Impact of sample preparation on mineralogical analysis of zero-valent iron reactive barrier materials

Permeable reactive barriers (PRBs) of zero-valent iron (Fe(0)) are increasingly being used to remediate contaminated ground water. Corrosion of Fe(0) filings and the formation of precipitates can occur when the PRB material comes in contact with ground water and may reduce the lifespan and effectiveness of the barrier. At present, there are no routine procedures for preparing and analyzing the mineral precipitates from Fe(0) PRB material. These procedures are needed because mineralogical composition of corrosion products used to interpret the barrier processes can change with iron oxidation and sample preparation. The objectives of this study were (i) to investigate a method of preparing Fe(0) reactive barrier material for mineralogical analysis by X-ray diffraction (XRD), and (ii) to identify Fe mineral phases and rates of transformations induced by different mineralogical preparation techniques. Materials from an in situ Fe(0) PRB were collected by undisturbed coring and processed for XRD analysis after different times since sampling for three size fractions and by various drying treatments. We found that whole-sample preparation for analysis was necessary because mineral precipitates occurred within the PRB material in different size fractions of the samples. Green rusts quickly disappeared from acetone-dried samples and were not present in air-dried and oven-dried samples. Maghemite/magnetite content increased over time and in oven-dried samples, especially after heating to 105 degrees C. We conclude that care must be taken during sample preparation of Fe(0) PRB material, especially for detection of green rusts, to ensure accurate identification of minerals present within the barrier system.     

Phytoremediation of heavy metal-contaminated land by trees--a review

This paper reviews the potential for using trees for the phytoremediation of heavy metal-contaminated land. It considers the following aspects: metal tolerance in trees, heavy metal uptake by trees grown on contaminated substrates, heavy metal compartmentalisation within trees, phytoremediation using trees and the phytoremediation potential of willow (Salix spp.).     

FLUVIAL PROCESSES AND MORPHOLOGICAL THRESHOLDS IN INCISED CHANNEL RESTORATION1

ABSTRACT: Incised channels are those in which an imbalance between sediment transport capacity and sediment supply has led to degradation of their beds. This is a frequent response to stream channelization, changes in land use, or lowering of base level. If the degradation causes a critical bank-height threshold to be exceeded, which is dependent on the geotechnical properties of the bank materials, then bank failure and channel widening follow. Interdependent adjustments of channel slope and cross-sectional area occur until a new state of dynamic equilibrium with the imposed discharge and sediment load is attained. These geomorphic adjustments can be described and quantified by using location-for-time substitution and a model of channel evolution can be formulated. Three approaches to rehabilitation of the degraded channels are possible; geomorphic, engineering and rational. The rational approach, which integrates elements of both the engineering and geomorphic approaches, is based on the channel evolution model, and it generally involves control of grade, control of discharge, or a combination of both.     

The analysis of flue gas treatment residues using non-destructive X-ray fluorescence as a regulatory compliance test

Current and proposed European Union (EU) regulations require the residual material from municipal solid waste incineration to be characterised prior to disposal. X-Ray fluorescence (XRF) provides a rapid and non-destructive technique for analysing such materials.     

Environmental health implications of global climate change

This paper reviews the background that has led to the now almost-universally held opinion in the scientific community that global climate change is occurring and is inescapably linked with anthropogenic activity. The potential implications to human health are considerable and very diverse. These include, for example, the increased direct impacts of heat and of rises in sea level, exacerbated air and water-borne harmful agents, and--associated with all the preceding--the emergence of environmental refugees. Vector-borne diseases, in particular those associated with blood-sucking arthropods such as mosquitoes, may be significantly impacted, including redistribution of some of those diseases to areas not previously affected. Responses to possible impending environmental and public health crises must involve political and socio-economic considerations, adding even greater complexity to what is already a difficult challenge. In some areas, adjustments to national and international public health practices and policies may be effective, at least in the short and medium terms. But in others, more drastic measures will be required. Environmental monitoring, in its widest sense, will play a significant role in the future management of the problem.     

QUANTIFICATION OF INCISED CHANNEL EVOLUTION AND EQUILIBRIUM1

ABSTRACT: Incised channels are caused by an imbalance between sediment transport capacity and sediment supply that alters channel morphology through bed and bank erosion. Consistent sequential changes in incised channel morphology may be quantified and used to develop relationships describing quasi‐equilibrium conditions in these channels. We analyzed the hydraulic characteristics of streams in the Yazoo River Basin, Mississippi in various stages of incised channel evolution. The hydraulic characteristics of incising channels were observed to follow the sequence predicted by previous conceptual models of incised channel response. Multiple regression models of stable slopes in quasi‐equilibrium channels that have completed a full evolutionary sequence were developed. These models compare favorably with analytical solutions based on the extremal hypothesis of minimum stream power and empirical relationships from other regions. Appropriate application of these empirical relationships may be useful in preliminary design of stream rehabilitation strategies.     

The dynamic context of southern African savannas: investigating emerging threats and opportunities to sustainability

The Southern African Savannas Network and the Southern African Vulnerability Initiative used study areas and information from a wide range of sources to assess threats and opportunities to savanna sustainability from a natural and social science perspective, respectively. This paper describes an attempt to synthesise their findings using structural analysis. Key driving processes, main dependent processes, and processes that are inherent to most interactions by having both high driving power and high dependency, were identified. Qualitative examination reveals that while many of the changes within savannas reinforce each other, many of the key driving factors are generated externally, such as economic globalisation and climate change. In order to take advantage of opportunities and address challenges within such a complex and dynamic system, future interventions must address the different elements of savannas in a coherent and multi-sectoral manner. Within the large social, economic and environmental changes taking place over the past decade, changes in institutions and technologies and in indigenous fauna and flora continue to play a central role both in driving, and being dependent on, other processes and must continue to be a key focus of any coherent savanna policy.     

In vitro effects of acephate on carbonic anhydrase activity in the blood and gills of rainbow trout, Salmo gairdneri

Acephate, a water-soluble organophosphate pesticide used to control terrestrial insect pests, may enter aquatic ecosystems in the course of its use and adversely affect fish populations. The in vitro effects of this insecticide on gill and red blood cell (RBC) carbonic anyhdrase (CA) activity in rainbow trout were investigated over a range of 100 mg/1 (0.55 mM) to 50,000 mg/l (273 mM) to assess the manner in which acephate might affect respiratory capacity in exposed fish. Concentrations required to produce 50% inhibition of CA activity in the gill and RBC preparations were 38,000 mg/l (207 mM) and 8,900 mg/l (48 mM) respectively. The toxic action of acephate may be related to inhibition of CA activity in the blood and gills with resultant disturbances of respiratory capacity and salt balance.