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排序方式: 共有362条查询结果,搜索用时 31 毫秒
341.
Pueyo M Rauret G Lück D Yli-Halla M Muntau H Quevauviller P López-Sánchez JF 《Journal of environmental monitoring : JEM》2001,3(2):243-250
Sequential extraction procedures have been used during the last decades to study and determine trace element mobility in aquatic sediments. However, the results obtained are operationally defined and, therefore, the significance of the analytical results is related to the extraction scheme used. So, there is a need for suitable reference materials for this type of study to enable the validation of the methodologies and to control the quality of the measurements. This paper describes the preparation of a sediment reference material, BCR-701, the homogeneity and stability studies and the analytical work performed for the certification of the extractable contents of some trace elements, following a collaboratively tested and optimised sequential (three-step) extraction procedure. The paper contains all the results and gives the methods used to certify the extractable contents (mass fractions expressed as mg kg-1 on a dry matter basis) of Cd, Cr, Cu, Ni, Pb and Zn in all steps. Moreover, indicative values are given for the aqua regia extractable contents of the six elements in the sediment and the residue obtained after sequential extraction. 相似文献
342.
《Atmospheric Environment. Part B. Urban Atmosphere》1990,24(1):43-48
Representative driving cycles across the Perth, Western Australia, metropolitan region illustrate a direct relationship to urban land use. Movement away from the central business district results in fewer traffic events, higher speeds, longer cruise periods and shorter stops. The consequent reduction in root mean square acceleration leads to a corresponding reduction in vehicle emission factors. Urban planning implications are pursued and highlight the importance of public transport as an option in reducing urban air pollution. 相似文献
343.
《Atmospheric Environment. Part A. General Topics》1993,27(10):1567-1578
Airborne particulate material contributes significant quantities of trace elements to surface waters. Metals may be partially transferred from airborne particulate material to the aqueous phase while they are still in the atmosphere, but transfer to solution is most important when the particles contact surface waters. In both artificial and natural waters, appreciable fractions of most metals dissolve within minutes. This is followed by a further, slower dissolution over a period of hours or days. Dissolved metals interact with natural organic material and mineral particles. Interactions with organics and metal oxides are now sufficiently understood for them to be modelled by considering surface charges and chemical binding. More measurements on natural systems are required to validate these models and to establish the respective importance and roles of organic and inorganic interactions. Compared to sea water, data on fresh water are scarce. In view of their compositional variability and the relatively high concentrations of trace metals which they often contain, there is an urgent need for systematic investigations of the partitioning of metals in fresh waters. 相似文献
344.
Rubiano ME Agulló-Barceló M Casas-Mangas R Jofre J Lucena F 《Environmental science and pollution research international》2012,19(4):1026-1032
Purpose
Need, coupled with advances in water treatment technology, is motivating a growing interest in augmenting drinking water supplies with reclaimed water. Using reclaimed water to increase the flow of the Llobregat River upstream the water catchment site of the complex multi-step drinking water treatment plant of Sant Joan Despí has been considered. The impact of reclaimed water discharges on the load of E. coli, spores of sulphite-reducing clostridia, somatic coliphages, cytopathogenic enteroviruses, and total and infectious Cryptosporidium oocysts in the Llobregat River water was assessed to gain information for funded decisions in potential future emergencies. 相似文献345.
