Steady-state modelling of hydroxyl radical concentrations at Mace Head during the EASE ’97 campaign,May 1997

Two different steady-state methods are applied to calculate OH radical concentrations based on the rates of known source and sink processes. The first method, which calculates only OH radical concentrations from measured data including HO₂ gives good correlation with measured OH concentrations but overpredicts by 30%. The second method applied calculates OH, HO₂ and RO₂ radical concentrations simultaneously. This second method overestimates the measured concentrations of OH by almost 3 times. This apparent overprediction may be a result of calculated concentrations of HO₂ which appear too high and may be indicative of a gap in our understanding of the relevant peroxy radical chemistry or a result of the limited peroxy radical chemistry assumed by the method.     

Feeding capabilities and limitation of herbivorous molluscs: A functional group approach

The susceptibility of an alga to an herbivorous mollusc depends, in part, upon the size and toughness of the plant relative to the feeding ability of the mollusc. In this study, algae are subdivided into seven functional groups based on these and other physiological characteristics. Herbivorous prosobranchs and chitons are subdivided into four functional groups based on the structure of their feeding apparatus. Distinct patterns in the diets of these molluscs are evident when feeding data, based on these functional groups, are examined. Most herbivorous mollusc species eat algal forms that are either minute (i.e., micro- and filamentous algae) or very large and expansive (kelp-like or crustose algae). Algae of intermediate size (erect forms 1- to 10-cm tall) are eaten to a lesser extent, possibly because they are too large to be rasped from the substratum and too small for most herbivores to occupy. Herbivorous archaeogastropods (excluding limpets) and mesogastropods tend to eat filamentous and microscopic algal forms predominantly, whereas limpets and chitons feed on large, leathery and crustose algae. These dietary differences reflect functional differences in the feeding apparatus of these herbivore groups. Radulae of herbivorous mesogastropods function like rakes and can ingest larger, tougher algae than can radulae of nonlimpet archaeogastropods. The latter function more like brooms by sweeping the substratum broadly, but exerting little force. Limpets and chitons have superior excavating abilities because their radulae have: robust buccal muscles surrounding them, a reduced number of points of contact on the substratum, and minerally hardened teeth. The feeding apparatus of chitons is most versatile since it possesses features found in all herbivorous gastropod functional groups, and thus, it can sweep and excavate simultaneously. This functional group approach suggests various hypotheses concerning algal community structure, plant/herbivore and herbivore/herbivore interactions, the relative importance of structural defenses in algae, and the evolution of specialized grazers. These hypotheses are examined using data from published accounts.     

Can boreal afforestation help offset incompressible GHG emissions from Canadian industries?

To mitigate greenhouse gas and comply with cap-and-trade systems, the carbon capture and storage (CCS) is presently unviable for industrials dealing with low concentration of CO₂ emissions. Alternatively, a new offset opportunity is being analysed in Canada: the afforestation of open woodlands (OWs) in the boreal territory. The results obtained from model simulations (with CBM-CFS3) showed that afforestation of boreal OWs can be a low C-intensive mitigation activity, in particular when understory planting is the chosen silvicultural approach, so that only 8–12 years are needed to reach a net positive C balance with the afforestation of OWs. A large-scale afforestation of boreal OWs – scheduled at 20 kha per year during 20 years for a maximum of 400 kha – could provide capped industrials with a significant offset potential, for instance up to nearly 8% offset of all Québec industrial process emissions (2009 data) after 45 years. In spite of a certain number of issues that can contribute to the uncertainty of the real environmental and economical benefits from the afforestation of OWs as a mitigation activity – most of which issues are discussed in this paper – this study presented a first glimpse at the extent to which the afforestation of boreal OWs in Québec can provide large emitters with eventually substantial and efficient GHG offset potential, especially those emitters tied up with incompressible GHG emissions.     

Comprehensive sensitivity analysis of an SO2 deposition model for three measurement sites: Consequences for SO2 deposition fluxes

A parameterization for the dry deposition of SO₂ is evaluated by means of four statistical sensitivity studies using a sampling-based approach to sensitivity analysis. Measurements over a heathland, grassland and coniferous forest are used to identify those meteorological and vegetation-specific factors which drive the deposition component of the model (model-based studies) and which are most important in the determination of model-measurement discrepancies. Sensitivity indices and scatter plots for monthly average fluxes indicate that the dominant factors are for most months related to non-stomatal components of the deposition flux.     

Annual and seasonal trends in chemical composition of precipitation in Japan during 1989–1998

Annual and seasonal trends were discussed for precipitation chemistry in Japan on the basis of a nationwide monitoring network by Japan Environment Agency. For this analysis, 17 sites, selected from the 23 network sites after evaluation of data completeness for the present purpose, were grouped into four areas in terms of the sea which could characterize each area: the Pacific Ocean, the Japan Sea, the Seto Inland Sea and the East China Sea areas. Major ion concentrations at each site were subjected to least-squares multiple regression analysis, and discussion was principally focused on the area-groups. Each area showed significant (p<0.05) decreasing trends in non-sea-salt sulfate (nss-SO₄²⁻) concentrations with the annual mean change rate of −3.0% yr⁻¹, whereas no significant trends were detected for NO₃⁻ at 59% of the sites. Ammonium (NH₄⁺) showed significant increasing trends for 35%, and decreasing trends for 18% of the sites; and, the maximum change rate of 3.8% yr⁻¹ was recorded in the Pacific Ocean area. Non-sea-salt calcium (nss-Ca²⁺) concentrations significantly decreased in northern and some industrialized areas. Both the annual cycle-amplitudes and effects of precipitation amounts were significant for the four ions at almost all sites. The maximum concentrations of nss-SO₄²⁻ and -Ca²⁺ occurred from winter to spring at most sites. The seasons when the maximum concentrations of NO₃⁻ and NH₄⁺ occurred, were found to differ from area to area. Furthermore, the trends in precipitation nss-SO₄²⁻, and NO₃⁻ were qualitatively consistent with those of anthropogenic emissions of SO₂, and NO_x in Japan, respectively.     

Chemical signals of epiphytic lichens in southwestern North America; natural versus man-made sources for airborne particulates

Ambient airborne particulate matter (PM) in southwestern North America consists of naturally derived desert dust, plus anthropogenic inputs from several sources. Epiphytic lichens (Usnea sp.) in this region are a useful biomonitor for the airborne PM because they derive nutrients and moisture largely from incorporated atmospheric aerosols, and not by absorption from the host tree limb from which they are suspended. Using a broad-based sampling strategy from southern Chihuahua, Mexico, to northern New Mexico, USA, we show that select elemental abundance ratios and lead isotopes from epiphytic lichens are useful for distinguishing between sources of airborne PM, and for gauging anthropogenic inputs into desert ecosystems. Abundance patterns of the trace elements La, Nd, and Sm in the lichens suggest origination from continental crust, but rare earth elements display a pronounced enrichment relative to the major element Fe by a factor of about 5. This enrichment appears related to geologic weathering, aeolian transport, and grain-size biases toward trace-element-rich mineral grains in the arid setting. Using the metal Pb as an indicator of human inputs, epiphytic lichens typically show Pb enrichments by a factor of about 25–60 over typical upper crustal values. Regional-scale differences in Pb isotope ratios of these lichens relate to different pollutant sources in southwestern North America.