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针对矿业废弃地高背景值-历史矿业源相叠加区下土壤重金属Cd污染问题,以西南地区某历史硫磺矿业废弃地重构土壤为研究对象,采集剖面土壤共30个样品,分析测试土壤样品中镉(Cd)、铬(Cr)、镍(Ni)、砷(As)和汞(Hg),利用电镜扫描-能谱分析(SEM-EDS)和重金属形态连续提取的BCR方法,分析不同土层厚度下Cd的赋存形式,运用风险评价编码法(RAC)和次生相与原生相分布比值法(RSP)对其进行有效性评价,以及对不同理化性质下Cd各形态的变化规律进行了初步探讨.结果表明,研究区5种重金属中Cd全量的富集系数最高,达4以上;通过形貌特征可以发现,样品中存在较多的次棱角状、棱角状颗粒,不同深度下的能谱特征显示结果相似,均含有Cd、Fe、S和As等元素,Cd元素是以类质同象形式存在;对Cd进行潜在风险评价,RAC结果显示为中等风险及以下,RSP结果主要为重度污染;重金属全量是影响Cd各形态含量分布的最主要因素,其次pH、有机质和CEC,对垂直深度的土壤Cd赋存形态也表现出不同程度的影响.该研究结果可为进一步了解Cd在剖面土壤的活性、迁移规律、生物毒性和赋存形式提供科学依据. 相似文献
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徐元凤 《中国个体防护装备》2012,(2):52-52
为了保证乘客的健康与安全,欧盟最近发布实施了一项新的关于机场安检人体扫描设备的法规。该新法规要求欧盟成员国更换现行人体扫描仪器的安检系统.因为现行扫描仪器是采用X射线扫描技术.它会对人体造成DNA的辐射并引发癌症。新的扫描系统采用的毫米波扫捕.即利用低能耗无线电波进行扫描。 相似文献
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To utilize visible light more effectively in photocatalytic reactions, a fly ash cenosphere (FAC)-supported CeO2-BiV04 (CeO2-BiVO4/FAC) composite photocatalyst was prepared by modified metalorganic decomposition and impregnation methods. The physical and photophysical properties of the composite have been characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and energy dispersive X-ray spectroscopy (EDX), X-ray photoelectron spectroscopy (XPS), and UV-Visible diffuse reflectance spectra. The XRD patterns exhibited characteristic diffraction peaks of both BiVO4 and Ce02 crystalline phases. The XPS results showed that Ce was present as both Ce4+ and Ce3+ oxidation states in Ce02 and dispersed on the surface of BiV04 to constitute a p-n heterojunction composite. The absorption threshold of the CeO2-BiVO4/FAC composite shifted to a longer wavelength in the UV-Vis absorption spectrum compared to the pure Ce02 and pure BiV04. The composites exhibited enhanced photocatalytic activity for Methylene Blue (MB) degradation under visible light irradiation. It was found that the 7.5 wt.% CeO2-BiVO4/FAC composite showed the highest photocatalytic activity for MB dye wastewater treatment. 相似文献
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Mechanism of Cu(Ⅱ) adsorption inhibition on biochar by its aging process 总被引:13,自引:0,他引:13
Biochar exposed in the environment may experience a series of surface changes, which is called biochar aging. In order to study the effects of biochar aging on Cu(Ⅱ) adsorption, we analyzed the surface properties before and after biochar aging with scanning electron microscopy(SEM) coupled to an energy-dispersive X-ray spectrometer(EDX) and diffuse reflectance infrared Fourier transform spectroscopy(DRIFTS), and then explored the influence of the aging process on Cu(Ⅱ) adsorption by batch experiments. After the aging process, the oxygen concentration, phenolic hydroxyl groups, aromatic ethers and other oxygen-containing functional groups on the biochar surface increased, while carboxyl groups slightly decreased. Thus, over a range of pH, the cation exchange capacity(CEC) and adsorption capacity of Cu(Ⅱ) on the aged biochar were smaller than those of new biochar,indicating that when biochar is incubated at constant temperature and water holding capacity in the dark, the aging process may inhibit Cu(Ⅱ) adsorption. Meanwhile, the dissociation characteristics of oxygen-containing functional groups changed through the aging process, which may be the mechanism by which the biochar aging process inhibits the Cu(Ⅱ) adsorption. Carboxyl groups became more easily dissociated at low pH(3.3–5.0),and the variation of maximum adsorption capability(qm) of Cu(Ⅱ) on the old biochar was enlarged. Phenolic hydroxyl groups increased after the aging, making them and carboxyl groups more difficult to dissociate at high pH(5.0–6.8), and the variation of qmof Cu(Ⅱ) on the aged biochar was reduced. 相似文献