Llorente-Mirandes T Ruiz-Chancho MJ Barbero M Rubio R López-Sánchez JF 《Chemosphere》2010,81(7):867-875
The determination of arsenic compounds in algae collected on the Catalan coast (Western Mediterranean) is reported. Ten algae species and the seagrass Posidonia oceanica were analyzed. Total arsenic in the samples was determined by microwave digestion and inductively coupled plasma mass spectrometry (ICPMS). Arsenic speciation in water extracts of samples was analyzed by liquid chromatography with both anionic and cationic exchange with ICPMS detection (LC-ICPMS). The total arsenic content of the algae samples ranged from 2.96 to 39.0mg As kg(-1). The following compounds were detected: arsenite (As(III)), arsenate (As(V)), methylarsonate (MA), dimethylarsinate (DMA), sulfonate sugar (SO3-sug), sulfate sugar (SO4-sug), phosphate sugar (PO4-sug), arsenobetaine (AB), arsenocholine (AC), trimethylarsine oxide (TMAO) and glycerol sugar (Gly-sug). The main arsenic species found were arsenosugars. Significant percentages of arsenobetaine (0.54 mg As kg(-1), 28% of the extractable arsenic and 0.39 mg As kg(-1), 18% of the extractable arsenic) were found in Ulva rigida and Enteromorpha compressa. These results are discussed in relation to the presence of epiphytes. 相似文献
346.
Mário Cerqueira Daniel Marques Alexandre Caseiro Casimiro Pio 《Atmospheric environment (Oxford, England : 1994)》2010,44(6):867-871
An apartment bedroom located in a residential area of Aveiro (Portugal) was selected with the aim of characterizing the cellulose content of indoor aerosol particles. Two sets of samples were taken: (1) PM10 collected simultaneously in indoor and outdoor air; (2) PM10 and PM2.5 collected simultaneously in indoor air. The aerosol particles were concentrated on quartz fibre filters with low-volume samplers equipped with size selective inlets. The filters were weighed and then extracted for cellulose analysis by an enzymatic method. The average indoor cellulose concentration was 1.01 ± 0.24 μg m?3, whereas the average outdoor cellulose concentration was 0.078 ± 0.047 μg m?3, accounting for 4.0% and 0.4%, respectively, of the PM10 mass. The corresponding average ratio between indoor and outdoor cellulose concentrations was 11.1 ± 4.9, indicating that cellulose particles were generated indoors, most likely due to the handling of cotton-made textiles as a result of routine daily activities in the bedroom. Indoor cellulose concentrations averaged 1.22 ± 0.53 μg m?3 in the aerosol coarse fraction (determined from the difference between PM10 and PM2.5 concentrations) and averaged 0.38 ± 0.13 μg m?3 in the aerosol fine fraction. The average ratio between the coarse and fine fractions of cellulose concentrations in the indoor air was 3.6 ± 2.1. This ratio is in line with the primary origin of this biopolymer. Results from this study provide the first experimental evidence in support of a significant contribution of cellulose to the mass of suspended particles in indoor air. 相似文献
347.
Steven Trabue Kenwood Scoggin Hong Li Robert Burns Hongwei Xin Jerry Hatfield 《Atmospheric environment (Oxford, England : 1994)》2010,44(29):3538-3546
Volatile organic compounds (VOCs) emitted from poultry production are leading source of air quality problems. However, little is known about the speciation and levels of VOCs from poultry production. The objective of this study was the speciation of VOCs from a poultry facility using evacuated canisters and sorbent tubes. Samples were taken during active poultry production cycle and between production cycles. Levels of VOCs were highest in areas with birds and the compounds in those areas had a higher percentage of polar compounds (89%) compared to aliphatic hydrocarbons (2.2%). In areas without birds, levels of VOCs were 1/3 those with birds present and compounds had a higher total percentage of aliphatic hydrocarbons (25%). Of the VOCs quantified in this study, no single sampling method was capable of quantifying more than 55% of compounds and in several sections of the building each sampling method quantified less than 50% of the quantifiable VOCs. Key classes of chemicals quantified using evacuated canisters included both alcohols and ketones, while sorbent tube samples included volatile fatty acids and ketones. The top five compounds made up close to 70% of VOCs and included: 1) acetic acid (830.1 μg m?3); 2) 2,3-butanedione (680.6 μg m?3); 3) methanol (195.8 μg m?3); 4) acetone (104.6 μg m?3); and 5) ethanol (101.9 μg m?3). Location variations for top five compounds averaged 49.5% in each section of the building and averaged 87% for the entire building. 相似文献
348.
