Economies of scale for future lithium-ion battery recycling infrastructure

While lithium-ion battery (LIB) technology has improved substantially to achieve better performance in a wide variety of applications, this technological progress has led to a diverse mix of batteries in use that ultimately require waste management. Development of a robust end-of-life battery infrastructure requires a better understanding of how to maximize the economic opportunity of battery recycling while mitigating the uncertainties associated with a highly variable waste stream. This paper develops and applies an optimization model to analyze the profitability of recycling facilities given current estimates of LIB technologies, commodity market prices of materials expected to be recovered, and material composition for three common battery types (differentiated on the basis of cathode chemistry). Sensitivity analysis shows that the profitability is highly dependent on the expected mix of cathode chemistries in the waste stream and the resultant variability in material mass and value. The potential values of waste streams comprised of different cathode chemistry types show a variability ranging from $860 per ton¹ for LiMn₂O₄ cathode batteries to $8900 per ton for LiCoO₂ cathode batteries. In addition, these initial results and a policy case study can also help to promote end-of-life management and relative policymaking for spent LIBs.     

Costs and benefits of packaging waste recycling systems

This Special Issue provides several different perspectives on the complex issue of packaging waste recycling. It comprises a diverse and rich set of contributions with insights from very different disciplines that range from economics to engineering. All types of “costs and benefits” are addressed in this collection of articles. In addition to the economic and strictly financial impacts of selective collection and sorting of packaging waste, several authors discuss other types of impacts, such as the environmental and social ones. The reader will find articles that address recycling systems as a whole, pieces that focus on specific impacts and detailed discussions of particular material streams or waste management strategies. The Special Issue represents an indispensable resource for academics, policy-makers and practitioners with interests in recycling and packaging waste management.     

Overview of household solid waste recycling policy status and challenges in Malaysia

With the annual increase in waste generation and heavy reliance on landfilling as disposal, method in Malaysia, it is just a matter of time before significant problems of space limitations, health, and environmental issues hit the nation severely. This paper attempts to develop an overview on solid, waste recycling in Malaysia at the most basic level of a community or nation which is the household, unit. Households are the main primary source of municipal solid waste in Malaysia, consisting of, recyclable materials at most 70% to 80% of the total waste composition as found placed in the, landfills. Overview on the existing household solid waste recycling policy and program status in, Malaysia is relevant in enhancing solid waste management measure from recycling perspective. Despite the high potential and opportunities for solid waste recycling, wastes are still simply being, dumped in an open area of ground without any attempt for recovery and recycling. Comparing to, recycling rates of neighboring countries, Malaysia is falling back at merely 5% which proves how, uncommon recycling practice is. The government is committed to significantly improve the national's, solid waste management services especially in waste minimization. Fortunately the emphasis on, recycling as a sustainable waste management strategy has taken a shift in paradigm as wastes, separation and recycling are part of the major changes in the current policy implementation. With, issues and challenges in recycling practice that were highlighted in this context especially from the, aspects of information availability and other loopholes within solid waste management policies and, related recycling program within the community, the question on whether the goals in 2020 can be, met remains unsure of but there is a possibility for a successful implementation of sustainable solid, waste management particularly in recycling.     

Towards the estimation of demand for recycling in Chile: The case of Santiago

In developing countries, the recycling of municipal solid waste (MSW) as an alternative to the traditional MSW management requires an economic sustainability valuation. From this perspective, the estimation of demand for recycling is crucial. In this paper, we study the case of recycling MSW in Santiago, Chile. We estimate the relation between the monthly amount of MSW separated voluntarily from apartments located in Santiago and the monthly price required to participate in a municipal recycling program. We consider the transference of the municipal cost savings to the owners of the apartments due to the amount of MSW separated for recycling, which is not collected and deposited in the current MSW system. For the estimation, we use concepts from environmental economics and psychology, analyzing the operation and municipal costs incurred by current MSW management and designing and applying a survey based on a contingent valuation method (CVM) approach. The results indicate that the percentage of MSW separated for recycling varies between a 27.98% and 33.18%, that only four MSW types are affected by a variation of the monthly price, and that a reduction of monthly collection trips in the current MSW system from 24 to 18 can be obtained. Additionally, we discuss a number of methodological aspects to be considered in a similar study of valuation of recycling in developing countries. Our conclusion is that Santiago has favorable conditions for the implementation of a recycling program as an alternative to the current MSW system.     

Closed loop recycling of plastics containing Flame Retardants

Annually 2.7 million tonnes of plastics containing Flame Retardants (FRs) are globally discarded in Waste Electrical and Electronic Equipment (WEEE). Little is known on the feasibility of closing material loops for FR plastics. Therefore, series of experiments were set up to analyze the feasibility of separating plastics containing FRs from one specific product category, namely End-of-Life (EoL) Liquid Crystal Display (LCD) TVs. The characterization of the housings of this waste stream indicated a concentration of 18 wt% Bromine based (Br) FRs and 31 wt% Phosphor based (P) FRs, the remainder not containing FRs. With practical tests it was demonstrated that, after disassembly and plastic identification, the co-polymer poly-carbonate (PC)/acrylonitrile-butadiene-styrene (ABS) containing PFR can be recycled in a closed loop system. Based on the determined plastic density distributions and separation efficiencies of optical sorters, a purity of 82% was calculated for PFR PC/ABS separated from EoL LCD TVs after size-reduction (shredding). Performed miscibility tests indicated that for this fraction at least a factor 10 dilution with virgin material is required. In addition, higher waste volumes are required for a size-reduction based treatment to become economically viable and technical challenges still need to be faced, whereas closed loop recycling of PFR PC/ABS from the current waste stream of EoL LCD TVs of different brands in a disassembly based treatment is found to be technically feasible and economically viable under European boundary conditions.     

