全文获取类型
收费全文 | 352篇 |
免费 | 63篇 |
国内免费 | 133篇 |
专业分类
安全科学 | 31篇 |
废物处理 | 49篇 |
环保管理 | 135篇 |
综合类 | 210篇 |
基础理论 | 29篇 |
污染及防治 | 48篇 |
评价与监测 | 4篇 |
社会与环境 | 10篇 |
灾害及防治 | 32篇 |
出版年
2024年 | 1篇 |
2023年 | 14篇 |
2022年 | 15篇 |
2021年 | 14篇 |
2020年 | 17篇 |
2019年 | 21篇 |
2018年 | 33篇 |
2017年 | 20篇 |
2016年 | 23篇 |
2015年 | 23篇 |
2014年 | 16篇 |
2013年 | 27篇 |
2012年 | 34篇 |
2011年 | 37篇 |
2010年 | 23篇 |
2009年 | 16篇 |
2008年 | 12篇 |
2007年 | 20篇 |
2006年 | 28篇 |
2005年 | 15篇 |
2004年 | 11篇 |
2003年 | 18篇 |
2002年 | 10篇 |
2001年 | 18篇 |
2000年 | 10篇 |
1999年 | 14篇 |
1998年 | 7篇 |
1997年 | 6篇 |
1996年 | 8篇 |
1995年 | 6篇 |
1994年 | 6篇 |
1993年 | 5篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1990年 | 3篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1980年 | 2篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1974年 | 1篇 |
1971年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有548条查询结果,搜索用时 0 毫秒
451.
452.
天然高分子改性阳离子絮凝剂的合成及其性能与机理的研究 总被引:20,自引:0,他引:20
以天然高分子物F691粉为原料,合成了一种新型阳离子絮凝剂FNQD。研究表明:在NaOH/F691质量比1、穹剂/F691质量比1.5,反应温度50℃、反应时间3h条件下,FNQD具有优导的絮凝性能。当PH=7、投加量3mg/1时,FNQCD对市内悬浊度去除率〉95%,絮凝性能明显优于PAM-C。机理表明FNQD与胶体颗粒间的镶嵌式引力和FNQD分子链的半刚性结构是FNQD具有优异的絮凝性能和良好 相似文献
453.
454.
利用水热法制备了Fe3O4纳米粒子(Fe3O4NPs),并对其进行改性制备了改性聚合物Fe3O4MMPs.同时,利用X射线衍射(XRD)、扫描电镜(SEM)和紫外可见漫反射(DRS)等手段对所制备的材料进行表征.通过比表面积(BET)测定发现,Fe3O4MMPs的比表面积较Fe3O4NPs增大约9倍.在可见光照射下(λ420 nm),以H2O2为氧化剂,比较研究了以Fe3O4NPs和Fe3O4MMPs为光催化剂降解罗丹明B(Rhodamine,RhB)的催化特性,并探讨了Fe3O4改性对催化活性的影响.结果表明,改性聚合物Fe3O4MMPs的稳定性增加,对底物RhB的降解活性提高,120 min时对RhB的脱色率在98%以上;此外,Fe3O4MMPs对水杨酸(Salicylic Acid,SA)也具有很好的降解效果.利用电子自旋共振技术(ESR)测定氧化物种的结果表明,降解过程涉及羟基自由基(·OH)和超氧自由基(·O-2)氧化机理. 相似文献
455.
456.
Streamflow,Sediment Transport,and Geomorphic Change during the 2011 Flood on the Missouri River Near Bismarck–Mandan,ND 下载免费PDF全文
Rochelle A. Nustad Adam J. Benthem Katherine J. Skalak Richard R. McDonald Edward R. Schenk Joel M. Galloway 《Journal of the American Water Resources Association》2018,54(5):1151-1167
Geomorphic change from extreme events in large managed rivers has implications for river management. A steady‐state, quasi‐three‐dimensional hydrodynamic model was applied to a 29‐km reach of the Missouri River using 2011 flood data. Model results for an extreme flow (500‐year recurrence interval [RI]) and an elevated managed flow (75‐year RI) were used to assess sediment mobility through examination of the spatial distribution of boundary or bed shear stress (τb) and longitudinal patterns of average τb, velocity, and kurtosis of τb. Kurtosis of τb was used as an indicator of planform channel complexity and can be applied to other river systems. From differences in longitudinal patterns of sediment mobility for the two flows we can infer: (1) under extreme flow, the channel behaves as a single‐thread channel controlled primarily by flow, which enhances the meander pattern; (2) under elevated managed flows, the channel behaves as multithread channel controlled by the interaction of flow with bed and channel topography, resulting in a more complex channel; and (3) for both flows, the model reach lacks a consistent pattern of deposition or erosion, which indicates migration of areas of erosion and deposition within the reach. Despite caveats and limitations, the analysis provides useful information about geomorphic change under extreme flow and potential implications for river management. Although a 500‐year RI is rare, extreme hydrologic events such as this are predicted to increase in frequency. 相似文献
457.