To better understand how Batrachupems tibetanus responds to different temperature regimes in the blood parameters and to estimate the change in plasma cortisol level in
this species exposed to different temperatures, the animals were stochastically divided into three groups and exposed respectively
to 4.6°C, 14.6°C and 19.6°C for 12 days. The concentrations of glucose, total protein, albumin, triacylglycerol, Ca2+, K+, Na+, Cl−, and plasma cortisol level were measured respectively. There was no significant difference between the plasma cortisol level
of the control group and the experiment groups. Glucose level at 4.6°C and 19.6°C was significantly lower than glucose level
at 14.6°C. The plasma triacylglycerol level was significantly influenced by acclimation temperature. The concentration of
total protein, albumin, globulin and the ratio between albumin and globulin were not significantly influenced by temperature
when compared with control group. There was no significant change in concentration of Ca2+ at different temperatures. The concentration of K+ was significantly influenced by temperature. Plasma K+ level significantly increased at 19.6°C. The plasma Na+ level and Cl− were significantly influenced by temperature. Na+: Cl− ratio was significantly influenced by temperature. Therefore, glucose, triacylglycerol, Na+ and Cl− levels could be considered as indicators of thermal stress in B. tibetanus; plasma cortisol, albumin, globulin levels, and albumin/globulin ratio are not influenced by temperature. 相似文献
349.
José L. Nava Ignasi Sirés Enric Brillas 《Environmental science and pollution research international》2014,21(14):8485-8492
This paper compares the performance of 2D (plate) and 3D (mesh) boron-doped diamond (BDD) electrodes, fitted into a filter-press reactor, during the electrochemical incineration of indigo textile dye as a model organic compound in chloride medium. The electrolyses were carried out in the FM01-LC reactor at mean fluid velocities between 0.9?≤?u?≤?10.4 and 1.2?≤?u?≤?13.9 cm s?1 for the 2D BDD and the 3D BDD electrodes, respectively, at current densities of 5.63 and 15 mA cm?2. The oxidation of the organic matter was promoted, on the one hand, via the physisorbed hydroxyl radicals (BDD(●OH)) formed from water oxidation at the BDD surface and, on the other hand, via active chlorine formed from the oxidation of chloride ions on BDD. The performance of 2D BDD and 3D BDD electrodes in terms of current efficiency, energy consumption, and charge passage during the treatments is discussed. 相似文献
350.
Eva Gorrochategui Josefina Casas Elisabet Pérez-Albaladejo Olga Jáuregui Cinta Porte Sílvia Lacorte 《Environmental science and pollution research international》2014,21(20):11907-11916
The aim of this study was to develop a method based on ultra high performance liquid chromatography coupled with mass spectrometry (UHPLC-MS) for lipid profiling in human placental choriocarcinoma (JEG-3) cells. Lipids were solid–liquid extracted from JEG-3 cells using a solution of chloroform/methanol (2:1, v/v) in a simple procedure requiring minimal sample alteration. Simultaneous separation of complex lipid mixtures in their major classes was achieved with a reversed-phase (C8) UHPLC column and a mobile phase containing methanol with 1 mM ammonium formate and 0.2 % formic acid (A)/water with 2 mM ammonium formate and 0.2 % formic acid (B). Lipids were characterized using time-of-flight (TOF) and Orbitrap under full scan and positive electrospray ionization mode with both analyzers. A total of 178 species of lipids, including 37 phosphatidylcholines (PC), 32 plasmalogen PC, 9 lyso PC, 4 lyso plasmalogen PC, 30 triacylglycerols, 22 diacylglycerols, 7 cholesterol esters, 25 phosphatidylethanolamines, and 12 sphingomyelins, were identified using TOF and Orbitrap. The identification of all lipid classes was based on exact mass characterization with an error < 5 ppm. The developed methodology was applied to study lipid alterations in human placental cells against the exposure to perfluorinated chemicals (PFCs) and tributyltin (TBT). 相似文献