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61.
建立了高效液相色谱法测定水中六种邻苯二甲酸酯(邻苯二甲酸二甲酯、邻笨二甲酸二乙酯、邻苯二甲酸二丁酯、邻苯二甲酸二(2-乙基己基)酯、邻苯二甲酸二辛酯、邻苯二甲酸丁基苄酯)的检测方法.对水样中邻苯二甲酸酯的萃取条件和高效液相色谱分析条件进行优化,采用正己烷二次萃取,浓缩定容后分析,以乙腈-水为流动相梯度洗脱,紫外检测波长226 nm,16 min可将六种邻苯二甲酸酯分离出.方法的检出限为0.13μg/L ~0.37 μg/L,加标回收率为78.6%~118.5%,相对标准偏差为0.82%~2.17%,是一种理想的测定水中六种邻苯二甲酸酯的方法. 相似文献
62.
表面活性剂辅助离子液体预处理稻秆的酶解动力学与结构变化分析 总被引:4,自引:3,他引:1
以稻秆为原料进行酶解研究,考察了纤维素酶和β-葡萄糖苷酶单独作用及协同作用对稻秆酶解还原糖产量的影响,以确定最佳酶体系,并研究在最佳酶体系中不同种类表面活性剂辅助离子液体对稻秆酶解的影响和动力学特征,最后通过稻秆成分分析、FTIR、XRD、SEM对预处理前后的稻秆结构、结晶性进行了分析比较.结果表明,纤维素酶与β-葡萄糖苷酶具有协同作用,而且在最佳酶体系中,与未处理稻秆及单独离子液体预处理相比,不同种类表面活性剂辅助离子液体预处理的稻秆在酶水解48 h时纤维转化率分别增加40%~85%、10%~31%,并且预处理对反应速率的提高有促进作用. 相似文献
63.
Heide Spiegel Manfred Sager Michael Oberforster Klemens Mechtler Hans Peter Stüger Andreas Baumgarten 《Environmental geochemistry and health》2009,31(5):549-560
Eighteen representative sites for the Austrian grain-growing and eight for the potato-growing zones (soils and crops) were
investigated. On each site, total element contents (B, Ba, Ca, Cd, Co, Cu, Fe, K, Li, Mg, Mn, Mo, Na, P, Sr and Zn) were determined
in 4–12 varieties of winter wheat (n = 136), 6 varieties of spring durum wheat (n = 30), 5 varieties of winter durum wheat (n = 15), 7 varieties of rye (n = 49), 5 varieties of spring barley (n = 30) and 5 varieties of potatoes (n = 40). Element accumulations in grain species and potato tubers varied significantly with site conditions, with the main
exceptions for B in potatoes and wheat as well as for Zn, Cu and Co in durum wheat. On average, across all investigated sites,
differences in varieties occurred concerning the elements Ca, Cd, Ba, Sr and Zn (except Zn in potatoes and winter durum).
A rough estimation revealed that an average Austrian consumer of wheat, rye and potatoes meets more than 50% of the needs
of daily element intake for K, P and Mg, between 36 and 72% for Fe, Zn and Cu, and more than 100% for Co, Mo and Mn. In particular,
the elements Ca and Na have to be added from other sources. 相似文献
64.
A. A. Al‐Mihanna A.K. Salama M.Y. Abdalla 《Journal of environmental science and health. Part. B》2013,48(6):693-704
Abstract Biodegradation of chlorpyrifos was studied in liquid culture media amended with either single or combined eight different plant pathogenic fungi isolated from the continuous cropping wheat fields. The average recovery of chlorpyrifos from the liquid media was found to be 86.1%. The detection limit of chlorpyrifos by the analytical method used was 19 ppb. Data showed that the growth of mixed fungi at concentrations up to 200 ppm of chlorpyrifos was higher than in the control treatment. Chlorpyrifos concentrations declined in the medium of combined fungi more than it did in the medium of any single fungus with increase in the incubation period. The amount of chlorpyrifos recovered was 79.8 ppm (39.9%) in the combined fungal cultures after 21 days. However, those recovered from the media of Fusarium graminearum, F. oxysporum, Rhizoctonia solani, Cladosporhim cladosporiodes, Cephalosporium sp., Trichoderma viridi, Alternaria alternata, and Cladorrhinum brunnescens, ranged from 48.0 to 74.8%. The half‐life value (T1/2) for chlorpynfos was 15.8 day in the medium amended with mixed fungi. However, for the single cultures it ranged from 19.3 to 33.0 day. 相似文献
65.