Dinuke Munasinghe Sagy Cohen Yu‐Fen Huang Yin‐Phan Tsang Jiaqi Zhang Zheng Fang 《Journal of the American Water Resources Association》2018,54(4):834-846
The objective of this study was to determine the accuracy of five different digital image processing techniques to map flood inundation extent with Landsat 8–Operational Land Imager satellite imagery. The May 2016 flooding event in the Hempstead region of the Brazos River, Texas is used as a case study for this first comprehensive comparison of classification techniques of its kind. Five flood water classification techniques (i.e., supervised classification, unsupervised classification, delta‐cue change detection, Normalized Difference Water Index [NDWI], modified NDWI [MNDWI]) were implemented to characterize flooded regions. To identify flood water obscured by cloud cover, a digital elevation model (DEM)–based approach was employed. Classified floods were compared using an Advanced Fitness Index to a “reference flood map” created based on manual digitization, as well as other data sources, using the same satellite image. Supervised classification yielded the highest accuracy of 86.4%, while unsupervised, MNDWI, and NDWI closely followed at 79.6%, 77.3%, and 77.1%, respectively. Delta‐cue change detection yielded the lowest accuracy with 70.1%. Thus, supervised classification is recommended for flood water classification and inundation map generation under these settings. The DEM‐based approach used to identify cloud‐obscured flood water pixels was found reliable and easy to apply. It is therefore recommended for regions with relatively flat topography. 相似文献
458.
The analysis of consequential alarms is beneficial to avoiding alarm flooding and finding out root alarms in an industrial process. In this context, a novel similarity computation method taking into account of correlation delays between process alarms is introduced firstly. Subsequently, the Granger causality method is suggested to further clarify mutual impacts of similar alarm variables based on process data. Through the combination of alarm data similarity analysis and process data causality analysis, the consequential alarms can be effectively identified along with their evolution paths. An industrial case is employed to illustrate the benefits of the contribution. 相似文献
459.
EG填充无卤阻燃型LDPE复合薄膜阻燃性能研究 总被引:1,自引:0,他引:1
为了改善聚合物低密度聚乙烯(LDPE)薄膜的阻燃性能,通过向其中添加膨胀型阻燃剂聚磷酸铵(APP)/季戊四醇(PER)和可膨胀石墨(EG),制备了无卤阻燃型低密度聚乙烯复合薄膜.实验研究了膨胀阻燃剂填充聚合物LDPE作为阻燃复合薄膜的性能,分析了膨胀阻燃剂的加入对复合膜阻燃性能、残重率和力学性能的影响机理.研究发现,该新型配方中的EG和APP/PER对复合薄膜的阻燃性能具有协同作用,当配方中APP/PER/EG的填充量达到30%质量分数(APP∶PER∶EG∶LDPE质量比16∶8∶6∶100)时,薄膜材料的氧指数可达到27.5%;与纯LDPE薄膜相比,阻燃薄膜的氧指数提高了10.3%,改善了阻燃效果. 相似文献
460.
A molecularly imprinted polymer (MIP) for selective removal of 2,4-dichlorophenol (2,4-DCP) in water was prepared as microspheres by the reverse microemulsion polymerization method based on the non-covalent interactions between 2,4-DCP, oleic acid, and divinylbenzene in acetonitrile. Microspheres have been characterized by Fourier transform infrared spectrometer (FTIR) and energy dispersive X-ray spectrometer (EDS) studies with evidence of 2,4-DCP linkage in polymer particles and scanning electron microscopy (SEM) to study their morphological properties. The proper adsorption and selective recognition ability of the MIP were studied by an equilibrium-adsorption method. The MIP showed outstanding affinity towards 2,4-DCP in aqueous solution and the optimum pH value for binding has been found around the neutral range. The molecular recognition of 2,4-DCP was analyzed in detail by using molecular modeling software. In addition, by investigating the variation in the adsorption ability of the MIP, it clearly showed excellent reproducibility. 相似文献