不同封闭情况下T型管道中瓦斯爆炸传播规律实验研究*

为研究不同封闭情况下T型管道中瓦斯爆炸的传播规律,在90°分岔管道中进行瓦斯爆炸实验,管道封闭情况为弱封闭（双PVC薄膜弱封闭）和强封闭（直管封闭或支管封闭）。实验结果表明:在瓦斯浓度为9.5%时,管道中各点处的瓦斯爆炸压力、火焰传播速度和火焰锋面振荡幅度最大,11%次之,8%最小。T型管道中,弱封闭端瓦斯爆炸压力不断减小;火焰传播速度先缓慢增大后减小,随后又快速增大。强封闭端,瓦斯爆炸压力增大;火焰传播速度先缓慢增大后略微下降,随后快速增大后又大幅度下降,甚至出现火焰锋面振荡现象。不同封闭管道中各测点的瓦斯最大爆炸压力和火焰传播速度大小比较可知,直管封闭管道＞双PVC薄膜弱封闭管道＞支管封闭管道。     

基于MODIS与HJ-1-B数据的雪盖率反演及其相关因子分析

随着空间信息技术的发展及社会经济对雪盖监测产品的需求,亚像元雪盖制图逐渐成为积雪监测研究的重点。以环境与减灾卫星（HJ 1 B）数据作为地面真值计算MODIS数据中每个像元的积雪覆盖率,并与归一化雪被指数(NDSI)建立回归模型,从亚像元尺度反演MODIS数据的积雪覆盖率。以青海省玉树州作为研究区,实验结果表明该算法反演的雪覆盖率平均绝对误差均在02以内,在可接受的误差范围之内,说明该算法具有较强的稳定性和实用性。此外,在积雪覆盖率反演基础上,提出了与积雪覆盖率相关的另外两个相关因子：地表温度(LST)和植被指数(NDSI),分析表明：这两个因子与积雪覆盖率均存在明显的负相关关系,为基于多因子的雪盖率反演奠定了基础     

复合催化电解法处理染料工业废水

采用复合催化电解法对染料工业废水的处理进行了研究,并获得相应的工艺参数。试验结果表明,复合催化电解法能有效地处理染料工业废水,在电解电压10V、电流0.1A、电解时间1.5h的条件下,催化电解能使废水COD_Cr去除率达到87.5％～90％,脱色率达99％～100％。复合催化电解法具有操作简便、能耗较低等特点,是处理染料工业废水的一条新途径     

基于循证理论的事故隐患排查治理研究

为更好对企业进行事故隐患排查治理,本文从知识可及性和知识转移等角度,分析导致企业隐患排查治理差异的因素;然后提出基于循证理论的企业隐患排查治理方法并进行实证分析。研究表明:将循证理论引入到企业事故隐患排查治理中具有可行性和有效性。     

再生水补给型城市景观水体中抗生素抗性基因的污染特征——以圆明园为例

由于抗生素抗性基因(Antibiotic Resistance Genes,ARGs)对环境和人类健康存在潜在威胁而逐渐受到人们的重视,高人口密度城市中典型景观水体是ARGs储存库和传播媒介.本研究采用实时荧光定量PCR技术,研究了圆明园不同点位的ARGs污染情况和分布特征.结果表明:园区中ARGs的绝对丰度范围在n.d.(未检出)～1.08×10~9copies·L~(-1)之间;园区进水口目标ARGs的丰度低于末端,表明封闭的水体可能为ARGs的积累提供了理想培养基.在所检测基因中,磺胺类ARGs占主导,ARGs的绝对丰度依次为:sulIIsulImefAtetQtetMermB.磺胺类ARGs与指示微生物粪大肠菌群和大肠杆菌间存在显著相关性,表明指示微生物在ARGs的传播中可能起着关键作用.     

基于文献计量的环境损害赔偿研究进展与展望

以环境损害赔偿为研究对象,通过对CNKI（中国知网）和Web of Science核心合集数据库中英文文献的梳理,对国内外环境损害赔偿文献年代分布、文献的机构、期刊分布与研究热点趋势等方面进行研究分析.结果显示：国内外环境损害赔偿的发文量呈显著上升趋势且国外研究时间较早;文献发表机构主要集中在中国和美国,其中英文文献主要集中在环境管理、生态经济、污染效应、政策实施等研究领域,中文文献则更注重环境污染损害赔偿的法律制度构建和责任保险制度的实施;近几年,随着区域性环境污染的逐渐增多,跨界环境污染损害赔偿以及系统、完善的制度建设、保障实施的机制构建等会成为未来学界关注的重点.     

