土壤溶液中镉的化学形态及化学平衡研究

据土壤溶液的实际情况建立简便的平衡模式,研究了红壤、黄棕壤、黄潮土三种典型土壤溶液中Cd的化学形态和化学平衡.结果表明,溶液中Cd的主要形态为Cd~(2+)、CdCl~+和CdSO_4~6.黄潮土还有一定量的CdHCO_3~+,其它形态Cd很少,其中游离Cd~(2+)占绝大部分.红壤最高,黄棕壤次之.红壤施石灰后游离Cd~(2+)下降,CdSO_4~6增加;添加氯化物后,溶液pH下降,大量Cd进入溶液中,CdCl~+比例明显升高.溶液中Cd的形态分布与土壤Cd的生物有效性有一定关系.此外,溶解度图证明,供试土壤中不可能有Cd的矿物生成.Cd在固液相间的平衡受吸附解吸反应控制.     

重庆南山马尾松衰亡与土壤铝活化的关系

研究了重庆南山马尾松衰亡与铝中毒的关系.发现南山土壤中活性铝含量相当高,而活性钙含量很低,轻灾区和重灾区的Al/Ca比都已超过伤害植物的阈值.试验结果表明,铝活化是土壤严重酸化的后果.溶液培养试验结果表明,铝对马尾松幼苗生长有明显毒害作用,且毒性最大的形态是Al~(3+),铝中毒是南山酸雨危害马尾松的主要原因.     

模拟酸雨对浙东北红壤中盐基离子和铝的淋失影响研究

通过对浙江省东北部杭州至宁波地区两个红壤剖面的模拟酸雨淋溶实验研究表明，随着时间的延续，盐基离子的淋失浓度会在某一时期出现一个峰值。该峰值的出现与酸雨的ｐＨ值并不简单相关，Ａｌ＾３＋的淋失浓度只是在酸雨ｐＨ值＝２．５左右才显增高并在淋出液ｐＨ＝４．０时有一个阈值，经ｐＨ＝２．５－３．０模拟酸雨１０余年降水量的淋溶，红壤中淋出液的ｐＨ值下降不超过０．８。     

南方山丘水库种草养鱼防淤减积综合利用的研究

在长沙县百倍冲水库进行多年的试验研究结果表明,开发利用库内长期荒芜的大片消落区种植黑麦草;荒山堤坝上种植扁穗牛鞭草、岸杂一号狗牙根、皇草、幼林间种植鸡脚草、拉丁鲁白三叶等饲草配套养鱼和防止水土流失、防淤减积试验获得成功。库内鲜鱼产量由种草前常年1000kg提高到7000～8000kg,泥砂淤积量每年减少0.516×104m3,经济生态效益显著。     

Elemental sulfur effects on Pb and Zn uptake by Indian mustard and winter wheat

A pot experiment was conducted to investigate the influence of elemental sulfur to contaminated soil on plant uptake by a heavy metal hyperaccumulator, Indian mustard( Brassica juncea ) and a field crop, winter wheat( Triticum. aestivum). Elemental sulfur(S) with different rates was carried out, they were 0(S0 ), 20(S20 ), 40(S40 ), 80(S80 ), and 160(S160 ) mmol/kg respectively. Extra pots with the same rates of S but without plants were used for soil sampling to monitor pH and CaCl2-extractable heavy metal changes. The results showed that S enhanced phytoextraction of Pb and Zn from contaminated soil. Application S effectively decreased soil pH down to 1.1 as the most at the rate of Sl60. The concentrations of CaCl2-extractable Pb and Zn in soil and uptake of Pb and Zn by the plants were increased with soil pH decreased. A good correlation between CaCl2-extractable Pb/Zn and soil pH was found( Rpb^2 = 0.847 and RZn^2 = 0,991, n = 25). With S application, soil CaCl2-extractable Pb and Zn concentrations, concentration of Pb and Zn in plants and the amount of removal by plant uptake were significanfly higher than those without S. Under the treatment of S160, the highest CaCl2-extmctable Pb and Zn were observed, they were 4.23 mg/kg and 0.40 mg/kg, 2.7 and 2.0 times as that of the control(So ) respectively. At the highest rates of S( Sl~0 ), both Indian mustard and winter wheat reached the highest uptake of Pb and Zn. The highest Pb concentrations in wheat and Indian mustard were 32.8 mg/kg and 537.0 mg/kg, all 1.8 times as that of the control, and the highest Zn concentrations in wheat and Indian mustard were 215.5 mg/kg and 404.0 mg/kg, 2.4 and 2.0 times as that of the control respectively. The highest removals of Pb and Zn from the contaminated soil were 0.41 rag/pot and 0.31 nag/pot by Indian mustard in the treatment of S160 through 50 days growth.     

