Longevity of granular iron in groundwater treatment processes: changes in solute transport properties over time

Although progress has been made toward understanding the surface chemistry of granular iron and the mechanisms through which it attenuates groundwater contaminants, potential long-term changes in the solute transport properties of granular iron media have until now received relatively little attention. As part of column investigations of alterations in the reactivity of granular iron, studies using tritiated water (3H(2)O) as a conservative and non-partitioning tracer were periodically conducted to independently isolate transport-related effects on performance from those more directly related to surface reactivity. Hydraulic residence time distributions (HRTDs) within each of six 39-cm columns exposed to bicarbonate solutions were obtained over the course of 1100 days of operation. First moment analyses of the data revealed generally modest increases in mean pore water velocity (v) over time, indicative of decreasing water-filled porosity. Gravimetric measurements provided independent estimates of water-filled porosity that were initially consistent with those obtained from 3H(2)O tracer tests, although at later times, porosities derived from gravimetric measurements deviated from the tracer test results owing to mineral precipitation. The combination of gravimetric measurements and 3H(2)O tracer studies furnished estimates of precipitated mineral mass; depending on the assumed identity of the predominant mineral phase(s), the porosity decrease associated with solute precipitation amounted to 6-24% of the initial porosity. The accumulation of mineral and gas phases led to the formation of regions of immobile water and increased spreading of the tracer pulse. Application of a dual-region transport model to the 3H(2)O breakthrough curves revealed that the immobile water-filled region increased from initially negligible values to amounts ranging between 3% and 14% of the total porosity in later periods of operation. For the aged columns, mobile-immobile mass transfer coefficients (k(mt)) were generally in the range of 0.1-1.0 day(-1) and reflected a slow exchange of 3H(2)O between the two regions. Additional model calculations incorporating sorption and reaction suggest that although changes in HRTD can have an appreciable effect on trichloroethylene (TCE) transformation, the effect is likely to be minor relative to that stemming from passivation of the granular iron surface.     

Response of magnesium-deficient saplings in a young, open stand of Picea abies (L.) Karst. to elevated soil magnesium, nitrogen and carbon

A decline in a Picea abies L. (Karst.) stand in the Fichtelgebirge, NE-Bavaria, FRG has been attributed to a nutritional disharmony-a seasonal imbalance between a high supply of nitrogen, caused by high nitrogen deposition, and a low supply of soil magnesium, caused by soil acidification (Oren et al., 1988a). The nutritional disharmony hypothesis was tested on ten-year-old P. abies saplings in an adjacent stand growing on identical soil. The supply rate of magnesium relative to nitrogen was continuously increased or decreased during three successive growing seasons. Increasing the nitrogen or carbon supply resulted in a small increase in foliar nitrogen concentrations. Magnesium or carbon addition slightly raised the concentration of magnesium in the foliage. Reduction in crown leaf-area did not result in any appreciable changes in nutrient concentrations. Increased N supply decreased foliar Mg concentrations. In spite of the changes in the nutritional status of the needles, gas-exchange rates, pigment concentrations, needle characteristics and growth of twigs and stems did not differ among treatments. It appears that the growth of saplings was unimpaired at the foliar magnesium concentration at which the growth of adjacent mature trees was reduced. Moreover, it was not possible to promote nutritional disharmony in the saplings, including those receiving three times the annual nitrogen input. The study demonstrates that in young, relatively open stands of P. abies, much of the deposited nitrogen is not absorbed by the roots of saplings. Thus, the conceptual model of nutritional disharmony cannot explain forest decline if nitrogen uptake does not increase with deposition. Identifying the processes which control the uptake relative to the supply of all nutrients, and quantifying the rates of nutrient uptake are essential steps in using the conceptual model to explain specific decline symptoms.     

Identification of surrogate compounds for the emission of PCdd/F (I-TEQ value) and evaluation of their on-line real-time detectability in flue gases of waste incineration plants by REMPI-TOFMS mass spectrometry

Correlations between products of incomplete combustion (PIC), e.g., chloroaromatic compounds, can be used to characterise the emissions from combustion processes, like municipal or hazardous waste incineration. A possible application of such relationships may be the on-line real-time monitoring of a characteristic surrogate, e.g., with Resonance-Enhanced Multiphoton Ionization-Time-of-Flight Mass Spectrometry (REMPI-TOFMS). In this paper, we report the relationships of homologues and individual congeners of chlorinated benzenes (PCBz), dibenzo-p-dioxins (PCDD), dibenzofurans (PCDF) and phenols (PCPh) to the International Toxicity Equivalent (I-TEQ) of the PCDD/F (I-TEQ value) in the flue gas and stack gas of a 22 MW hazardous waste incinerator (HWI). As the REMPI detection sensitivity is decreasing with the increase of the degree of chlorination, this study focuses on the lower chlorinated species of the compounds mentioned above. Lower chlorinated species, e.g., chlorobenzene (MCBz), 1,4-dichlorobenzene, 2,4,6-trichlorodibenzofuran or 2,4-dichlorophenol, were identified as I-TEQ surrogates in the flue gas. In contrast to the higher chlorinated phenols, the lower chlorinated phenols (degree of chlorination <4) were not reliable as surrogates in the stack gas. The identified surrogates are evaluated in terms of their detectability by REMPI-TOFMS laser mass spectrometry. The outcome is that MCBz is the best suited surrogate for (indirect) on-line measuring of the I-TEQ value in the flue gas by REMPI-TOFMS. The correlation coefficient r of the MCBz concentration to the I-TEQ in the flue gas was 0.85.     