Liquid household hazardous wastes in the United States: Identification,disposal, and management plan
David K. Robertson Jude Akagha Jon Belasco Jane Bullis Gloria Byrne Joan Di Patria Wayne Fisher James Fonzino Jeffrey Hsu Lucy Merchan David Oster Jon Rosenberg Sabine Von Aulock Barry Vroeginday 《Environmental management》1987,11(6):735-742
Present methods of disposal of today's hazardous household chemicals in the United States are frequently not acceptable because of pathways to groundwater, surface water, and the atmosphere. This report identifies potentially hazardous liquid waste in the household, notes current disposal practices, and recommends an improved management plan that utilizes consumer education, manufacturer cooperation, and governmental intervention. Laws requiring uniform disposal labeling on packaging are critical. Local, county, and state governments must be encouraged to coordinate the necessary infrastructure. Managing hazardous household wastes now will mitigate potential disposal problems. 相似文献
66.
地面水中叶枯灵的高效液相色谱测定 总被引:2,自引:0,他引:2
本文采用反相高效液相色谱法,在质控条件下,对河水,塘水两种地面水中叶枯灵的检验方法进行了测试,用Shimapck ODS柱为分析柱,以甲醇:水=50:50为流动相,并用冰醋酸调PH至4-5,紫外检测波长281nm,两种水样的平均回收率分别为91.7-96.3%,90-95.8%,相对标准偏差为4.3%,最低检出限为0.0261mg/l,为地面水中叶枯灵卫生标准的实施提供了简便,灵敏,正确的配套测试手段。 相似文献
67.
氯化法处理医院废水的研究 总被引:2,自引:0,他引:2
介绍了次氯酸钠法和液氯法2种目前常用的处理医院废水的方法.对2家医院的废水处理过程进行了测试及实验研究.结果表明,这2家医院的废水处理后细菌总数和余氯量未达到国家规定的排放标准.主要原因是加氯量不精确,加氯后的停留时间不足,不能有效杀死废水中的病菌.对加氯量和停留时间的实验研究表明,每吨医院废水中次氯酸钠和液氯的最佳投入量分别为90 g和9 g,加氯后的停留时间不少于60min. 相似文献
68.
环境水样阴离子表面活性剂光度测定法 总被引:2,自引:0,他引:2
杨四海 《中国环境管理干部学院学报》1999,(4)
本文通过实验研究,提出了对河水及生活废水阴离子表面活性剂的水相直接测定方法,此方法具有简便、快速的特点,且有良好的准确性和再现性。 相似文献
69.
Ramessur RT 《Environment international》2004,30(8):1039-1044
Cr, Zn and Pb were quantified using atomic absorption spectrometry (AAS) from urban and rural estuarine sediments collected along the western coast of Mauritius during the period July 2002-January 2003. The mean concentration of Cr (225.4 mg kg(-1)), Zn (107.0 mg kg(-1)) and Pb (27.0 mg kg(-1)) in sediments along the six estuaries can be considered below those from contaminated estuarine sediments. Zn and Pb were significantly higher in urban sediments downstream St. Louis River compared to a rural estuary at Tamarin at 5% significance level. Zn was also significantly lower in Tamarin compared to Petite Riviere Noire estuary. Cr was however not significantly different in sediments from the six estuaries and could be considered of basaltic origin and were correlated to neither lead nor zinc. The concentration of Zn and Pb were greatest in the more urbanised upper and lower reaches of the St. Louis estuary during the period of study and were also significantly positively correlated in the estuarine sediments indicating that the cycling of Pb and Zn were linked indicating a common source for Pb and Zn. The potential sources of Pb and Zn in the urban estuarine sediments were considered to arise from road runoff causing significant quantities to be trapped. At present, compared to contaminant levels found in the UK and elsewhere, Mauritius still looks relatively uncontaminated but there is growing concern about heavy metal contamination in urban estuaries. There is therefore a need for long-term studies in estuarine management to involve integrated strategies in which water-sediment interactions in estuaries need to be considered and international standards for sediment quality developed. Such studies undertaken in the future would further the understanding of the biogeochemical processes of estuarine systems in Mauritius which could then be used in environmental development schemes and effective coastal zone management. 相似文献
70.