Designing monitoring networks to represent outdoor human exposure

Measurements of outdoor human exposure to suspended particulate matter (PM) are always constrained by available resources. An effective network design requires tradeoffs between variables measured, the number of sampling locations, sample duration, and sampling frequency. Sampling sites are needed to represent neighborhood and urban spatial scales with minimal influences from nearby sources. Although most PM measurements for determining compliance with standards are taken over 24-h periods every third to sixth day, outdoor human exposure assessment requires measurements taken continuously throughout the day, preferably over durations of 1 h or less. More detailed particle size and chemistry data are also desirable, as smaller size fractions and specific chemicals may be better indicators of adverse health effects than total mass samples.     

Source profiles for industrial, mobile, and area sources in the Big Bend Regional Aerosol Visibility and Observational study

Representative PM2.5 and PM10 source emissions were sampled in Texas during the Big Bend Regional Aerosol Visibility and Observa (BRAVO) study. Chemical source profiles for elements, ions, and carbon fractions of 145 samples are reported for paved and unpaved road dust, soil dust, motor vehicle exhaust, vegetative burning, four coal-fired power stations, an oil refinery catalytic cracker, two cement kilns, and residential meat cooking. Several samples were taken from each emitter and source type, and these were averaged by source type, and in source subgroups based on commonality of chemical composition. The standard deviation represents the variability of the chemical mass fractions. BRAVO profiles differed in some respects from profiles measured elsewhere. High calcium abundances in geological dust, high selenium abundances in coal-fired power stations, and high antimony abundances in oil refinery catalytic cracker emissions were found. Abundances of eight thermally evolved carbon fractions [Atmos. Environ. 28 (15) (1994) 2493] differ among combustion sources, and a Monte Carlo simulation demonstrates that these differences are sufficient to differentiate among several carbon-emitters.     

Protection from fishing alters the species composition of fish assemblages in a temperate-tropical transition zone

Closure of areas to fishing is expected to result in an increase in the abundance of targeted species; however, changes to populations of species not targeted by fishermen will depend upon their role in the ecosystem and their relationship with targeted species. The effects of protection on targeted and non-targeted reef fish species at the Houtman Abrolhos Islands, Western Australia were studied using baited remote underwater stereo–video cameras. Video images were collected from shallow (8–12 m) and deep (22–26 m) reef sites inside a Marine Protected Area (MPA) at each of three island groups and from three replicate fished locations at each of these groups that span a temperate-tropical transition area. The MPAs were established in 1994 and vary in size from 13.72 km² at the Pelsaert group in the south to 22.29 km² at the Easter group to 27.44 km² at the Wallabi group in the north. The relative abundances of 137 fish species from 42 families were recorded. Large differences in fish assemblage structure existed between MPA and fished locations, and also between shallow and deep regions. Targeted fish species Plectropomus leopardus, Lethrinus miniatus, Lethrinus nebulosus, Pagrus auratus and Glaucosoma hebraicum were more abundant inside MPAs than in areas open to fishing. Their abundance inside MPAs was between 1.13 and 8 times greater than their abundance at fished locations. For non-targeted fish species many were more abundant in areas open to fishing, e.g. Coris auricularis, Thalassoma lutescens, Thalassoma lunare, Dascyllus trimaculatus, however others were conversely more abundant inside MPAs, e.g. Gymnothorax spp, Kyphosus sydneyanus, Scarus microhinos, Chromis westaustralis, Chaetodon spp. This study demonstrates that the removal of abundant targeted species from an ecosystem by fishing can indirectly impact non-fished species and alter the trophic structure of fish assemblages. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Response of Algal Biomass to Large‐Scale Nutrient Controls in the Clark Fork River,Montana, United States1

Suplee, Michael W., Vicki Watson, Walter K. Dodds, and Chris Shirley, 2012. Response of Algal Biomass to Large‐Scale Nutrient Controls in the Clark Fork River, Montana, United States. Journal of the American Water Resources Association (JAWRA) 48(5): 1008‐1021. DOI: 10.1111/j.1752‐1688.2012.00666.x Abstract: Nutrient pollution is an ongoing concern in rivers. Although nutrient targets have been proposed for rivers, little is known about long‐term success of programs to decrease river nutrients and algal biomass. Twelve years of summer data (1998‐2009) collected along 383 km of the Clark Fork River were analyzed to ascertain whether a basin‐wide nutrient reduction program lowered ambient total nitrogen (TN) and total phosphorus (TP) concentrations, and bottom‐attached algal biomass. Target nutrient and algal biomass levels were established for the program in 1998. Significant declines were observed in TP but not TN along the entire river. Downstream of the city of Missoula, TP declined below a literature‐derived TP saturation breakpoint and met program targets after 2005; TN was below targets since 2007. Algal biomass also declined significantly below Missoula. Trends there likely relate to the city’s wastewater facility upgrades, despite its 20% population increase. Upstream of Missoula, nutrient reductions were less substantial; still, TP and TN declined toward saturation breakpoints, but no significant reductions in algal biomass occurred, and program targets were not met. The largest P‐load reduction to the river was from a basin‐wide phosphate laundry detergent ban set 10 years before, in 1989. We document that nutrient reductions in rivers can be successful in controlling algal biomass, but require achievement of concentrations below saturation and likely close to natural background.     