铬在土壤-地下水系统中的污染研究

根据铬在土壤-地下水环境中的化学特性,通过实验,研究了两种价态的铬[Cr(Ⅲ),Cr(Ⅵ)]在水、土中的污染过程,并着重分析了Cr(Ⅵ)在水土体系中所产生的物理化学作用及其在土中的稳定性。结合铬污染实例,阐明了铬在水-土体系中污染的条件和迁移过程。     

Soil and water loss in the Lancang River-Mekong River watershed (in Yunnan section, China) and its control measures

ＭｅｋｏｎｇＲｉｖｅｒｉｓｏｒｉｇｉｎａｔｅｄｉｎｔｈｅｎｏｒｔｈｅｒｎｒａｎｇｅｏｆＴｉｂｅｔＱｉｎｇｈａｉＰｌａｔｅａｕｏｆＣｈｉｎａ,ｆｌｏｗｉｎｇｔｈｒｏｕｇｈｓｉｘｃｏｕｎｔｒｉｅｓ,ｔｈｅｙａｒｅＣｈｉｎａ(ＹｕｎｎａｎＰｒｏｖｉｎｃｅ),Ｍ?..     

土壤中嗪草酮迁移和降解的研究

 通过两季马铃薯大田试验，研究了嗪草酮在灌溉沙壤土中的消失和移动情况。结果表明，表层土壤中，嗪草酮施用后最初7～15天内其含量急剧降低，此后随时间推移降低幅度平缓，1993年和1994年试验结束时的残留量分别为5.9μg/kg和2.3μg/kg。两年共采集的379个土样（分布在15～75cm各土层）中只有5个检测到有嗪草酮。1994年大田135cm土层处的水样中，嗪草酮的检测率高达66％，检测浓度范围为0.06～15.85μg/kg，平均浓度为1.94μg/kg。相比较，嗪草酮在大田试验中的消失速率远大于实验室控制条件下的降解速率。     

Soil water characteristics in mountain poplar stand and its benefits to soil and water conservation in loess hilly region

ＳｏｉｌｗａｔｅｒｃｈａｒａｃｔｅｒｉｓｔｉｃｓｉｎｍｏｕｎｔａｉｎｐｏｐｌａｒｓｔａｎｄａｎｄｉｔｓｂｅｎｅｆｉｔｓｔｏｓｏｉｌａｎｄｗａｔｅｒｃｏｎｓｅｒｖａｔｉｏｎｉｎｌｏｅｓｓｈｉｌｌｙｒｅｇｉｏｎＷｕＱｉｎｘｉａｏ；ＬｉｕＸｉａｎｇｄｏｎｇ...     

城市生活垃圾堆肥对水稻生长和土壤的影响

利用城市生活垃圾堆肥作为肥料,采用水培法和土培法对水稻生长和土壤的影响进行了试验研究。结果表明,施用城市生活垃圾堆肥明显提高了水稻的生长量,增加了水稻植株茎叶中硅的含量;降低了糙米中有毒元素镉的含量;改变了土壤的酸度,增强了土壤的肥力;水稻植株和土壤中某些有害元素的含量略有增加,但远低于环境的允许值。