Variations in pesticide leaching related to land use, pesticide properties, and unsaturated zone thickness

Pesticide leaching through variably thick soils beneath agricultural fields in Morgan Creek, Maryland was simulated for water years 1995 to 2004 using LEACHM (Leaching Estimation and Chemistry Model). Fifteen individual models were constructed to simulate five depths and three crop rotations with associated pesticide applications. Unsaturated zone thickness averaged 4.7 m but reached a maximum of 18.7 m. Average annual recharge to ground water decreased from 15.9 to 11.1 cm as the unsaturated zone increased in thickness from 1 to 10 m. These point estimates of recharge are at the lower end of previously published values, which used methods that integrate over larger areas capturing focused recharge in the numerous detention ponds in the watershed. The total amount of applied and leached masses for five parent pesticide compounds and seven metabolites were estimated for the 32-km2 Morgan Creek watershed by associating each hectare to the closest one-dimensional model analog of model depth and crop rotation scenario as determined from land-use surveys. LEACHM parameters were set such that branched, serial, first-order decay of pesticides and metabolites was realistically simulated. Leaching is predicted to be greatest for shallow soils and for persistent compounds with low sorptivity. Based on simulation results, percent parent compounds leached within the watershed can be described by a regression model of the form e(-depth) (a ln t1/2-b ln K OC) where t1/2 is the degradation half-life in aerobic soils, K OC is the organic carbon normalized sorption coefficient, and a and b are fitted coefficients (R2 = 0.86, p value = 7 x 10(-9)).     

Simulated fate and transport of metolachlor in the unsaturated zone, Maryland, USA

An unsaturated-zone transport model was used to examine the transport and fate of metolachlor applied to an agricultural site in Maryland, USA. The study site was instrumented to collect data on soil-water content, soil-water potential, ground water levels, major ions, pesticides, and nutrients from the unsaturated zone during 2002-2004. The data set was enhanced with site-specific information describing weather, soils, and agricultural practices. The Root Zone Water Quality Model was used to simulate physical, chemical, and biological processes occurring in the unsaturated zone. Model calibration to bromide tracer concentrations indicated flow occurred through the soil matrix. Simulated recharge rates were within the measured range of values. The pesticide transport model was calibrated to the intensive data collection period (2002-2004), and the calibrated model was then used to simulate the period 1984 through 2004 to examine the impact of sustained agricultural management practices on the concentrations of metolachlor and its degradates at the study site. Simulation results indicated that metolachlor degrades rapidly in the root zone but that the degradates are transported to depth in measurable quantities. Simulations indicated that degradate transport is strongly related to the duration of sustained use of metolachlor and the extent of biodegradation.     

Forest Cover Change,Physiography, Local Economy,and Institutions in a Mountain Watershed in Nepal

This study assessed changes in forest cover in a mountain watershed in central Nepal between 1976 and 2000 by comparing classified satellite images coupled by GIS analyses, and examined the association of forest change with major physiographic, economic, and local forest governance parameters. The results showed an increase in forested area (forest plus shrublands) by 7.6% during 1976–2000. Forest dynamism (changes including improvement, deterioration, gain, and loss) was highest in low-elevation, south-facing and less-steep slopes that were closer to roads. Proportionately the highest net improvement and gain to forested area also took place in those locations. Forest degradation occurred at twice the rate of improvement in high elevation areas (> 2300 m). Forests located in urban and semiurban areas (i.e., a market-oriented economy) experienced a proportionately higher amount of net improvement and gain than forests in rural areas (i.e., a subsistence economy). Among the three governance arrangements, proportionately the highest net improvement and gain took place in semigovernment forests (forested area legally under the forest department but with de facto control and claim of ownership by local communities and/or municipality) followed by formalized community forests (including leasehold). Government forests, which were mostly found in the southern high mountains and had virtually open access, remained relatively stable during the study period. Over 50% of the watershed forests have not come under community-based management despite favorable policy and more than two decades of government intervention with continuous donor support. The findings indicate that the present one size fits all approach of community forest handover policy in Nepal needs rethinking to accommodate biophysical and socioeconomic variations across the country.     

Integrating social preference in GIS-aided planning for forestry and conservation activities: a case study from rural SE Asia

Land-use planning using geographic information systems (GIS) commonly emphasizes biophysical spatial data; however planning can be improved by integrating spatial sets of socioeconomic data into the GIS. As an example, we compared a traditional GIS-aided forestry planning protocol that considered only biophysical suitability, with an integrated GIS-aided approach that incorporated both biophysical and socioeconomic suitability. The analyses were conducted for the planning of plantation investments in the Kyaukpadaung Township in the dry zone of central Myanmar. The traditional approach used three biophysical layers for suitability: land use, slope, and accessibility. In contrast, the integrated GIS approach included biophysical suitability data, perceptions and preferences of local villagers towards forestry (social suitability), and quantitative socioeconomic data. The results indicated that the integrated approach provided two principal benefits over the traditional method. First, the integrated method resulted in a more precise idea of suitable sites for plantation investment that could benefit more rural people and also lead to greater investment efficiency. Second, incorporating social preference into the GIS takes into account the crucial element of social capital (viz., social preference), which should lead to higher levels of community acceptance of plantation projects because those plantations would be established on socially suitable land. A second GIS exercise showed how conservation investment decisions could be informed using the integrated method. The results of this study support the idea that GIS-aided planning activities can be enhanced through the incorporation of social data into the analysis. When applicable, spatial data collection efforts for GIS-based planning exercises should incorporate spatial socioeconomic data.     

