内蒙古省级层面碳汇总量评估必要性与框架初探

结合国内外最新研究进展，制定适合内蒙古区域特点的碳汇测算方法和评估体系框架，科学估算碳汇状况，系统分析我区不同陆地生态系统类型的碳汇大小及其机制，可提供关于我区陆地生态系统碳汇功能可信、翔实和正确的估算结果；新时期省级层面上开展陆地生态系统碳汇总量评估十分重要。     

Modeling the carbon dynamics of the La Grande hydroelectric complex in northern Quebec

A mechanistic semi-empirical carbon cycle model of the La Grande reservoir complex in northern Quebec, Canada was conceived in order to investigate the climate impact of such a large alteration of the continental water cycle. The model includes inputs from the drainage basin, organic matter release from flooded soils, CO₂ emissions across the water-atmosphere interface and sedimentation. Most input data stems from previous research by our group on those ecosystems. The model includes the seven reservoirs of the La Grande complex and was run for periods of 50 and 100 years. Terrigeneous dissolved, particulate and suspended soil carbon fluxes and concentrations were computed. Over 100 years, 31.3 × 10¹² g C are released from flooded soils, equivalent to 28-29% of inputs from the drainage basin. 40-74% of dissolved organic carbon is mineralized. CO₂ fluxes over 100 years are 50.5-79.8 × 10¹² g C, 46.4-67.9 × 10¹² g C more than in the absence of reservoirs. The increase in mineralization of organic matter and in CO₂ emissions is a result of the increase in cumulated water residence time due to the creation of the reservoirs. Changes in other carbon sinks and sources likely offset a part of this additional carbon flux to the atmosphere. In the first years following flooding of the reservoir, organic carbon release from flooded soils exceeds CO₂ emissions, implying the downstream export of large quantities of eroded soil organic carbon. After this initial period, CO₂ emissions are fuelled by organic carbon originating from the drainage basin.     

Modelling the impact of nitrogen deposition, climate change and nutrient limitations on tree carbon sequestration in Europe for the period 1900-2050

We modelled the combined effects of past and expected future changes in climate and nitrogen deposition on tree carbon sequestration by European forests for the period 1900-2050. Two scenarios for deposition (current legislation and maximum technically feasible reductions) and two climate scenarios (no change and SRES A1 scenario) were used. Furthermore, the possible limitation of forest growth by calcium, magnesium, potassium and phosphorus is investigated. The area and age structure of the forests was assumed to stay constant to observations during the period 1970-1990. Under these assumptions, the simulations show that the change in forest growth and carbon sequestration in the past is dominated by changes in nitrogen deposition, while climate change is the major driver for future carbon sequestration. However, its impact is reduced by nitrogen availability. Furthermore, limitations in base cations, especially magnesium, and in phosphorus may significantly affect predicted growth in the future.     

A survey on the public perception of CCS in France

An awareness and opinion survey on carbon capture and storage (CCS) was conducted on a representative sample of French residents aged 15 years and above. About 6% of respondents were able to provide a satisfactory definition of the technology. The key question about ‘approval of or opposition to’ the use of CCS in France was asked twice, first after presenting the technology, then after explaining its potential adverse consequences. The approval rates, which were 59% and 38%, respectively, show that there is no a priori rejection of the technology. The sample was split in two to test for a semantic effect: half of the questionnaires used “Stockage” (English: storage), the other half “Sequestration”. Manipulating the vocabulary had no statistically significant effect on approval rates. Stockage is more meaningful, but does not convey the idea of permanent monitoring.     

Payments for Environmental Services in Latin America as a Tool for Restoration and Rural Development

Payments for Environmental Services (PES) can encourage projects that enhance restoration, production, and rural development. When projects promote differentiated systems by paying farmers for the provision of services, the application of PES requires evaluation of the environmental services provided by each system. We present evaluations of carbon stocks and biodiversity in pure and mixed native tree plantations in Costa Rica. To illustrate how monetary values can be assigned, we discuss a project that awarded PES to silvopastoral systems in Costa Rica, Nicaragua, and Colombia based on carbon stocks and biodiversity. PES can promote positive environmental attitudes in farmers. Currently this project is being scaled up in Colombia based on their positive experiences with PES as a tool to promote adoption. Compared to PES systems that include only one environmental service, systems that incorporate bundling or layering of multiple services can make sustainable land uses more attractive to farmers and reduce perverse incentives.     

