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41.
Moon DH Dermatas D Wazne M Sanchez AM Chrysochoou M Grubb DG 《Environmental geochemistry and health》2007,29(4):289-294
Several million tons of Chromite Ore Processing Residue (COPR) were deposited at two sites in New Jersey and Maryland, USA,
and over time they exhibited extensive heaving phenomena. Ettringite, a needle-shaped mineral and an expansive mineral commonly
recognized in the literature concerning cement- and soil, has been identified extensively in numerous COPR samples collected
from these sites. It was therefore believed that ettringite formation and its crystal growth are strongly associated with
COPR heaving. We investigated the correlation between ettringite and the heaving phenomena in COPR materials that contained
no initial ettringite. Two identical COPR samples were exposed to a 4% w/w sulfate solution (25°C, 50°C) in a confined swell
test apparatus. Both swell test samples were analyzed by means of X-ray powder diffraction. The peak intensities of newly
formed ettringite were more pronounced in the sample tested at 50°C, and swell development was only observed in this sample.
Scanning electron microscopy analyses revealed well-crystallized ettringite needles exceeding 40 μm in length for this sample,
while ettringite crystals less than 15 μm in length formed in the sample tested at 25°C. Therefore, the results suggest that
the quantity of ettringite and the extent of crystallization play a key role in the heave of COPR. 相似文献
42.
Selected results from the degradation of reactive-dye hydrolysates after UV irradiation, ozonation and sodium peroxodisulphate (NaPS) treatment are presented. Reactive dyes with representative chromophores and anchor groups were chosen for the research project. Different stages of oxidative decolourisation were examined and determined by water parameters for biological degradation (BOD). The paper focuses on toxicity tests with Pseudomonas putida to consider whether the oxidative treatments result in products with a risk for the environment. Tests were performed with the AQUALYTIC® Sensomat System, which measures biological oxygen demand (BOD). It was determined that the chosen oxidative treatments had as a rule no bearing on respiration of P. putida. Experiments with hydrolysates after short-term UV irradiation resulted in a slightly increased but not long-lasting toxicity in comparison with treatments with ozone or NaPS. Toxic effects were found in tests with hydrolysates of metalliferous dyes. During oxidative treatment, metals were liberated from the chromophores. This did cause complete inhibition of respiration of P. putida. Dye Blue E, a member of a dye class with chlorotriazine anchor groups, was itself found to be toxic, caused by the reactivity of the anchor group. The hydrolysate is only of minor toxicity. 相似文献
43.
Palut JM Montarnal P Gautschi A Tevissen E Mouche E 《Journal of contaminant hydrology》2003,61(1-4):203-218
A long-term single borehole diffusion experiment using tritiated water as tracer was carried out in Opalinus clay, an argillaceous rock formation that is accessible at the Mont Terri Underground Research Laboratory, situated in the Swiss Jura. The tracer was diluted in reconstituted formation water and introduced into a packed-off section of a borehole located in saturated rock. Pressure in this interval was maintained equal to the pore pressure of the surrounding rock in order to prevent any hydraulic gradient around the borehole and to avoid advective transport processes. The evolution of the tracer concentration in the injection system was monitored over time. After 1 year of diffusion, the claystone surrounding the interval was retrieved by overcoring the whole borehole and packer system, and by an adjacent oblique borehole. Compressed air was used as drilling fluid to reduce rock disturbances. The recovered overcore was sampled along profiles perpendicular to the borehole wall with a view to determining the tracer-concentration profiles in the rock. To avoid further evaporation of tritiated water, subsamples were immediately transferred into polyethylene bottles and disaggregated by adding a known amount of tracer-free water. Fifteen profiles were determined and showed a decreasing tracer concentration with distance into the rock. The pore-water contents were constant along those profiles, confirming that only very little water was lost during overcoring operations. The evolution of tritium-tracer concentration in the injection system over time and in situ profiles were interpreted with a 3-D numerical simulation of the experiment. That allowed for the identification of the transport parameters (orthotropic diffusion tensor and porosity) by minimising the relative quadratic error between the experimental and simulated data. The fitting is good and the results are consistent with data obtained on drill-core samples. The result of tritiated water is discussed regarding (1) the potential effect of mechanical and/or chemical disturbances around the injection borehole and (2) the specific behaviour of tritiated water. 相似文献
44.