Insights into measurements of water-soluble ions in PM2.5 and their gaseous precursors in Beijing

To better understand the characteristics and transformation mechanisms of secondary inorganic aerosols, hourly mass concentrations of water-soluble inorganic ions (WSIIs) in PM_2.5 and their gaseous precursors were measured online from 2016 to 2018 at an urban site in Beijing. Seasonal and diurnal variations in water-soluble ions and gaseous precursors were discussed and their gas-particle conversion and partitioning were also examined, some related parameters were characterized. The (TNH₃) _Rich was also defined to describe the variations of the excess NH₃ in different seasons. In addition, a sensitivity test was carried out by using ISORROPIA II to outline the driving factors of gas-particle partitioning. In Beijing, the relative contribution of nitrate to PM_2.5 has increased markedly in recent years, especially under polluted conditions. In the four seasons, only a small portion of NO₂ in the atmosphere was converted into total nitrate (TNO₃)_, and more than 80% of TNO₃ occurred in the form of nitrate due to the abundant ammonia. The concentration of total ammonia (TNH₃) was much higher than that required to neutralize acid gases, and most of the TNH₃ occurred as gaseous NH₃. The nitrous acid (HONO) concentration was highly correlated with NH₃ concentration and had increased significantly in Beijing compared with previous studies. The total chloride (TCl) was the highest in winter, and ε(Cl^?) was more sensitive to variations in the ambient temperature (T) and relative humidity (RH) than ε(NO₃^?).     

Ce-Mn/TiO2吸附剂的脱汞性能及抗SO2特性

采用浸渍法制备Mn/TiO₂（MT）、Ce/TiO₂（CT）和Ce-Mn/TiO₂（CMT）脱汞吸附剂,在固定床脱汞实验台上研究吸附剂的脱汞性能.结果表明,吸附温度为100~200℃时,3种吸附剂的脱汞性能均随温度的升高而增强;而在200~300℃范围内,脱汞效率均出现不同程度的降低.MT、CT及CMT吸附剂的脱汞效率在200℃时达到最高,分别为91%、58%和95%.MT和CT吸附剂的抗SO₂性能较弱,在N₂+6% O₂+1000×10^-6SO₂烟气条件下,30min内脱汞效率均下降到50%,而CMT吸附剂在2h内仍能保持80%以上的脱汞效率,表明在MT中掺杂Ce不仅可以提高吸附剂的脱汞性能,还可以增强抗SO₂性能.利用N₂吸附/脱附、X射线衍射（XRD）、H₂-程序升温还原（H₂-TPR）和X射线光电子能谱（XPS）等方法对吸附剂的物理化学性质进行表征,并对吸附产物进行热重分析（TG）和程序升温脱附实验（TPD）,阐明了CMT脱汞吸附剂的抗SO₂特性机理.Ce的掺杂,提高了活性组分在吸附剂表面的分散度及Mn⁴⁺的比例;相比于MnO₂,CeO₂可优先与SO₂反应,抑制了SO₂对Mn⁴⁺的毒害作用,从而提高了抗硫性能.     

Technical feasibility study of an onshore ballast water treatment system

To fulfill the requirements of Guidelines for approval of ballast water management system (G8), a set of onshore ballast water treatment equipment utilizing micro-pore ceramic filtration (MPCF) and UV radiation (MPCF&UV) system was designed and set up with a maximum flow rate of 80 m³·h^-1. Technical feasibilities of MPCF&UV system were evaluated in three areas: removal efficiencies of indicator organism and oceanic bacteria, perdurability of a ceramic filter, and application on native seawater. The results showed that no indicator organism (Dunaliella) or oceanic bacteria was detected after treatment of 20 L MPCF and UV radiation at 1.3× 10⁴ μW·s·cm^-2. A 20 L ceramic filter can run continuously for 5.3 h at the flow rate of 15 m³·h^-1 before its pressure drop up to 0.195 MPa. The removal percentage of total plankton amounts were 91.9% at a flow rate of 70 m³·h^-1 by 80 L MPCF and UV radiation at 1.3× 10⁴ μW·s·cm^-2.     

淮南矿区高矿化度矿井水淡化工艺实例

为充分利用水资源,提高矿井水回用率,淮南矿区谢桥煤矿对高矿化度矿井水进行淡化处理。根据现场运行数据、现场试验,简述了高矿化度矿井水应用反渗透(RO)工艺过程和淡化技术要领。工程运行结果表明:反渗透工艺在煤矿高矿化度矿井水淡化处理中产生了良好的经济、社会和环境效益。