基于CONE和MCC的典型电缆燃烧性能研究

采用锥形量热仪和微燃烧量热仪对四类不同护套材料的八种电缆样品进行燃烧性能分析,研究结果表明：电缆燃烧热释放过程不仅与护套、绝缘的材料密切相关,也与电缆结构密不可分;对于护套材料相同而大小或结构不同的电缆点燃时间和到达第一个峰值的时间以及第一个峰值最大热释放速率基本一致;聚烯烃无机阻燃材料电缆能够有效降低热释放速率峰值,CO2、CO释放量也明显低于橡胶电缆、普通PVC电缆和阻燃PVC电缆;微燃烧量热仪和锥形量热仪实验数据存在一定的相关性,微燃烧量热仪实验数据可以对电缆锥形量热仪实验的第一燃烧阶段燃烧行为进行预测。     

聚合物燃烧放热的通风

本文在小尺寸试件燃烧实验的基础上,着重研究了几种典型聚合物燃烧时放热参数的变化规律及其通风影响,通过实验数据的拟合和分析,揭示了燃烧放热、通风条件和燃料种类之间复杂的关系,给出了由放热参数决定的可燃性区域,得到了一些新的结论,有助于材料放热特性认识和室内火分析的进一步深入。     

Structure of flames propagating through aluminum particles cloud and combustion process of particles

Structure of flames propagating through aluminum particles clouds and combustion processes of the particles have been examined experimentally to understand the fundamental behavior of a metal dust explosion. The combustion process of individual aluminum particles in a flame propagating through the aluminum particles cloud has been recorded by using a high-speed video camera with a microscopic optical system, and analyzed. The flame is shown to be consisted of a preheat zone of about 3 mm thick, followed by a combustion zone of 5–7 mm thick. In the combustion zone, discrete gas phase flames are observed around each aluminum particle. Also an asymmetric flame around a particle is observed, which might be caused by an ejection of aluminum vapor from a crack of oxide shell surrounding the particle.     

脉冲燃烧控制技术在加热炉中的环保节能应用

党的十七大提出"加强能源资源节约和生态环境保护,增强可持续发展能力",这是我们党科学发展、和谐发展理念的一次升华。开发低碳能源是建设低碳城市的基本保证,清洁生产是建设低碳城市的关键。传统燃煤加热炉能耗高、污染重。P-HTAC是在蓄热式加热炉的基础上研制的先进技术,采用脉冲方式控制燃烧系统,使燃烧更充分、炉温控制更精确,为企业走上一条经济效益好、资源消耗低、环境污染少的可持续发展道路铺垫了坚实的技术基础。     

Comparative assessment of the explosion characteristics of alcohol–air mixtures

Explosion characteristics of five alcohol–air (ethanol, 1-butanol, 1-pentanol, 2-pentanol and 3-pentanol) mixtures were experimentally conducted in an isochoric chamber over wide ranges of initial temperature and pressure. The effect of temperature and pressure on the different explosion behaviors among these alcohols with various structures were investigated. Results show that the peak explosion pressure is increased with the decrease of temperature and increase of pressure. Maximum rate of pressure rise is insensitive to the temperature variation while it significantly increases with the increase of initial pressure. Among the 1-, 2-, and 3-pentanol–air mixtures, 1-pentanol has the highest values in peak explosion pressure and maximum rate of pressure rise and 2-pentanol gives the lowest values at the initial pressure of 0.1 MPa. These differences tend to be decreased with the increase of initial pressure. Among the three primary alcohol–air (ethanol, 1-butanol and 1-pentanol) mixtures, a similar explosion behavior is presented at the lean mixture side because of the combined effect of adiabtic temperature and flame propagation speed. At the rich mixture side, 1-pentanol gives the highest values in peak explosion pressure and maximum rate of pressure rise and ethanol gives the lowest values. This phenomenon can be interpretated from the combining influence of heat release and heat loss, since the flame speeds of ethanol-, 1-butanol-, 1-pentanol–air mixtures are close at rich mixture side.     