Basic hydrologic studies for assessing impacts of flow diversions on riparian vegetation: Examples from streams of the eastern Sierra Nevada,California, USA

As the number of proposals to divert streamflow for power production has increased in recent years, interest has grown in predicting the impacts of flow reductions on riparian vegetation. Because the extent and density of riparian vegetation depend largely on local geomorphic and hydrologic setting, site-specific geomorphic and hydrologic information is needed. This article describes methods for collecting relevant hydrologic data, and reports the results of such studies on seven stream reaches proposed for hydroelectric development in the eastern Sierra Nevada, California, USA. The methods described are: (a) preparing geomorphic maps from aerial photographs, (b) using well level records to evaluate the influence of streamflow on the riparian water table, (c) taking synoptic flow measurements to identify gaining and losing reaches, and (d) analyzing flow records from an upstream-downstream pair of gages to document seasonal variations in downstream flow losses. In the eastern Sierra Nevada, the geomorphic influences on hydrology and riparian vegetation were pronounced. For example, in a large, U-shaped glacial valley, the width of the riparian strip was highly variable along the study reach and was related to geomorphic controls, whereas the study reaches on alluvial fan deposits had relatively uniform geomorphology and riparian strip width. Flow losses of 20% were typical over reaches on alluvial fans. In a mountain valley, however, one stream gained up to 275% from geomorphically controlled groundwater contributions.     

The analysis of flue gas treatment residues using non-destructive X-ray fluorescence as a regulatory compliance test

Current and proposed European Union (EU) regulations require the residual material from municipal solid waste incineration to be characterised prior to disposal. X-Ray fluorescence (XRF) provides a rapid and non-destructive technique for analysing such materials.     

Small-scale temporal variation and the effect of urbanisation on extracellular enzyme activity in streams

The activity of six extracellular enzymes involved in the degradation of dissolved organic carbon compounds was measured in two highly urbanised and two minimally impacted streams east of Melbourne, Australia, using 4-methylumbelliferyl-substrates. Small-scale temporal variation in enzyme activity was determined by repeatedly sampling the same point in the water column, while the effect of flow was determined by sampling in regions of higher and lower flow in both stream types. Replicate samples showed that enzyme activity was not significantly different over small (minutes) time scales. On five of six sampling occasions the enzyme activity was unaffected by flow. On one sampling occasion in a minimally disturbed stream, the difference between the high- and low-flow regions was statistically significant (ANOSIM, Global R= 0.78, P= 0.03). Enzyme activity profiles (activities of the suite of enzymes) of the streams in urbanised catchments were different to those in minimally disturbed catchments. The measurements made in four different streams showed high reproducibility over short time periods (minutes) which lends greater credibility to analogous spatial studies. Although these results determined that small-scale temporal variability was not significant, and that the effects of flow were generally minimal, it is recommended that spatial and temporal variability in the stream be at least considered before any studies measuring extracellular enzyme activity in stream waters are carried out. Such an approach will lead to conclusions from measurements that are not likely to be confounded by variables such as flow rate or time.     

Coping with drought and food insecurity in ethiopia

In this article I examine the impact of drought on farm households in Ethiopia and their response to crisis conditions. I ask whether every household in a community is equally affected by drought and what households do to mitigate the effects of drought and associated food insecurity. Information on production, income and food consumption is disaggregated by agroecological zone (highland and lowland), and by socioeconomic strata (relatively wealthy versus poor). Such detailed analysis permits an improved understanding of why the poor are much more vulnerable than the wealthy to drought and associated famines and why they need to be more effectively targeted by relief and development interventions. In a world of limited public resources for crisis intervention, such understanding is crucial to the design of improved policies and projects for reaching people most at risk.     

Effects of suburban land use on phosphorus fractions and speciation in the Upper Peruque Creek, Eastern Missouri

This field study was conducted to explore the spatial and seasonal changes in total phosphorus and fraction distribution in relation to land uses. Water samples were collected biweekly at four sampling locations, which represented different potential phosphorus sources along the Upper Peruque Creek in Eastern Missouri. Total phosphorus concentrations of > 0.8 mg/L appeared sporadically at site 2, downstream of a small community, with an average of 0.82 +/- 0.14 mg/L in fall. Particulate phosphorus accounted for approximately 80% of total phosphorus at all sampling sites, except for site 2, where approximately 50 to 75% of dissolved phosphorus was often observed. Approximately 71 and 85% of total phosphorus in the sediment was in the form of iron (III) phosphate at the headwaters and downstream sites, respectively; 29 and 15% was in the form of phytic acid at the two sites. Land uses affect the total phosphorus concentration and alternate phosphorus fraction and speciation in the creek.