The structure of the fire fighting foam surfactant Forafac®1157 and its biological and photolytic transformation products

For several decades, perfluorooctane sulfonate (PFOS) has widely been used as a fluorinated surfactant in aqueous film forming foams used as hydrocarbon fuel fire extinguishers. Due to concerns regarding its environmental persistence and toxicological effects, PFOS has recently been replaced by novel fluorinated surfactants such as Forafac®1157, developed by the DuPont company. The major component of Forafac®1157 is a 6:2 fluorotelomer sulfonamide alkylbetaine (6:2 FTAB), and a link between the trade name and the exact chemical structure is presented here to the scientific community for the first time. In the present work, the structure of the 6:2 FTAB was elucidated by ¹H, ¹³C and ¹⁹F nuclear magnetic resonance spectroscopy and high-resolution mass spectrometry. Moreover, its major metabolites from blue mussel (Mytilus edulis) and turbot (Scophthalmus maximus) and its photolytic transformation products were identified. Contrary to what has earlier been observed for PFOS, the 6:2 FTAB was extensively metabolized by blue mussel and turbot exposed to Forafac®1157. The major metabolite was a deacetylated betaine species, from which mono- and di-demethylated metabolites also were formed. Another abundant metabolite was the 6:2 fluorotelomer sulfonamide. In another experiment, Forafac®1157 was subjected to UV-light induced photolysis. The experimental conditions aimed to simulate Arctic conditions and the deacetylated species was again the primary transformation product of 6:2 FTAB. A 6:2 fluorotelomer sulfonamide was also formed along with a non-identified transformation product. The environmental presence of most of the metabolites and transformation products was qualitatively demonstrated by analysis of soil samples taken in close proximity to an airport fire training facility.     

Gas/particle partitioning of atmospheric PCDD/Fs in a satellite town in Eastern China

Gas/particle partitioning of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in ambient air was investigated in a satellite town in Eastern China from April 2007 to January 2008 comprehending large temperature variations (from 3 to 34 °C, daily average). Molecular weight, molecular structure and ambient temperatures are the three major factors that govern the gas/particle partitioning of atmospheric PCDD/Fs throughout the year. Generally, good agreements were obtained (except for winter) between measured particulate fractions and theoretical estimates of both the Junge–Pankow adsorption model and Harner Bidleman absorption model using different sets of subcooled liquid vapor pressure and octanol–air partition coefficient (K_oa), respectively. Models utilizing estimates, derived from gas chromatographic retention indices (GC-RIs), are more accurate than that of entropy-based. Moreover, during winter, the K_oa-based model using the GC-RIs approach performs better on lower chlorinated PCDD/Fs than that of -based. Furthermore, possible sources of mismatch between measured and predicted values in winter (3–7 °C) were discussed. Gas adsorption artifact was demonstrated to be of minor importance for the phenomena observed. On the other hand, large deviations of slopes (m_r) and intercepts (b_r) in logK_p vs. plots from theoretical values are observed in the literature data and these are found to be linearly correlated with ambient temperatures (P<0.001) in this study. This indicates that the non-equilibrium partitioning of PCDD/Fs in winter may be significantly influenced by the colder temperatures that may have slowed down the exchange between gaseous and particulate fractions.     

西昌市大气污染现状调查及保护对策

本文对西昌市大气污染现状进行调查分析，揭示了大气环境污染的特征及其变化规律，从宏观上提出了保护大气环境的对策。     

玉.玉文化.旅游

开发旅游新产品，是促进我国旅游业不断迈上新台阶需要研究解决的问题之一。本文通过作者实施踏勘和检索有关文献，阐述了玉的种类及其主要产地的状况，并揭示它新蕴涵的文化内容。     

印染废水静电场处理机理分析

本文提出一种利用静电场的印染废水处理方法，印染废水中的污染颗粒在电场的作用下，朝一定的方向迁移，从而发生“强制电中和”作用，这种电中和作用的场能消耗极小，而被中和的污染物颗粒由于凝聚作用，则会不断长大而易于通令过滤去除，这一处理工艺在经“自数”预处理之后，可继续使COD和色度的去除百分数分别达60％和63％以上。     

PHOSPHORUS MANAGEMENT TO PROTECT LAKE WATER QUALITY1

ABSTRACT: The Hallett Quarry gravel pit lakes are an active sand and gravel extraction operation located 0.4 km north of the City of Ames, Iowa. During periods of drought, these lakes serve as a supplemental water supply for Ames. A modified version of the Vollenweider input-output model was used to predict future water quality under various watershed land use, drainage, and lake configurations. The dominant factor controlling the future water quality of the lakes was found to be the nutrient input. It is recommended that a management plan to protect the future water quality should be oriented towards reducing the sources of phosphorus to the lakes.     

