磷酸铵镁沉淀法预处理垃圾渗滤液

探讨了用磷酸铵镁沉淀法预处理垃圾渗滤液时,沉淀剂种类、pH值、物质摩尔配比和反应时间等因素对氨氮去除效果的影响。得出了处理氨氮浓度为2 677.34 mg/L的垃圾渗滤液时,在兼顾所用镁盐量尽量低和处理出水氨氮或磷酸盐的残留量都比较低的较佳实验条件为:沉淀剂种类为:MgSO4.7H2O和Na2HPO4.12H2O,反应时间为20 min,pH=9.5,n(Mg)∶n(P)∶n(N)=1.3∶1.15∶1.0。在较佳实验条件下,垃圾渗滤液的NH3-N去除率为97.05%,处理出水PO34--P含量为8.35 mg/L,NH3-N含量为75.86 mg/L。对所得沉淀物进行了成分分析和X-衍射光谱、扫描电镜表征,表明大部分沉淀物为磷酸铵镁物质。     

吹扫捕集气质联用测定水中嗅味物质的研究

文章建立了一种用吹扫捕集—气相色谱质谱联用技术测定饮用水中土臭素(GSM)和二甲基异冰片(2-MIB)等嗅味物质的分析方法,确定了最佳的色谱条件、质谱条件和水样处理方法。当取样量为25mL时,回收率分别为96%和89%,RSD<10%,检出限为0.002mg/L。     

喜凉作物生长期对全球变暖停滞响应的时空差异——以中国绿洲为例

基于中国绿洲喜凉作物（chimonophilous crop）分布区39个站点1960~2016年逐日平均气温资料,运用线性趋势法、反距离加权插值（IDW）、Morlet小波、Mann-Kendall检验等方法,研究中国绿洲喜凉作物气候生长期的时空变化对变暖停滞的响应.结果表明：①变暖停滞期,中国绿洲喜凉作物气候生长期起、止日及生长期日数以-0.2d/10a、0.33d/10a、0.53d/10a的趋势变化,较1960~2016年起始日提前趋势减缓1.01d/10a,终止日推迟减缓1.28d/10a,生长期日数延长减缓2.3d/10a,对变暖停滞有响应.②中国绿洲喜凉作物气候生长期起始日对变暖停滞响应的站点有44%,终止日和生长期日数均为49%,主要分布在南疆、柴达木盆地和河西绿洲,其中河西绿洲对变暖停滞响应最明显,南疆次之,柴达木最小,而北疆绿洲不存在滞缓现象,显然空间差异明显.③M-K检验显示,中国绿洲喜凉作物气候生长期起、止日及生长期日数分别在2001年、1990年和1997年发生突变,起始日晚于变暖停滞起始年份,终止日和生长期日数早于变暖停滞起始年,且分绿洲生长期日数突变年与变暖停滞起始年相接近.④Morlet小波得出变暖停滞期其变化稳定存在2.4~4.3a的震荡周期,表明未来几年中国绿洲喜凉作物气候生长期仍持续延长.     

The role of doped-Mn on enhancing arsenic removal by MgAl-LDHs

To meet the challenges posed by global arsenic water contamination, the MgAlMn-LDHs with extraordinary efficiency of arsenate removal was developed. In order to clarify the enhancement effect of the doped-Mn on the arsenate removal performance of the LDHs, the cluster models of the MgAlMn-LDHs and MgAl-LDHs were established and calculated by using density functional theory (DFT). The results shown that the doped-Mn can significantly change the electronic structure of the LDHs and improve its chemical activity. Compared with the MgAl-LDHs that without the doped-Mn, the HOMO-LUMO gap was smaller after doping. In addition, the -OH and Al on the laminates were also activated to improve the adsorption property of the LDHs. Besides, the doped-Mn existed as a novel active site. On the other hand, the MgAlMn-LDHs with the doped-Mn, the increased of the binding energy, as well as the decreased of the ion exchange energy of interlayer Cl⁻, making the ability to arsenate removal had been considerably elevated than the MgAl-LDHs. Furthermore, there is an obvious coordination covalent bond between arsenate and the laminates of the MgAlMn-LDHs that with the doped-Mn.     

