城市热岛效应下浅层土中混凝土的酸腐蚀试验研究

针对城市热岛效应引起城区浅层土地温场升高这一观测结果,采用室内快速模拟试验方法,对城区酸性土壤腐蚀混凝土材料的温度效应开展了试验研究.试验研究了在温度为5℃、20℃和40℃条件下,混凝土试样在酸浓度分别为0%、5%和10%的沙土介质中放置30 d、90 d后的抗压强度变化规律,并对混凝土试样在腐蚀过程中的腐蚀系数变化规...     

锈蚀钢筋混凝土圆柱抗震性能的试验研究

对不同锈蚀程度的钢筋混凝土圆柱进行低周反复试验,研究了不同轴压比下的钢筋锈蚀率对钢筋混凝土圆柱滞回曲线、骨架曲线、刚度、延性及耗能能力的影响;给出了试件累积耗能、屈服荷栽、极限荷栽、荷栽最大值和位移延性系数与钢筋锈蚀率和轴压比的关系.研究表明,随着钢筋锈蚀率和轴压比的增大,试件的滞回曲线趋于干瘪,骨架曲线下降段变陡,试...     

磷对环境的污染及防治对策

我国水体富营养化严重，其主要控制因子是磷。在分析磷污染的污染状况，污染源的基础上，介绍了防治对策，采用低磷循环冷却水处理剂，减少磷排放，是防止工业磷污染的有效方法。     

自然灾害保险的委托─代理模型

灾害保险是筹措防灾救灾资金的重要手段．本文运用委托-代理理论建立了自然灾害的保险模型,对自然灾害的最优保险合同和保险费率进行了研究,为开展自然灾害的保险业务提供了理论依据．     

The impact of handpump corrosion on water quality in rural areas of West African sub-region

Water, even in its natural environment, contains some level of impurities. Water is nearly a universal solvent. It contains dissolved solids and gases, and hosts a number of micro-organisms. The exploitation of groundwater by means of boreholes for supplying small user groups and rural communities with water has been widely applied in certain parts of the world for several decades. In recent years this practice has spread all over the globe, and hundred of thousands of boreholes have beendrilled to tap low-yield aquifers. It is evident that such boreholes require pumps for lifting thewater. In developing countries these are usually handpumps, butsolar as well as other systems with submersible pumps are also used, depending upon the energy sources available and the financial means of the beneficiaries. This article gives a general overview of groundwater quality with regard to itsphysico-chemical composition. The results presented originatefrom the experience gained from handpump equipped boreholes within the UNICEF through German Centre for Technical EducationTransfer executed inter-regional UNDP-Handpumps Project inWest African Regions. Particular attention is paid to presenting corrosion onthe water quality of wells in terms of iron concentrationand other parameters. Furthermore, the corrosion attack ongalvanised iron, the effect of biofilms on the corrosionrate, and the difference between internal and externalcorrosion of rising mains are shown.     

超临界水氧化中设备腐蚀的研究现状

超临界水氧化（SCWO）技术是近年发展起来的处理有机难溶废物的安全高效的新技术。在阐述超临界水的物理、化学性质的基础上，介绍了SCWO反应的工作原理和流程，分析总结了世界范围内开展的SCWO环境中设备腐蚀及监测技术等方面的研究动态，提出了我国SCWO技术研究的未来发展方向。     

Exposure Programme on Atmospheric Corrosion Effects of Acidifying Pollutants in Tropical and Subtropical Climates

Many national exposure programmes have been performed in tropical and subtropical climates during the last 50 years. However, ambitious programmes involving more than a few countries are scarce. In this paper a recently formed network of test sites is described involving 12 test sites in Asia (India, Vietnam, Thailand, Malaysia and China including Hong Kong) and four test sites in Africa (South Africa, Zambia and Zimbabwe). This effort is part of the 2001–2004 Swedish International Development Agency (SIDA) funded Programme on Regional Air Pollution in Developing Countries (RAPIDC). Corrosion attack after one (2002–2003) year of exposure (carbon steel, zinc, copper, limestone and paint coated steel) are presented together with environmental data (SO₂, NO₂, HNO₃, O₃, particles, amount and pH of precipitation, temperature and relative humidity) for all the test sites. The obtained corrosion values are substantially higher than expected for limestone, higher than expected for carbon steel and lower than expected for zinc compared to values calculated using the best available dose–response functions.     

