膜法水处理在油田和石化行业中的应用

在石油开采和石化加工过程中耗水量巨大,为了环保和降低成本需求,对污水的处理回用技术就显得十分重要。膜法水处理是一项发展迅猛的技术,在油田和石化行业中采用膜法处理污水,可以节约资源,保护环境,降低成本。1膜技术概论随着材料学和各种分离理论的发展,膜分离技术取得了迅猛的发展。膜分离是利用功能膜作为分离介质,实现     

Transformations of particles, metal elements and natural organic matter in different water treatment processes

Characterizing natural organic matter （NOM）, particles and elements in different water treatment processes can give a useful information to optimize water treatment operations. In this article, transformations of particles, metal elements and NOM in a pilot-scale water treatment plant were investigated by laser light granularity system, particle counter, glass-fiber membrane filtration, inductively coupled plasma-optical emission spectroscopy, ultra filtration and resin absorbents fractionation. The results showed that particles, NOM and trihalomethane formation precursors were removed synergistically by sequential treatment of different processes. Preozonation markedly changed the polarity and molecular weight of NOM, and it could be conducive to the following coagulation process through destabilizing particles and colloids; mid-ozonation enhanced the subsequent granular activated carbon （GAC） filtration process by decreasing molecular weight of organic matters. Coagulation-flotation and GAC were more efficient in removing fixed suspended solids and larger particles; while sand-filtration was more efficient in removing volatile suspended solids and smaller particles. Flotation performed better than sedimentation in terms of particle and NOM removal. The type of coagulant could greatly affect the performance of coagulation-flotation. Pre-hydrolyzed composite coagulant （HPAC） was superior to FeCl3 concerning the removals of hydrophobic dissolved organic carbon and volatile suspended solids. The leakages of flocs from sand-filtration and microorganisms from GAC should be mitigated to ensure the reliability of the whole treatment system.     

Biological control experiment of excess propagation of Cyclops for drinking water security

Cyclops of zooplankton propagated excessively in eutrophic water body and could not be effectively inactivated by the conventional disinfections process like chlorination due to its stronger resistance to oxidation. In this study, an ecological project was put forward for the excess propagation control of Cyclops by stocking the filter-feeding fishes such as silver carp and bighead carp under the condition of no extraneous nutrient feeding. The results of experiments with different stocking biomass showed that the propagation of Cyclops could be controlled effectively, and the water quality was improved simultaneously by impacting on nutriment level and plankton community structure at proper stocking density of 30 g/m^3 of water. The growth of Cyclops may not be effectually controlled with lower biomass of fish （10 g）, and the natural food chain relation may be destroyed for Cyclops dying out in water while the intense stocking of 120 g per cubic meter of water. In addition, the high predator pressure may accelerate supplemental rate of nutrients from bottom sediments to water body to add the content of total nitrogen and phosphorus in water.     

低温A/O-MBR工艺启动试验研究

研究了A/O-MBR工艺低温(水温在5~12℃)启动效能,结果表明,低温下A/O-MBR工艺启动迅速,活性污泥的培养驯化时间较短。启动过程中根据出水水质情况,逐渐提高负荷,运行34 d,系统对COD的去除率能达到90%以上,系统对氨氮的去除率能达到96%以上,至稳定运行后氨氮的负荷平均可达到0.419kg/(m3.d),反硝化效果系统去除率基本能稳定在60%左右。     

典型气浮净水设备评述

文章主要从气浮设备的原理与结构、优缺点、应用情况等方面评述了加压溶气气浮设备、涡凹气浮设备、浅层气浮设备、电气浮设备、充气水力旋流器、多段环流气浮塔和旋流-充气气浮系统等气浮设备,并讨论了气浮设备的研究和应用发展趋势。     

光助-Fenton法处理均酐生产废水的实验研究

采用光助-Fenton处理均苯四甲酸二酐生产废水。以废水的TOC去除率为指标,通过单因素试验和正交试验,对影响光助-Fenton的因素进行分析。结果表明:室温下,在反应初始pH=3.5,[H2O2]=12mmol/L,[Fe2+]=1.5mmol/L,反应时间为80min,光源为500W汞灯的条件下,TOC的去除率NN达到76%。     

物理水处理技术在循环冷却水处理中的应用

物理法替代化学法处理循环冷却水已得到越来越多的重视。本文综述了物理水处理技术的机理和研究现状,指出了现行物理处理法在循环冷却水处理中存在的问题,并对其发展前景做了展望,合理了利用是一个水处理行业中的可持续的方法。     

油田回注水质稳定处理及测试

油田回注水质存在不稳定情况,影响注水效果。通过分析水质pH、溶解氧、二价还原性离子及细菌等因素,明确了导致水质不稳定的原因。通过控制水质不稳定因素的方式促进水质稳定,确保其达到回注要求。以两个具体实例说明针对水质自身的特点采取相应的措施,可促进水质稳定。针对1#水样低pH、高浓度二价铁的特点,筛选并投加50 mg/L pH调节剂ZYJ-1以及20 mg/L预氧化剂,促进了回注水质的稳定。针对2#水样高含硫、高含细菌、腐蚀严重的问题,投加100 mg/L杀菌剂ZYC-4,40 mg/L氧化除硫剂,处理后水质腐蚀速率从1.0226 mm/a下降到0.0461 mm/a,达到回注要求。     

日本膜技术的发展与产业化及其借鉴意义

对日本膜技术发展历史及现状进行了系统梳理。研究表明,经过数十年持续不断的投入,日本膜技术已广泛应用在净水处理、生活污水处理、工业废水处理及脱盐等领域,并在国际市场占据重要地位。虽然受本土市场规模的局限,超滤微滤膜在日本给水处理领域的处理规模仅为1.3×106m3d,反渗透膜脱盐能力为1.44×106m3d,但日本的超滤微滤膜在全球给排水领域的应用约为1.0×107m3d,反渗透膜产品在全球的应用超过3.0×107m3d。建议我国膜企业应借鉴日本膜产业的发展经验,加大膜企业的研发投入,加强膜技术的研发创新能力,通过提供更高性价比的产品和卓越的技术服务开拓国际市场。     

欢迎订阅《工业水处理》杂志

正《工业水处理》杂志于1981年创刊,是经国家科委和国家新闻出版署批准,由中海油天津化工研究设计院主办的专业性科技刊物。专门报道国内外循环冷却水、锅炉水、工艺用水及工业废水的水处理技术动态、科研成果、实践经验及科学管理等内容,设有专论与综述、试验研究、分析与监测、经验交流、工程实例、油气田水处理、科学管理等栏目。涵盖领域广阔、内容丰富严谨、信息反应快捷,是反映当代水处理技术面貌的权威性杂志,深受水处理工作者的喜爱。适于从事工业水处理领域科研、设计、生产、教学等工作的单位及个人订阅。