某些芳香化合物生物降解性研究

研究了５类３２种芳香化合物生物降解性，选用城市污水场污泥富集的混合菌种做菌源，在好氧生物解实验条件下，苯甲酸类、苯酚类和甲苯是较容易降解的；苯和苯的同系物是可生物降解的；苯磺酸类和含氮芳氮芳香化合物均是难降解的。     

污泥静态好氧发酵中堆体板结与通风的研究

为研究污泥静态好氧发酵中板结对强制通风和发酵进程的影响,降低通风能耗,基于理论研究确定了压降为强制通风风量的决定性因素,并通过实验获取不同发酵阶段和强制通风条件下的堆体通风量和抗剪强度数据,分析堆体内板结的形成规律,通过计算验证板结的形成和消失对通风的影响,提出了需要改善通风的时间节点;然后基于风机的变频控制研究了风机功率变化对强制通风的影响。提出的通风解决方案采用阶段变频通风,实现了堆体温度和通风风量的有效控制。     

河流枯水流量特征研究

本文以泾、洛、渭三河流干流在陕西境内的主要控制断面为例,分析了１４个时段枯水流量的概率分布特征,选定了理论分布线型,揭示了各枯水序列的时段平均流量均值、变差系数和偏态系数的变化规律,建立了推求不同频率不同时段的枯水流量的经验公式。绘制了相应的关系曲线,应用十分方便。     

Seasonal variation and size distribution of biogenic secondary organic aerosols at urban and continental background sites of China

Size-resolved biogenic secondary organic aerosols(BSOA) derived from isoprene and monoterpene photooxidation in Qinghai Lake, Tibetan Plateau(a continental background site) and five cities of China were measured using gas chromatography/mass spectrometry(GC/MS). Concentrations of the determined BSOA are higher in the cities than in the background and are also higher in summer than in winter. Moreover, strong positive correlations(R2= 0.44–0.90) between BSOA and sulfate were found at the six sites,suggesting that anthropogenic pollution(i.e., sulfate) could enhance SOA formation,because sulfate provides a surface favorable for acid-catalyzed formation of BSOA. Size distribution measurements showed that most of the determined SOA tracers are enriched in the fine mode( 3.3 μm) except for cis-pinic and cis-pinonic acids, both presented a comparable mass in the fine and coarse( 3.3 μm) modes, respectively. Mass ratio of oxidation products derived from isoprene to those from monoterpene in the five urban regions during summer are much less than those in Qinghai Lake region. In addition, in the five urban regions relative abundances of monoterpene oxidation products to SOA are much higher than those of isoprene. Such phenomena suggest that BSOA derived from monoterpenes are more abundant than those from isoprene in Chinese urban areas.     

Effects of organic matter on Leymus chinensis germination,growth, and urease activity and available nitrogen in coastal saline soil

ABSTRACT

The present study was carried out to investigate the effect of three organic matters (stalk powder, microbial fertilizer, and manure) on Leymus chinensis germination, growth, and urease activity and available nitrogen (N) in coastal saline soil. The study was conducted in a completely randomized design with eight treatments: J₀V₀Y₀, J₁V₀Y₀, J₀V₁Y₀, J₀V₀Y₁, J₁V₁Y₀, J₁V₀Y₁, J₀V₁Y₁, J₁V₁Y₁. The notations were based on the quantities of each agent added to 1 kg of coastal saline soil: J₀ – no straw powder, J₁ – 0.2 kg straw powder, Y₀ – no manure, Y₁ – 0.3 kg manure, V₀ – no microbial fertilizer, V₁ – 0.2 L microbial fertilizer, each in quantic repeat. L. chinensis was sown as 50 seeds per pot. Results indicated that addition of organic agents exerted a significantly enhanced germination, increase in fresh weight and elevated soil urease activity. Soil available N levels were significantly positively correlated with soil urease activity and fresh weight, but not with germination rate. It is noteworthy that the halophyte L. chinensis showed improved characteristics when grown in coastal saline soil with addition of organic amendments.     

轿厢意外移动保护的一种实现方式

主要介绍了电梯的意外轿厢移动保护功能。轿厢意外移动对乘客安全存在巨大隐患，为实现意外移动保护，利用门区及辅助轿门触点构成检测单元；AGSR及BCR检测继电器组合控制UCMR继电器，形成控制单元；UCMR继电器分别控制安全回路及抱闸回路，形成执行单元。