钠盐量影响下DD6单晶高温合金的高温热腐蚀规律研究

目的 开展镍基单晶高温合金DD6在950 ℃下的热盐腐蚀试验(95%Na2SO4+5%NaCl)，探明涂盐量和涂盐方式(周期涂盐和单次涂盐)对DD6高温热腐蚀的影响规律和机理。方法 结合扫描电子显微镜、X射线能量色散谱、X射线衍射等设备，对不同涂盐量及涂盐方式下DD6的表面及横截面形貌进行观察分析，分析不同涂盐量和涂盐方式下DD6的高温热腐蚀机理。结果 DD6在950 ℃下主要发生碱性熔融热腐蚀，同时伴随氧化、硫化和氯化等过程。高温热腐蚀使得DD6合金表面生成的保护性氧化膜被熔融态的腐蚀介质破坏，导致O、S、Cl等外部元素通过氧化膜的缺陷进入DD6基体中，在合金的亚表面发生内氧化、内硫化以及内氯化反应，横截面上出现明显的腐蚀层，其主要由氧化物以及硫化物组成。随着热腐蚀的进行，DD6表面物质发生了剥蚀，沉积盐量的增加导致剥蚀现象越加严重，合金内部致密的组织结构也被破坏，横截面上出现了大量孔洞、裂纹等缺陷。在相同涂盐量下，周期涂盐法使得DD6的腐蚀程度高于单次涂盐法。结论 DD6高温热腐蚀行为与涂盐量及涂盐方式密切相关，相同涂盐方式下，涂盐量越大，DD6热腐蚀更加严重。涂盐量一定时，周期涂盐法使得DD6的热腐蚀剧烈程度大于单次涂盐法，且DD6在上述热腐蚀条件下均发生剥蚀破坏。     

储罐硫腐蚀产物标志性气体的监测

含硫油品储罐内的腐蚀产物与油品中的活性硫反应生成硫化物,而此类硫腐蚀产物氧化自燃是导致储油罐发生火灾、爆炸事故的重要原因.通过试验考察了氧气体积比对硫腐蚀产物氧化自燃过程的影响,探索了铁锈模拟物在氧化过程中SO2气体的释放规律.结果表明:氧气浓度越高,硫腐蚀产物的自燃危险性越大;随着O2浓度增加,氧化反应中SO2的浓度越大,SO2气体析出速度越快,当氧化反应的温度为40℃时,SO2气体浓度达到最大.     

Inhibition effects of aluminum dust explosions by various kinds of ammonium polyphosphate

In this work, vinyltriethoxysilane (A151) and 3-aminopropyltriethoxysilane (KH550) were used to modify ammonium polyphosphate (APP), showing that the dispersibility of APP could be improved remarkably by A151 and KH550. The maximum explosion pressure of aluminum dust explosion decreased with the addition of APP, A151-APP (APP-A) and KH550-APP (APP-B), with the exception of the case where the inerting ratio (α) of APP-A was less than 0.4. After the addition of APP-B, there was little difference in flame propagation behavior and explosion pressure compared with that of adding APP, indicating that APP-B could retain the inhibition performance of APP compared with APP-A. When the inerting ratios of APP, APP-A and APP-B were 1.2, 1.4 and 1.4, respectively, the aluminum dust explosion could be completely inhibited. The explosion residues of aluminum dust/APP mainly consisted of Al₂O₃, P-containing and N-containing compounds. It could be analyzed that APP exerted the inhibition effect through both chemical and physical effects.