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Jun HUANG Yamei HUI Toru MATSUMURA Gang YU Shubo DENG Makoto YAMAUCHI Changmin WU Norimasa YAMAZAKI 《Frontiers of Environmental Science & Engineering》2014,8(2):195-204
Homolog and congener profiles of polychlori- nated biphenyls (PCBs), polychlorinated dibenzo-p- dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) in commercial PCBs formulations are useful information for the source appointment of PCBs contam- ination as well as the risk assessment caused by potential exposure. Dielectric oil (ASKAREL Nr 1740) in an imported transformer found in China was sampled and analyzed by isotope dilution technology using high resolution gas chromatography-high resolution mass spectrometry (HRGC/HRMS). The detailed homolog and congener profiles of PCBs obtained were compared with those of known Aroclor formulations. High similarity in the homolog profile between the oil sample and Aroclor 1260was found, with the hexachlorinated and hepta- chlorinated biphenyls accounting for more than 80.2% of the total PCBs concentration. Severn indicator PCBs contribute about 30%, while 12 PCB congeners (i.e., # 153, #143, #168, #180, #149, #165, #138, #170, #190, #187, #174, #181) account for more than 50% of the total PCB concentrations. Total concentration ofPCDDs, PCDFs and dioxin-like PCBs (DL-PCBs) was found to be 740 ng TEQ/g, of which 620 ng TEQ/g came from DL-PCBs. The contribution of PCDDs to the total TEQ was neglectable. The concentration of PCDFs homologs follows the order of OCDF 〉 HxCDFs 〉 HpCDFs 〉 PeCDFs 〉 TeCDFs, which is in consistence with the previous study on Aroclor 1260. Three DL-PCBs congeners (i.e., #118, #156, #157) accounted for 77% of the total concentration of DL-PCBs, also they contribute 72% in the TEQ caused by DL-PCBs. 相似文献
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The activities of CeO2 nanocubes calcined at di erent temperatures were tested for catalytic oxidation of o-xylene. Using
CeO2 nanocubes as catalysts, complete catalytic oxidation of o-xylene was achieved below 210°C. The CeO2 nanomaterials were
characterized by means of BET, X-ray di raction (XRD), transmission electron microscopy (TEM), and high-resolution transmission
electron microscopy (HRTEM). From the TEM images, all CeO2 nanocubes displayed cubic morphology irrespective of calcination
temperature. The HRTEM images revealed that these nanocubes were enclosed by reactive f001g planes, which may contribute to the
intrinsically catalytic property of o-xylene oxidation. The higher activity of CeO2 nanocubes calcined at 550°C than those calcined
at above 550°C was attributed to their smaller crystallite size and larger surface area. The influences of reaction conditions were also
studied, which found that a higher reaction temperature was necessary for complete catalytic oxidation of o-xylene at higher weight
hourly space velocity (WHSV) and o-xylene concentration. 相似文献
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利用EIA法快速筛查垃圾焚烧飞灰和烟气中的二恶英毒性水平 总被引:3,自引:0,他引:3
基于CAPE技术公司的兔子复合克隆抗体的二恶英(PCDD/F)酶免疫分析试剂盒,建立了快速检测垃圾焚烧飞灰和烟气中PCDD/F毒性(TEQ值)的方法.试剂盒的最低检测限为3.3pg·tube-1(即3.3pgTEQ每EIA试管),线性检测范围为10~30pg·tube-1.样品经甲苯索氏抽提后过硅胶柱连接小碳柱净化处理,TCDD/F的回收率大约为50%,与原飞灰PCDD/F分布模式相比净化处理后样品中的TCDD/F含量明显降低.用净化处理后的飞灰溶液作标准溶液,绘制PCDD/F剂量-效应关系曲线,定量分析了2个飞灰样品和2个烟气样品的TEQ浓度,结果表明分析样品的TEQ实测值(HRGC/HRMS分析获得)与预测值(标准曲线计算值)的相对偏差(Rd)均小于15%,说明用该方法定量分析垃圾焚烧飞灰和烟气中PCDD/F毒性是可行的. 相似文献
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钢铁厂及其周围土壤中二恶英和多氯联苯污染物的分布规律研究 总被引:3,自引:1,他引:2
利用同位素稀释高分辨气相色谱-高分辨质谱(HRGC/HRMS)的分析方法研究了东北某钢铁厂及其周围生活区、背景对照区土壤中二噁和多氯联苯污染物的污染水平和分布规律。结果表明,土壤中二噁的浓度和毒性当量分别为26pg/g(6.02~109pg/g)、0.72pg I-TEQ g-1(0.008~5.43pg I-TEQ g-1)。土壤中多氯联苯的浓度为955pg/g(268~3504pg/g),毒性当量值达0.07pg TEQ g-1(0.006~0.33pg TEQ g-1)。该区域土壤中的二噁和多氯联苯浓度明显低于一般国家居住地的土壤控制标准,处于较低的污染水平。 相似文献