediction of hydraulic conductivity on a larger scale. Overall, the results are in agreement with values published for other Hawaiian islands.     

Disruption of biofilms from sewage pipes under physical and chemical conditioning

Biofilms grown inside two sewage collecting pipes located in industrial and residential areas are studied. Bacterial biomass inside three layers of biofilms was evaluated. Biofilm cohesion under different mixing rate and ionic strength was also investigated. Effects of physical and chemical parameters in the biofilms were evaluated by monitoring turbidity, chemical and biochemical oxygen demands. Extracted organic matter from biofilms was partitioned to polar, aromatic and saturated fractions using activated silica column chromatography. Results revealed that bacterial biomass growth depending on biofilm thickness and stratification. The most loaded stratum in bacterial biomass was the sewage-biofilm interface stratum that represented 51% of the total bacterial biomass. Stirring rate and ionic strength of mono and bivalent salts showed a major influence in biofilm disruption. The stirring time enhanced the exchange dynamic and matter capture between biofilm fragments at the critical stirring rate 90 r/min. Sodium chloride showed the dispersing effect on biofilms in suspension, and decreased the BOD5 (biochemical oxygen demand) beyond the physiological salt concentration.