普伐他汀的光催化降解性能及机理研究

通过水热法合成Bi₂WO₆,并利用XPS,XRD,BET,UV-Vis和SEM等方法对样品进行了表征;通过光催化性能实验考察了Bi₂WO₆投加量,溶液pH值对普伐他汀（PR）降解效果的影响;通过自由基捕获实验及中间产物的鉴定探明了Bi₂WO₆光催化降解PR过程的主要活性自由基,中间产物及降解机理,并采用发光细菌急性毒性试验评估了PR降解前后的毒性.结果表明,所制备的Bi₂WO₆是由大量纳米片组成的正交晶系花瓣状微球,各元素物质的量比为Bi：W：O=2.5：1：6.7,比表面积为26.67m²/g,带隙能为2.74eV;光催化性能结果表明,对于10mg/L PR,当溶液pH=6.5,Bi₂WO₆投加量为0.4g/L时降解效果最佳,降解率可达80.6%,矿化度为40.2%;自由基捕获实验结果表明降解过程中h⁺起主要的氧化作用,·OH和·O₂^-的氧化起辅助作用.基于活性自由基和中间产物的鉴别结果提出了Bi₂WO₆光催化降解PR的机理,即以h⁺为主,·OH和·O₂^-为辅联合攻击PR分子中C－C键,C＝C双键,酯键等化学键,进而将其分解为易降解小分子有机物.另外,毒性测试结果表明PR经光催化降解后的小分子产物与PR原液相比毒性并没有增强.     

青年群体对传统绿色生态文化回归的影响研究

传统方法对青年群体绿色生态文化回归的影响分析中,存在青年群体分析影响片面,影响分析计算准确率较低的问题。为此提出青年群体对传统绿色生态文化回归的影响与思考。通过勒布朗斯回归数学影响方程确定影响因子,建立青年群体主观因子与客观因子之间的动态关联;采用大数据分析,构建大数据影响因子数据分析模型;依托绿色生态文化回归影响算法,从而完成青年群体对传统绿色生态文化回归的影响分析。该影响分析方法比传统方法平均准确度提升3.55倍,且能够实现青年群体对传统绿色生态文化回归的影响分析。     

Attributes of reliable long-term landscape-scale studies: Malpractice insurance for landscape ecologists

Monitoring long-term change in forested landscapes is an intimidating challenge with considerable practical, methodological, and theoretical limitations. Current field approaches used to assess vegetation change at the plot-to-stand scales and nationwide forest monitoring programs may not be appropriate at landscape scales. We emphasize that few vegetation monitoring programs (and, thus, study design models) are designed to detect spatial and temporal trends at landscape scales. Based primarily on advice from many sources, and trial and error, we identify 14 attributes of a reliable long-term landscape monitoring program: malpractice insurance for landscape ecologists. The attributes are to: secure long-term funding and commitment; develop flexible goals; refine objectives; pay adequate attention to information management; take an experimental approach to sampling design; obtain peer-review and statistical review of research proposals and publications; avoid bias in selection of long-term plot locations; insure adequate spatial replication; insure adequate temporal replication; synthesize retrospective, experimental, and related studies; blend theoretical and empirical models with the means to validate both; obtain periodic research program evaluation; integrate and synthesize with larger and smaller scale research, inventory, and monitoring programs; and develop an extensive outreach program. Using these 14 attributes as a guide, we describe one approach to assess the potential effect of global change on the vegetation of the Front Range of the Colorado Rockies. This self-evaluation helps identify strengthes and weaknesses in our program, and may serve the same role for other landscape ecologists in other programs.     

环境水样中痕量砷(Ⅲ)的荧光动力学分析

基于酸性介质中As(Ⅲ)能催化碘酸钾氧化丁基罗丹明B使其荧光猝灭,建立了测定痕量As(Ⅲ)的新方法。在最佳实验条件下,测定As(Ⅲ)的线性范围为16~320ng/ml,方法的检出限为5·7ng/ml。平行测定浓度为80ng/ml和160ng/ml的As(Ⅲ)标准溶液的相对标准偏差分别为2·0%和0·92%。并考察了二十多种物质的干扰情况。该方法已用于自来水、地表水、地下水等环境水样中痕量As(Ⅲ)分析。     

沿江施工产生悬浮物对环境影响分析

通过对太仓港围滩吹填工程施工过程泥浆水的采样分析，研究涉及工程施工过程泥浆扩散和演变规律；进而评价吹填工程施工引起悬浮物的增加对水质、水生生物和鱼类的影响。     

绿色制造评价系统与评价方法的研究及应用

 绿色制造是实现可持续发展的必然选择.绿色制造评价是保证工业产品制造“绿色程度”的关键技术.本文论述了绿色制造及其评价系统和评价方法,并通过实例验证了该评价系统的可行性和实用性.     

哈尔滨市交通噪声监测与评价

本文结合哈尔滨市历年交通噪声的状况及变化趋势,探讨了其近几年交通噪声的状况,并对部分路段进行了实际监测.根据调查结果和实际监测结论,本文综合系统地分析了哈尔滨市交通噪声强度和主要影响因素的发展变化趋势,对哈尔滨市交通噪声进行了初步评价,提出了全市交通噪声控制对策.     

无盘网络系统的介绍和应用

无盘网络系统是一种很适合在计算机配置较固定、软件程序较划一的网络环境中运行的网络系统,随着电脑教育的规模扩大,网络教室的普及,发展也非常快.本文简述了其产生环境、功能介绍,针对其优势和不足说明了无盘网络系统的应用前景是非常广阔的.     

Mechanics Principle and Engineering Application of Split Layer and Bed Separation of Mining Overburden

<正>To control land surface subsidence caused the underground mineral exploitation and the catastrophic phenomena such as serious damage of buildings, waterbodies, cultivated lands, railways, bridges caused by land subsidence, bed separation grouting technology of overburden is put forward. To provide theoretical support for the technology, the characteristics and the mechanics mechanism of mining overburden from layer-split to formation of bed separation are studied. On the basis of elastic sheet board theory, calculation formula of rock sheet deflection is presented, and the mechanics criteria of the separation formation and the calculation formula of bed separation volume are set up. Finally, the applications and technics of bed separation grout technology of mining overburden to control land subsidence in china are introduced.     

分散式小区污水回用分析研究

污水回用处理可分为分散式和集中式,本文着重就分散式小区污水回用处理模式进行探讨,比较分析国内外典型国家或城市的技术和应用现状,在此基础上,指出我国分散式小区污水回用模式当前实施存在的问题及今后的发展趋势.