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101.
102.
The spatial variation of heavy metals in the soils in Shuikoushan mining-smelting area, Hunan Province, China, was investigated
using multivariate and geo-statistic analysis. A total of 106 composite soil samples were collected in an area of about 100 km2.
Concentrations of total As, Cd, Pb, Zn, Cu and Cr were measured using inductively coupled plasma mass spectrometry (ICP-MS).
Arsenic and Pb were found to have a common source, indicating the same sources and spreading processes, such as aerosols and
airborne particulates from smelting chimneys. Airborne sources from smelting chimneys contributed greatly to Cd in the area, which
demonstrated the same dispersion pattern as As and Pb. However, two hot spots of Cd around smelters were possibly enlarged by
wastewaters, demonstrating another important source of Cd in Shuikouhsan. Geo-statistic interpolated mapping demonstrated that hotspots
of Zn were only found proximal to the large smelters, suggesting that Zn primarily came from the chimneys of larger smelters.
The major Cu hot-spots appeared closely to the tailing dam, indicating that weathering and leaching of tailings were the major sources
of Cu contamination in Shuikoushan. Our findings indicated that airborne volatile particles and aerosols contributed the most to As,
Cd, Pb, Zn and Cu contamination, while Cd and Cu may also derive from the discharge of wastewater from smelters and the leaching
of tailings, respectively. 相似文献
103.
采用低温等离子体和絮凝剂协同处理印染废水.结果表明,染料废水脱色率和COD去除率随输入电压增大和放电时间延长而增加;电极间距、废水初始浓度、通入空气流量等因素对印染废水处理效果也有很大影响;气相中放电效果优于液相中放电,阳极电极在液面以上8mm左右时放电效果最好,在其他条件不变情况下随废水初始浓度和通入空气流量增大废水脱色和COD脱除率先增大再减小,有一最佳峰值.印染废水先经过等离子体处理后再加入絮凝剂处理效果优于先加絮凝剂后放电、仅有等离子体放电的过程.在本实验中初始浓度200mg/L(CODCr初始值572)印染废水在外加电压40kV、放电时间20min、电极间距8mm、通入空气流量16L/h条件下,与絮凝剂PAC相互协同作用可达到96%脱色率、63%COD去除率. 相似文献
104.
温室效应导致全球变暖已成为全球性的环境问题之一.采用放电等离子体法转化CO2,不仅可消纳温室气体,缓解全球变暖的巨大影响,还可制备化工原料CO和O2.充分利用了C1(含1个碳原子的化合物分子)资源,对高频同轴式介质阻挡放电等离子体分解纯CO2进行了研究.结果发现:在采用不锈钢光滑内电极,放电间隙为2.0mm,注入功率为180W,气体流量为170mL/min的条件下,CO2转化率可达18.2%,CO和O2产率分别为10.1%和4.7%;增大注入功率,减小气体流量、选择合适的放电间隙和内电极形式,均有利于提高CO2转化率,获得更多的CO和O2. 相似文献
105.
Low-cost, easy-maintenance and high-e ciency decentralized wastewater treatment technologies are urgently needed in rural areas
of China. Processes with high potential for phosphorus removal are of great interest. However, commonly used treatment methods often
do not meet the strict criteria for removing phosphorus from rural wastewater. In order to search an economic and simple technology
for phosphorus removal from the common bio-technologies e uent, seven soil types collected from di erent rural areas in China were
investigated for their ability to remove phosphorus. X-ray di raction (XRD) was used to analyse the mineral structure, and inductively
coupled plasma optical emission spectrometer (ICP-OES) was used to analyse the geochemical composition of the soil samples. Three
primary minerals – quartz, albite and montmorillonite – were clearly detected. The samples were divided into two soil types, acidic
soils and alkaline soils, based on their pH values. The geochemical composition study indicated that a higher percentage of Ca and Mg
occurred in alkaline soils (pH > 8) than in acidic soils (pH < 6.5). Adsorption isotherms from batch experiments fitted the Langmuir
and Freundlich models well, the maximum P adsorption capacities ranged from 0.256 to 1.598 mg P/g, indicating a high phosphorus
removal potential for all of these soils. The P fractions extracted revealed that the sum of NaOH-extracted inorganic P (NaOH-Pi) was
the major P component in the acidic soils, and CaCO3-bound phosphorus (Ca-P) in the alkaline soils. Dynamic adsorption simulation
showed that these soils have the ability to remove phosphorus from wastewater. 相似文献
106.
《辽宁城乡环境科技》2009,(8)
德国开发出"可印刷的"电池德国研究人员最近开发出了世界上首款"可印刷的"电池,它薄如纸张,用丝网印刷技术就能生产。据德新社报道,德国弗劳恩霍弗电子纳米系统研究所研发的这种"薄纸"电池每个质量不足1克,厚度不到1毫 相似文献
107.
108.
采用电感耦合等离子体质谱仪测定水中的钴,在0μg/L~300μg/L范围内线性良好,相关系数均达到0.9999。该法对钴标准样品测定的结果在保证值范围。对三份不同浓度水样分别进行测定,其结果的RSD为0.2%~1.2%,空白水样的加标回收率在99%~107%之间。通过对水样的分析,符合标准要求,ICP-MS质谱仪具有灵敏度高,检出限低,取样量少,线性范围宽等特点,能快速测出水中的微量重金属元素含量。 相似文献
109.
热解析-脉冲低温等离子体集成处理系统是专门针对典型含汞废物安全处置而开发的,可以同时有效控制汞等多种复合气体污染物。通过检测热解炉后烟气中和等离子体反应器入口、出口气体中Hg0和Hg2+浓度,研究汞的价态转化及添加剂对脱汞效果的影响。结果表明:热解烟气中Hg2+/HgT为17%~45%,Hg0/HgT为55%~83%,热解温度主要影响汞价态分布,WMC添加量主要影响汞浓度值;加入添加剂会促进汞的脱除,但添加剂过量不利于汞的氧化;热解炉中添加50 g WMC和5 g升华硫添加剂时,反应器内Hg0氧化率和总汞损失率分别可达55%和42%。该研究可以为探索新型含汞废物处置工艺,实现含汞废物深度净化提供新思路。 相似文献
110.
比较电热板消解和微波消解两种消解方法对测定含油固体废物金属元素的影响,并通过电感耦合等离子体质谱(ICP-MS)法测定其中10种金属元素的含量。通过F检验验证两种消解方法的差异,结果表明:电热板消解和微波消解两种消解方法对测定数据准确性无显著影响,但微波消解具有精密度好、耗酸量少、不易引入污染、消解彻底、用时较短等优势。进一步对微波消解体系和ICP-MS分析条件进行优化后发现,采用HNO_3-H_2O_2-HF混合酸体系微波消解含油固体废物样品后以~(103 )Rh作为内标元素,能够有效校正含油固体废物样品基体干扰。元素检出限为0.06~1.8mg/L,相对标准偏差在2.99%~9.63%的范围内,加标回收率在89.4%~113%之间。该方法耗酸量少,灵敏度高,快速准确,能够应用于含油固体废物中金属元素的测定。 相似文献