Design and Testing of a New Size Classifying Isokinetic Sequential Aerosol Sampler

Two versions of a size-classifying isokinetic sequential aerosol sampler (SCISAS) have been designed, built, tested, and deployed in a field program in the southwestern United States. The SCISAS units can operate at unattended sites, exposing four or more filter types simultaneously, in two size ranges, for six sampling time Intervals. Design considerations included theoretical estimates of aerosol particle losses in the 0-15 μm size range.

SCISAS prototypes have been tested to evaluate their sampling efficiency as a function of flow rate, the sensitivity of the sampling efficiency to isokinetic matching within the SCISAS sampling stack, the equivalency of their sampling ports, and their passive deposition characteristics. The prototypes were also compared to several other types of aerosol filtration samplers already in common use. These tests show that particle loss mechanisms within the SCISAS usually cause no more than 5 percent losses, and that the SCISAS units agree, within one to two measurement uncertainty intervals, with other types of aerosol samplers.     

Emissions of gas- and particle-phase polycyclic aromatic hydrocarbons (PAHs) in the Shing Mun Tunnel,Hong Kong

Real-world vehicle emission factors for seventeen gas and particulate polycyclic aromatic hydrocarbons (PAHs) were quantified in the Shing Mun Tunnel, Hong Kong during summer and winter 2003. Naphthalene, acenaphthylene, and acenaphthene were the most abundant gas PAHs while fluoranthene and pyrene were the most abundant in the particle phase. Most (98%) of the gas PAHs consisted of two- and three-aromatic rings whereas most of the particle-phase PAHs were in four- (～60%) and five-ring (～17%) for fresh exhaust emissions. Average emission factors for the gas- and particle PAHs were 950–2564 μg veh^?1 km^?1 and 22–354 μg veh^?1 km^?1, respectively. Good correlations were found between diesel markers (fluoranthene and pyrene; 0.85) and gasoline markers (benzo[ghi]perylene and indeno[1,2,3-cd]pyrene; 0.96). Higher PAH emission factors were associated with a higher fraction of diesel-fueled vehicles (DV) passing through the tunnel. Separate emission factors were determined from diesel and non-diesel exhaust by the regression intercept method. The average PAH emission factor (i.e., sum of gas and particle phases) from DV (3085 ± 1058 μg veh^?1 km^?1) was ～5 times higher than that from non-diesel-fueled vehicles (NDV, 566 ± 428 μg veh^?1 km^?1). Ratios of DV to NDV emission factors were high for diesel markers (>24); and low for gasoline markers (<0.4).     

Filter light attenuation as a surrogate for elemental carbon

Light attenuation (b(att)) measured from filter light transmission is compared with elemental carbon (EC) measurements for more than 180,000 collocated PM2.5 (particulate matter [PM] < or = 2.5 microm in aerodynamic diameter) and PM10 (PM < or = 10 microm in aerodynamic diameter) samples from nearly 200 U.S. locations during the past 2 decades. Although there are theoretical reasons for expecting highly variable relationships between b(att) and EC (such as the effects of "brown carbon" and iron oxides in PM2.5), reasonable correlations are found. These correlations are not a strong function of season or location (e.g., rural vs. urban). Median EC concentrations can be predicted from filter transmittance measurements to within +/- 15-30%. Although EC predicted from b(att) shows larger uncertainties (30-60%), especially at concentrations less than 0.3 microg/m3, the consistent mass absorption efficiency (sigm(att)) derived from the regression analysis demonstrates the feasibility of using b(att) as a surrogate for EC. This study demonstrates that a constant factor of 0.1 g/m2 (equivalent to the 10 m2/g sigma(att) used in the Interagency Monitoring of Protected Visual Environments chemical extinction formula) can be used to estimate EC concentrations from b(att) through a Teflon-membrane filter sample. Greater accuracy is achieved with site-specific sigma(att) derived from a period with collocated EC measurements.