Emissions from the combustion of eucalypt and pine chips in a fluidized bed reactor

Interest in renewable energy sources has increased in recent years due to environmental concerns about global warming and air pollution,reduced costs and improved efficiency of technologies.Under the European Union(EU)energy directive,biomass is a suitable renewable source.The aim of this study was to experimentally quantify and characterize the emission of particulate matter(PM_(2.5))resulting from the combustion of two biomass fuels(chipped residual biomass from pine and eucalypt),in a pilot-scale bubbling fluidized bed(BFB)combustor under distinct operating conditions.The variables evaluated were the stoichiometry and,in the case of eucalypt,the leaching of the fuel.The CO and PM_(2.5)emission factors were lower when the stoichiometry used in the experiments was higher(0.33±0.1 g CO/kg and 16.8±1.0 mg PM_(2.5)/kg,dry gases).The treatment of the fuel by leaching before its combustion has shown to promote higher PM_(2.5)emissions(55.2±2.5 mg/kg,as burned).Organic and elemental carbon represented 3.1 to 30 wt.% of the particle mass,while carbonate(CO_3~(2-))accounted for between 2.3 and 8.5 wt.%.The particulate mass was mainly composed of inorganic matter(71% to 86% of the PM_(2.5)mass).Compared to residential stoves,BFB combustion generated very high mass fractions of inorganic elements.Chloride was the water soluble ion in higher concentration in the PM_(2.5)emitted by the combustion of eucalypt,while calcium was the dominant water soluble ion in the case of pine.     

A study of Cr(VI) in ashes from fluidized bed combustion of municipal solid waste: leaching, secondary reactions and the applicability of some speciation methods

The use of the fluidized bed technique for the combustion of municipal solid waste is a rather new concept. This type of combustor produces ash residues with somewhat different properties than the residues generated from the traditional mass burn techniques. Therefore, chemical characterization and the investigation of toxic metals behavior during ash water reactions are necessary for the safe disposal of these residues. In the present work, the total elemental composition, mineralogy and leaching behavior of ashes from the combustion of municipal solid waste in a fluidized bed combustion boiler have been investigated. The cyclone ash and, in particular, the filter ash contained considerable amounts of soluble substances, thus giving leachates with high levels of Cl-, Na+, K+, Ca2 + and Al(IIl). On the other hand, the two ash fractions taken in the boiler, the bottom and hopper ashes, were much more stable with respect to the release of salts and heavy metals. Since Cr(VI) is mobile and toxic its release from combustion residues can pose environmental problem. Even though the total Cr contents were similar in all ashes studied, the bottom ash gave about a thousand times higher levels of Cr(VI) in test leachates than the hopper, cyclone and filter ashes. However, it was found that the leached amount of Cr(VI) from the bottom ash decreased significantly when bottom ash was mixed with the hopper ash. The most probable cause for this decrease is the coupled oxidation of Al(0) to Al(III) and reduction of dissolved Cr(VI) to Cr(III). This finding that the mixing of two ash streams from the same boiler could result in the immobilization of Cr may point at a simple stabilization method. Selective extraction of water soluble, exchangeable and sparingly soluble forms of Cr(VI) was also investigated. Extraction methods were evaluated for their suitability for ash matrixes. It was found that interferences due to the presence of reducing substances in some ash materials may occur.     

Investigation of ammonium nitrate based emulsion ignition characteristic

This paper presents an analysis of the observed ignition behaviors of ammonium nitrate (AN) and emulsion explosives (EE). Pure AN and EE locally ignited by a heat source do not undergo sustained combustion when the pressure is lower than some threshold value usually called the Minimum Burning Pressure (MBP). A reason for pure AN's and EE's incapable of burning was suggested, and the roles of sample water, inorganic salts, oil phase, and sensitizer were discussed. Accelerating rate calorimeter (ARC) was used to study the thermal stability of EE and AN. The results also showed that MBP is of vital importance and useful for the manufacture and application of AN and EE in terms of accident prevention.     

工业锅炉低 NOx 燃烧技术简介

本文介绍了NOx的产生类型,以及低NOx 燃烧技术的研究和应用现状,并对不同类型工业锅炉的NOx防治措施进行了分析。     

燃烧加热污染空气对超燃冲压发动机性能影响研究

针对燃烧加热地面试验设备存在的工质污染问题,采用数值模拟方法研究了燃烧加热污染空气对氢燃料超燃冲压发动机性能的影响。以飞行马赫数Ma=6.5,当量油气比ER=0.6为计算基准状态,分别对纯净空气和污染空气来流下氢燃料超燃冲压发动机的整机流场和性能进行了对比计算分析。燃烧化学反应模拟采用了改进的H₂/O₂七组分八方程模型,湍流模型为标准的 k-ε模型,并采用直连式燃烧室试验数据进行了数值方法的验证。研究结果表明:(1)相对于纯净空气来流,污染空气来流下的超燃冲压发动机推力和比冲均有所下降。(2)采用酒精燃烧加热器的前提下,来流参数匹配静温、静压、马赫数时,发动机性能与纯净空气来流下的结果最为接近,而匹配总温、总压、马赫数时相差最大。(3)来流参数匹配总焓、静压、马赫数的前提下,采用氢燃烧加热器时发动机性能与纯净空气来流下的结果最为接近,而采用甲烷燃烧加热器时相差最大。 