Present situation of wastewater treatment in the Iranian industrial estates: Recycle and reuse as a solution for achieving goals of eco-industrial parks

Iran is located in arid and semi-arid region, which means water resource management is a strategic issue for this country. Water scarcity is one of the most critical concerns of industrial estates in Iran. For this reason, recycling and reusing of treated wastewater is the most practical solution for compensating of water shortage in industrial estates. Currently, only 20% of total treated wastewater is used for irrigation and almost 0.81% is consumed for industrial purpose. This study presents an overview on the wastewater management at the Iranian industrial estates for the purpose of achieving the goal of eco-industrial parks by describing the present situation and discussing the experiences of wastewater reuse systems for irrigation and industrial purposes. The aims of this study was to provide an overview of the wastewater management at the industrial estates in Iran towards achieving eco-industrial parks by describing present states and the outcome of wastewater consumption for irrigation and industrial purposes.     

Recycling, reuse and energetic valuation of meat industry wastes in Extremadura (Spain)

The environmental problem caused by the effluents from the four main agrifood industries in Extremadura (W Spain) is evaluated in the present work. In particular, attention is paid to the management of wastes from slaughterhouse operations. Pollution is quantified in terms of equivalent population and biological oxygen demand, for which very high values are reported.Efforts are also focused on the search of viable technical solutions for the treatment of those residues and their energetic valuation. In this sense, anaerobic digestion techniques are proposed, not only because they lead to a drastic decrease in their pollution potential, but also because significant volumes of biogas are obtained. This biogas might be used to produce electricity to be transferred to the electrical network. This way, anaerobic digestion plants would allow depreciation within a relatively short period.In particular, an analysis of the economics of a plant for the codigestion of solid and liquid effluents from meat industry is carried out, and a payback time between 7 and 8 years was achieved.     

Global disposal strategies for waste cathode ray tubes

The collection and management of waste electrical and electronic appliances around the world, and the possible negative environmental consequences have been an issue of current debate. Cathode ray tubes (CRTs) used as display screen for computer monitors and televisions contains large quantities of lead, estimated at between 0.5 and 4 kg, depending on the size of the CRT and has been identified as the most polluting of all electronic waste components. Having failed the tests used in the toxicity characterization of solid wastes, CRTs have been declared ‘hazardous’ and subsequently banned from landfills and incinerators in most developed countries. Presently, large quantities of CRTs are generated globally with only few developed countries having effective take back and sound management program. Meanwhile, large quantities of CRT-containing devices are being moved across frontiers into developing countries in the name of ‘reuse’ and ‘bridging the digital divide’. With near absence of recycling infrastructure for electronic wastes in most developing countries, waste CRTs are disposed of with MSW at open dumps and unsanitary landfills. This paper reviews the current practices in the management of CRTs around the world, with emphasis on the role of regulations, availability of recycling infrastructure, recycling/reuse routes, and export into developing countries. Inappropriate disposal of waste CRTs creates the opportunity for large-scale environmental contamination with heavy metals, especially lead. Appropriate disposal routes are required globally in the management of CRTs in order to mitigate environmental contamination and human exposure to toxins.     

The potential contribution of sustainable waste management to energy use and greenhouse gas emission reduction in the Netherlands

Future limitations on the availability of selected resources stress the need for increased material efficiency. In addition, in a climate-constrained world the impact of resource use on greenhouse gas emissions should be minimized. Waste management is key to achieve sustainable resource management. Ways to use resources more efficiently include prevention of waste, reuse of products and materials, and recycling of materials, while incineration and anaerobic digestion may recover part of the embodied energy of materials. This study used iWaste, a simulation model, to investigate the extent to which savings in energy consumption and CO₂ emissions can be achieved in the Netherlands through recycling of waste streams versus waste incineration, and to assess the extent to which this potential is reflected in the LAP2 (currently initiated policy). Three waste streams (i.e. household waste, bulky household waste, and construction and demolition waste) and three scenarios compare current policy to scenarios that focus on high-quality recycling (Recycling+) or incineration with increased efficiency (Incineration+). The results show that aiming for more and high-quality recycling can result in emission reductions of 2.3 MtCO₂ annually in the Netherlands compared to the reference situation in 2008. The main contributors to this reduction potential are found in optimizing the recycling of plastics (PET, PE and PP), textiles, paper, and organic waste. A scenario assuming a higher energy conversion efficiency of the incinerator treating the residual waste stream, achieves an emission reduction equivalent to only one third (0.7 MtCO₂/year) of the reduction achieved in the Recycling+ scenario. Furthermore, the results of the study show that currently initiated policy only partially realizes the full potential identified. A focus on highest quality use of recovered materials is essential to realize the full potential energy and CO₂ emission reduction identified for the Netherlands. Detailed economic and technical analyses of high quality recycling are recommended to further evaluate viable integrated waste management policies.