90锶在核排污水域中的分布与监测

本文报告了川江上游核排污水环境中９０ Ｓｒ 的监测结果。表明：９０ Ｓｒ 在河水和底泥中的含量与排污距离密切相关,在不同水生物种之间的蓄积分布有显著性差异,其中底泥和含钙高的生物对９０ Ｓｒ 有较强的浓集作用。所以,选用指示性物种能提高９０ Ｓｒ 监测灵敏度,是核污染监测的较好方法。     

长输管道事故数据库的对比分析

从影响长输管道安全的外部因素、事故定义、事故分类以及事故数据分析和事故报告等几个方面,对国际上主要长输管道事故数据库进行了对比分析,提出了建立我国长输管道事故数据库的建议.     

Recovery of Cu and Fe from Printed Circuit Board waste sludge by ultrasound: Evaluation of industrial application

The paper presents a novel cleaner process for metal recovery from the Printed Circuit Board (PCB) waste sludge by assistance of ultrasound. The process can effectively recover heavy metals at low cost with high separation and recovery efficiency, produce high quality products and also achieve zero waste discharge with operation at industrial scale. With the PCB waste sludge containing (wet content) 3.14–4.85% copper and 3.71–4.23% iron, copper recovery efficiency of 95.2–97.5% and iron recovery efficiency of 97.1–98.5% were achieved, while the purity of copper sulfate produced by the process was 98.0% and the produced ferric chloride had a satisfied quality for using as a coagulant material for the plant on-site wastewater treatment. The process had been successfully scaled up to the industrial scaled applications in a heavy metal recovery plant in city of Huizhou, China for more than two years. The novel cleaner heavy metal recovery process has a great prospect on the applications of resources recovery and environmental protection practices.     

长江三峡花岗岩地区土壤流失时间分布特性

长江三峡花岗岩地区坡面土壤流失以耕地砂砾化面蚀和有部分植物覆盖坡面的鳞片状面蚀为主，该地土壤流失研究结果表明，由以上两类面蚀导致的土壤流失量月分布与月降雨量的分布基本趋势一致，二者呈现较为明显的线性相关关系。地面坡度＞３０°的裸地土壤流失量达５０００ｔ／ｋｍ３·ａ以上，覆盖度≥０．７０的林地土壤流失量＜５００ｔ／ｋｍ２·ａ，该流域土壤流失量为１５４４．１４ｔ／ｋｍ２·ａ，产沙量为６９４．８６ｔ／ｋｍ２·ａ     

催化光度法测定桂林风景点水中痕量铁(Ⅲ)

本文以过氧化氢-甲基红,在活化剂α、α~1-联吡啶存在下,建立了催化光度法测定痕量铁(Ⅲ)的方法,其灵敏度为2.68×10~(-11)gFe(Ⅲ)/ml,线性范围为0～0.6μgFe(Ⅲ)/25ml。用于桂林风景点水中痕量铁测定,结果令人满意。     

Degradation kinetics and mechanism of aniline by heat-assisted persulfate oxidation

Oxidation of aniline by persulfate in aqueous solutions was investigated and the reaction kinetic rates under different temperature, persulfate concentration and pH conditions were examined in batch experiments. The results showed that, the aniline degradation followed pseudo first-order reaction model. Aniline degradation rate increased with increasing temperature or persulfate concentration. In the pH range of 3 to 11, a low aniline degradation rate was obtained at strong acid system (pH 3), while a high degradation rate was achieved at strong alkalinity (pH 11). Maximum aniline degradation occurred at pH 7 when the solution was in a weak level of acid and alkalinity (pH 5, 7 and 9). Produced intermediates during the oxidation process were identified using liquid chromatography-mass spectrometry technology. And nitrobenzene, 4-4’-diaminodiphenyl and 1-hydroxy-1,2-diphenylhydrazine have been identified as the major intermediates of aniline oxidation by persulfate and the degradation mechanism of aniline was also tentatively proposed.     

热水锅炉水冷壁管爆管事故综合分析

对在同一单位的三台热水锅炉发生多起水冷壁管爆管事故进行了综合分析,提出了相应的改进措施。     

中国东南大陆中生代火山岩带的火山岩相类型

本文根据岩浆作用的表现形式、火山喷发方式、搬运方式、堆积环境、成岩过程以及距火山口远近等因素，将岩浆作用产物的岩相类型分为侵入岩相、侵出岩相、火山岩相等三大类十二种岩相类型．并详细阐述了区内火山岩相类型及其时间分布特征。     

中国东南沿海中生代火山作用基本特征

中国东南沿海自晚侏罗世到白垩纪火山活动分为二期、四个旋回,在空间上有迁移性,在时间上与侵入活动呈交替式演变。建立火山碎屑流等五种岩相模式,岩浆爆发占主导地位,同时存在蒸气岩浆爆发。确定破火山口、火山穹隆和锥火山为火山构造基本类型。由火山作用与区域构造作用、沉积作用控制形成火山沉积洼地、火山构造洼地和火山构造隆起。提出不同类型火山构造组合形式和相互演化关系。火山岩系列属高钾钙碱系列,晚期则具双模式性质。它们的地球化学型式兼具大陆边缘和大陆板内双重特性。     

Photocatalytic remediation of γ-HCH contaminated soil induced by α-Fe2O3 and TiO2

Heterogeneous photocatalytic degradation of γ-HCH on soil surfaces was carried out to evaluate the photocatalytic effectiveness of α-Fe2O3 and TiO2 toward degrading γ-HCH on soil surfaces. After being spiked with γ-HCH, soil samples were loaded with α-Fe2O3 or TiO2 and exposed to UV-light irradiation. Different catalyst loads(0%, 2%, 5%, 7%, and 10% (wt). α-Fe2O3; 0%, 0.5%, 1%, 2% wt. TiO2) were tested for up to 7 d irradiation. The effects of soil thickness, acidity, and humic substances were also investigated. The obtained results indicated that the γ-HCH photodegradation follows the pseudo-first-order kinetics. The addition of α-Fe2O3 or TiO2 accelerates the photodegradation of γ-HCH, while the photodegradation rate decreases when the content of α-Fe2O3 exceeds 7%(wt.). The degradation rate increases with the soil pH value. Humic substances inhibit the photocatalytic degradation of γ-HCH. Pentachlorocyclohexene, tetrachlorocyclohexene, and trichlorobenzene are detected as photodegradation intermediates, which are gradually degraded with the photodegradation evolution.