THE EFFECTS OF A MOVING RAINSTORM ON DIRECT RUNOFF PROPERTIES1

ABSTRACT: The effects of a moving rainstorm on flood runoff characteristics were investigated. A flood hydrograph simulation model called “FH-Model” and a natural watershed were used. A hypothetical rainstorm of 50 years recurrence interval, 75 mm depth, and 4 hours duration was used to show the effects of velocity and direction of the moving rainstorm on the runoff characteristics. Compared with an equivalent stationary rainstorm (ESRS), the peak flow caused by a rainstorm moving in a downstream direction with a speed equal to channel velocity, V, was 27.5 percent higher and the peak flow caused by the same rainstorm moving in an upstream direction was 21.7 percent smaller. These percentages reduced to 10.5 percent and 8.6 percent for storms moving downstream and upstream, respectively, at three times the channel velocity, 3V. There were negligible differences in the time of peak, T_p between runoff caused by storms moving downstream and runoff produced by ESRS. However, T_p for a storm moving upstream at V velocity was 82 percent higher than that produced by ESRS, but was reduced to 27 percent higher when the storm velocity was 3V.     

A PRELIMINARY QUANTIFICATION OF THE IMPACTS OF ASPEN TO CONIFER SUCCESSION ON WATER YIELD- II. MODELING RESULTS1

ABSTRACT: Heat pulse velocity techniques were developed for effective monitoring of water movement in aspen (Populus tremuloides), subalpine fir (Abies lasiocarpa), and Englemann spruce (Picea engelmannif). Water loss was monitored in replicated trees of each species for one year. These data were used to modify the plant activity index (a reflection of the ability of plants to transpire water at various times during a year) and the crop coefficient (a reflection of differences in consumptive use rates of water by different vegetation types when all other factors are held constant) for each species within the model ASPCON, a deterministic, lumped-parameter model describing the hydrology of aspen to conifer succession. Results of the modeling in dicate 18.6 cm net loss of moisture available for streamflow when spruce replaced aspen, and a loss of 7.2 cm when fir forests replaced aspen. The aspen to conifer successional trend appears, therefore, to be significantly reducing water yields in the western United States.     

A FIELD TECHNIQUE FOR WEIGHING BEDLOAD SAMPLES1

ABSTRACT: A technique for weighing bedload samples that was developed for laboratory use has been modified for field application. The technique involves determining the submerged weight of bedload samples as they are collected. The submerged weights are converted to dry weights from a knowledge of the specific gravity of the bedload material. The technique makes bedload transport data available immediately and eliminates costly and time-consuming steps involved with saving samples for laboratory analysis. Only samples designated for particle-size or other lab analyses need to be saved.     

FACTORS CONTROLLING RUNOFF NUTRIENT LOSS FROM CULTIVATED LAND IN EASTERN SOUTH DAKOTA1

ABSTRACT A stepwise multiple regression was used to evaluate the relative importance of antecedent-, event-, and high-intensity-precipitation amounts; runoff volume; and precipitation nutrient contents and concentrations in determining nutrient losses in runoff. Plots were fertilized at high, medium, and low rates and had cultivation ridges oriented up-and-down slope or on the contour. Runoff volume was the important factor in determining the loss of NO₃, soluble PO₄, total PO₄, and soluble K ions in runoff from fallow, corn, or soybean plots. NH₄-N loss was controlled mainly by the precipitation content and antecedet precipitation since fertilizer had been applied. Nutrient losses were greater from plots fertilized at the high rate and from plots with cultivation ridges oriented up-and-down slope rather than on the contour.