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121.
冶金污泥稳定化/固化处理工艺研究 总被引:4,自引:0,他引:4
冶金工业在生产过程中产生大量酸性废水.对这类废水目前通常采用石灰中和沉淀处理.文章中通过研究采用水泥和工业废渣作固化基材固化处理冶金工业酸性废水用石灰混凝所产生的含铜、砷的污泥,分析了影响固化块抗压强度的多种因素,采用固体废物浸出毒性浸出方法对浸出率进行实验探讨. 相似文献
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采用粒径<200μm、在酸碱介质中溶胀率小且能稳定存在的壳聚糖/PVA微粒对Cu2+的吸附进行了研究,结果表明,在pH 6,室温条件下,其饱合吸附量达56.0mg/g,随温度升高,吸附量降低.通过计算不同温度下各热力学参数△G0、△H0和△S0,证实该吸附为自发的放热过程.对实验数据运用相关数学模型拟合,显示等温吸附平衡符合Langmuir模型,吸附过程动力学更适合二级反应,被吸附在壳聚糖/PVA微粒上的Cu2+,可被0.01mo/L的EDTS或HNO3溶液快速地脱附出来,其洗脱率分别为85.3%和65.9%. 相似文献
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Xiaoyang Fan Yili Wang Daxin Zhang Yajie Guo Shihui Gao Enrui Li Huaili Zheng 《环境科学学报(英文版)》2020,32(5):73-84
The effects of four conditioning approaches:Acid,Acid-zero-valent iron(ZVI)/peroxydisulfate(PMS),Fe(Ⅱ)/PMS and ZVI/PMS,on wastewater activated sludge(WAS) dewatering and organics distribution in supernatant and extracellular polymeric substances(EPS) layers were investigated.The highest reduction in bound water and the most WAS destruction was achieved by Acid-ZVI/PMS,and the optimum conditions were pH 3,ZVI dosage 0.15 g/g dry solid(DS),oxone dosage 0.07 g/g DS and reaction time 10.6 min with the reductions in capillary suction time(CST) and water content(Wc) as 19.67% and 8.49%,respectively.Four conditioning approaches could result in TOC increase in EPS layers and supernatant,and protein(PN) content in tightly bound EPS(TB-EPS).After conditioning,organics in EPS layers could migrate to supernatant.Polysaccharide(PS) was easier to migrate to supernatant than PN.In addition,Acid,Acid-ZVI/PMS or Fe(Ⅱ)/PMS conditioning promoted the release of some polysaccharides containing ring vibrations v P=O,v C-O-C,v C-O-P functional groups from TB-EPS.ESR spectra proved that both radicals of SO_4~-· and·OH contributed to dewatering and organics transformation and migration.CST value of WAS positively correlated with the ratios of PN/PS in LB-EPS and total EPS,while it negatively correlated with TOC,PN content and PS content in TB-EPS,as well as PS content in supernatant and LB-EPS.BWC negatively correlated to zeta potential and TOC value,PN content,and HA content in supernatant. 相似文献
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Guofei Jiang Benjie Zhu Junzhi Sun Fang Liu Yongqiang Wang Chaocheng Zhao 《环境科学学报(英文版)》2023,35(3):244-257
High-efficiency photocatalysts are of great significance for the application of photocatalytic technology in water treatment.In this study,N/Cu co-doped ZnS nanosphere photocatalys(N/Cu-ZnS) is synthesized by a hydrothermal method for the first time.After doping,the tex ture of nanosphere becomes loose,the nanometer diameter is reduced,making the specific surface area of catalyst increased from 34.73 to 101.59 m2/g.The characterization results show that more ZnS (111) crystal planes a... 相似文献
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采用聚合羟基复合阳离子合成交联黏土A1-Ce-PILC,经SO4^2-改性后,以浸渍法制备了铜基交联黏土催化剂Cu/A1-Ce-PILC,并将其应用于C3H6选择性催化还原NO的反应,350℃时NO转化率达到最大值56%,700℃时下降至22%.为探究催化剂高温失活的原因,采用XPS、TPR、TGA、Py-IR和DSC对反应前后催化剂的物化性能进行了表征.结果表明,经过H2预处理活化后活性组分Cu物种以Cu^+形式存在,而高温反应后Cu物种除以Cu^+和Cu^2+ 2种形式存在外,还出现了少量CuO物种;高温反应过程中A1-Ce-PILC上结构羟基和SO4^2-流失导致催化剂表面酸性减弱;此外,还存在表面积炭覆盖了部分活性中心并堵塞了催化剂孔道的现象.这三者的共同影响促进了C3H6深度氧化,抑制了NO还原,从而导致催化剂的失活. 相似文献
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Robert France 《Environmental management》1996,20(2):249-255
Due to assimilation of recycled CO2 from litter decomposition and photosynthetic changes in carbon fractionation at low light levels, the foliage at the base of a forest is often more depleted in13C compared to that exposed to the atmosphere in either the canopy or in open clearings. This is referred to as the canopy effect. African research has indicated that these habitat differences in foliar 13C can be substantial enough to affect the carbon isotope ratios of resident fauna. Previous work documenting a 30-year chronology on moose teeth from Isle Royale National Park indicated a progressive depletion in13C and suggested that this could be due to forest regrowth following extensive burning. The present study examined the assumption implicit in this hypothesis that foliar 13C varies between open and closed boreal forest sites. I found a marginal canopy effect of 2 13C difference between upper canopy and ground flora for a forest in northwestern Ontario and an average difference of 1.2 in under- and mid-story vegetation between closed forests and open clear-cuts. Because of these small differences, the utility of carbon isotope analysis in quantifying temporally integrated exploitation of deforested habitats will be low for northern boreal locations. In denser forests, such as those in the tropics or western North American where the canopy effect can be expected to be much greater, 13C analysis may still offer some promise for determining selection by wildlife of disturbed habitats. 相似文献