In situ methods are needed to evaluate the effectiveness of chemical amendments at enhancing reductive dechlorination rates in groundwater that is contaminated with the priority pollutant, trichloroethene (TCE). In this communication, a method that utilizes single-well, “push–pull” tests to quantify the effects of chemical amendments on in situ reductive dechlorination rates is presented and demonstrated. Five push–pull tests were conducted in each of five monitoring wells located in a TCE-contaminated aquifer at the site of a former chemical manufacturing facility. Rates for the reductive dechlorination of the fluorinated TCE-surrogate, trichlorofluoroethene (TCFE), were measured before (test 1) and after (test 5) three successive additions (tests 2–4) of fumarate. Fumarate was selected to stimulate the growth and activity of indigenous microorganisms with the metabolic capability to reduce TCFE and TCE. In three wells, first-order rate constants for the reductive dechlorination of TCFE increased by 8.2–92 times following fumarate additions. In two wells, reductive dechlorination of TCFE was observed after fumarate additions but not before. The transformation behavior of fumarate was also monitored following each fumarate addition. Correlations between the reductive dechlorination of TCFE and the reduction of fumarate to succinate were observed, indicating that these reactions were supported by similar biogeochemical conditions at this site. 相似文献
45.
The purpose of this paper is to develop a set of associated statistical tests for spatial clustering. In particular, a set
of three associated tests will be developed; these will correspond to the three types of tests set out by Besag and Newell
(general tests, focused tests, and tests for the detection of clustering). The associated tests draw primarily, though not
exclusively, upon existing tests and results. The principal contributions are based upon the score statistic for focused tests,
which has been an important approach to testing for clustering around environmental hazards. The first contribution consists
of the formulation of a global statistic for general tests that corresponds to focused score statistics, along with an assessment
of the distribution of the statistic under the null hypothesis of no raised incidence. The local score statistics used for
focused tests will have the property of summing to the global statistic used for the corresponding general test. Attention
is also given to the maximum local score statistic for the “test for the detection of clustering”. The critical values of
this statistic which are required for testing the null hypothesis are described. Application of the methods is made to leukemia
data for central New York State. 相似文献
46.
B. Sango Otieno Christine M. Anderson-Cook 《Environmental and Ecological Statistics》2006,13(3):311-324
Circular or angular variables indicating direction or cyclical time can be of great interest to scientists studying ecology,
biology or environmental issues. A common problem of interest in circular data is estimating a preferred direction and its
corresponding distribution. This problem is complicated by the so-called “wrap-around effect” on the circle, which exists
because there is no natural minimum or maximum. The usual statistics employed for linear data are inappropriate for directional
data, as they do not account for its circular nature. Three choices for summarizing the preferred direction (the sample circular
mean, sample circular median and a circular analog of the Hodges–Lehmann estimator) are discussed, with examples from environmental
and ecological applications. Similar to the linear data case, the relative emphases of different methods sometimes yield different
measures of preferred direction in the presence of outliers or lack of symmetry in the original data.
Received: November 2003 / Revised: June 2004 相似文献
47.
An agricultural system is sustainable if productive output is maintained economically over time when assessed in relation to environmental concern. This paper considers ways of statistically evaluating measures of sustainability illustrated by reference to extensive data from the Classical Experiments at Rothamsted. 相似文献
48.
49.
50.
为防止空调系统内霉菌、细菌的过度孳生,本文以空调系统内常见的黑曲霉(A. niger)、大肠埃希氏菌(E. coli)、金黄色葡萄球菌(S. aureus)、枯草芽孢杆菌(B. subtilis)为典型霉菌、细菌,基于纸片扩散法药敏试验,研究了空调除湿常用工质LiCl溶液对上述典型菌种的抑制作用及浓度影响规律.结果表明:在常见除湿浓度范围(35%~40%)内,LiCl溶液对上述4种典型菌种均有抑制作用;特别是对A. niger抑制效果最强,在15%的低浓度下即可产生明显抑制;其次为E. coli,而对S. aureus和B. subtilis的抑制相对较弱.此外,所得抑制效果随LiCl溶液浓度的提高而明显增强,特别是对A. niger和E. coli,溶液浓度与抑菌圈直径呈显著的正相关性. 相似文献