A novel method for measuring the evaporation of contaminant liquids from sands

A novel experimental system, electrodynamic levitation, is used to measure the evaporation of liquids from microparticles of sand. The levitator is used to measure the evaporation rate of diethylphthalate (DEP) from microparticles of Saudi Arabian sand at 1 atm pressure and 25 degrees C. Evaporation experiments were conducted for both inland- and coastal-sand microparticles, the diameter of which is 50 microm. The DEP-evaporation rate is determined from gravimetric changes in the DEP-sand-mixture particle, the weight of which is directly proportional to the levitating electric-field intensity. From telemicroscopical observations, it is found that, when the sand particle is enclosed in DEP liquid, the sand-DEP-mixture particle evaporates like a pure DEP droplet. However, when sufficient DEP liquid has evaporated and the DEP is adsorbed into the sand microparticle, the DEP evaporation rate is reduced by a factor of 3-5 as compared with a pure DP droplet.     

ENGINEERING A TRANSITION TO COAL

As nations seek alternatives to oil, coal promises to become one of the principal replacement fuels in the world energy system. Engineering a transition to coal and other energy sources from the current reliance on petroleum will be a difficult task requiring a significant commitment of capital, labour, materials, equipment, land and water resources. Engineering this transition to coal will be further complicated by the long lead times that are required. This paper presents an analysis of the timing and magnitude of national resources required to implement several alternative coal development programmes in the United States. Preliminary experience aimed at extending the analysis to international energy and resource relationships is also discussed. Tandis que les nations cherchent à remplacer le pétrole, le charbon est en passe de devenir un des principaux combustibles de remplacement du système énergétique mondial. Assurer une transition à partir de la dépendance actuelle du pétrole vers le charbon et d'autres sources d'énergie s'avérera être difficile et exigera des investissements importants en capitaux, main-d'oeuvre, matériaux, équipement et ressources en terrains et en eau. Effectuer cette transition vers le charbon sera de plus compliqué par les longs délais d'éxécution qui sont requis. Cet article fait l'analyse du calendrier et de l'ampleur des ressources nationales nécessaires à la mise en valeur de plusieurs programmes de rechange en matière de développement du charbon aux Etats-Unis. On y discute également une expérience préliminaire visant à intégrer l'analyse des rapports internationaux en matière d'énergie et de ressources. En la búsqueda de combustibles alternativos al petróleo, el carbón parece ser la principal alternativa dentro del sistema energético mundial. La adaptación tecnológica al carbón y otros recursos energéticos, partiendo de la dependencia actual en el petróleo, va a ser una tarea difícil que requerirá comprometer importances cantidades de capital, trabajo, equipo, terrenos y recursos de ague. Esta transición al carbón será complicada aún mas por el prolongado lapso necesario para su ejecución. Este artículo presenta un análisis de la programación en el tiempo y la magnitud de los recursos nacionales necesarios para implementar los programas alternatives de desarrollo del carbón en los Estados Unidos. Se discute también experiencias preliminares orientadas a la extensión de este análisis a las relaciones internationales en energía y recursos.     

Die cholinerge Nervenendigung

Progress made in the study of the cellular and molecular function of cholinergic nerve terminals suggests that the textbook schemes need to be extended. Vesicles contained in cholinergic nerve terminals not only store acetylcholine but also ATP and Ca2+ as well as peptides. These substances when co-released by exocytosis may modulate transmission both pre- and postsynaptically.     

Kontinuierliche Druckmessung in Pflanzenzellen

The Science of Nature -     

Effects of sample survey design on the accuracy of classification tree models in species distribution models

We evaluated the effects of probabilistic (hereafter DESIGN) and non-probabilistic (PURPOSIVE) sample surveys on resultant classification tree models for predicting the presence of four lichen species in the Pacific Northwest, USA. Models derived from both survey forms were assessed using an independent data set (EVALUATION). Measures of accuracy as gauged by resubstitution rates were similar for each lichen species irrespective of the underlying sample survey form. Cross-validation estimates of prediction accuracies were lower than resubstitution accuracies for all species and both design types, and in all cases were closer to the true prediction accuracies based on the EVALUATION data set. We argue that greater emphasis should be placed on calculating and reporting cross-validation accuracy rates rather than simple resubstitution accuracy rates. Evaluation of the DESIGN and PURPOSIVE tree models on the EVALUATION data set shows significantly lower prediction accuracy for the PURPOSIVE tree models relative to the DESIGN models, indicating that non-probabilistic sample surveys may generate models with limited predictive capability. These differences were consistent across all four lichen species, with 11 of the 12 possible species and sample survey type comparisons having significantly lower accuracy rates. Some differences in accuracy were as large as 50%. The classification tree structures also differed considerably both among and within the modelled species, depending on the sample survey form. Overlap in the predictor variables selected by the DESIGN and PURPOSIVE tree models ranged from only 20% to 38%, indicating the classification trees fit the two evaluated survey forms on different sets of predictor variables. The magnitude of these differences in predictor variables throws doubt on ecological interpretation derived from prediction models based on non-probabilistic sample surveys.