火电厂CO2捕集与封存技术探讨

火电厂CO2减排技术主要包括燃烧前处理、燃烧中减排及燃烧后捕集三类。介绍了IGCC、富氧燃烧、胺吸收法、生物法等CO2捕集与封存技术,分析其存在问题及应用前景。     

Elevated carbon dioxide does not offset loss of soil carbon from a corn-soybean agroecosystem

The potential for storing additional C in U.S. Corn Belt soils - to offset rising atmospheric [CO₂] - is large. Long-term cultivation has depleted substantial soil organic matter (SOM) stocks that once existed in the region's native ecosystems. In central Illinois, free-air CO₂ enrichment technology was used to investigate the effects of elevated [CO₂] on SOM pools in a conservation tilled corn-soybean rotation. After 5 and 6 y of CO₂ enrichment, we investigated the distribution of C and N among soil fractions with varying ability to protect SOM from rapid decomposition. None of the isolated C or N pools, or bulk-soil C or N, was affected by CO₂ treatment. However, the site has lost soil C and N, largely from unprotected pools, regardless of CO₂ treatment since the experiment began. These findings suggest management practices have affected soil C and N stocks and dynamics more than the increased inputs from CO₂-stimulated photosynthesis.     

Carbon nanotubes as sorbents in the analysis of pesticides

With increasing public concerns for agrochemicals and their potential movement in the ecosystem, very sensitive, selective and precise methods for the analysis of pesticides are needed. Because these substances are present usually at trace levels, the extraction and preconcentration steps are so far essential for their detection. Discoveries of novel nanomaterials with unique properties have significant impact on their use also in extraction techniques. This overview reports the recent application of carbon nanotubes in the analysis of pesticides. The largest numbers of reported applications of carbon nanotubes concern their role as a sorbent materials in solid-phase extraction and microextraction techniques.     

Kinetics of carbon dioxide absorption into mixed aqueous solutions of MDEA and MEA using a laminar jet apparatus and a numerically solved 2D absorption rate/kinetics model

New comprehensive numerically solved 1D and 2D absorption rate/kinetics models have been developed, for the first time, to interpret the experimental kinetic data obtained with a laminar jet apparatus for the absorption of carbon dioxide (CO₂) in CO₂ loaded mixed solutions of mixed amine system of methyldiethanolamine (MDEA) and monoethanolamine (MEA). Three MDEA/MEA weight ratios ranging from 27/03 to 23/07, over a concentration range of 2.316–1.996 kmol/m³ for MDEA and of 0.490–1.147 kmol/m³ for MEA were studied. The models take into account the coupling between chemical equilibrium, mass transfer, and the chemical kinetics of all possible chemical reactions involved in the CO₂ reaction with MDEA/MEA solvent. The partial differential equations of the 1D model were solved by two numerical techniques; the finite difference method (FDM) based on in-house coded Barakat–Clark scheme and the finite element method (FEM) based on COMSOL software. The FEM comprehensive model was then used to solve the set of partial differential equations in the 2D cylindrical coordinate system setting. Both FDM and FEM produced very accurate results for both the 1D and 2D models, which were much better than our previously published simplified model. The reaction rate constant obtained for MEA blended into MDEA at 298–333 K was k_MEA = 5.127 × 10⁸ exp(−3373.8/T). In addition, the 2D model, for the first time, has provided the concentration profiles of all the species in both the radial and axial directions of the laminar jet, thereby enabling an understanding of the correct sequence in which the reaction steps involved in the reactive absorption of CO₂ in aqueous mixed amines occur.     

Molecular composition of recycled organic wastes,as determined by solid-state 13C NMR and elemental analyses

Using solid state ¹³C NMR data and elemental composition in a molecular mixing model, we estimated the molecular components of the organic matter in 16 recycled organic (RO) wastes representative of the major materials generated in the Sydney basin area. Close correspondence was found between the measured NMR signal intensities and those predicted by the model for all RO wastes except for poultry manure char. Molecular nature of the organic matter differed widely between the RO wastes. As a proportion of organic C, carbohydrate C ranged from 0.07 to 0.63, protein C from <0.01 to 0.66, lignin C from <0.01 to 0.31, aliphatic C from 0.09 to 0.73, carbonyl C from 0.02 to 0.23, and char C from 0 to 0.45. This method is considered preferable to techniques involving imprecise extraction methods for RO wastes. Molecular composition data has great potential as a predictor of RO waste soil carbon and nutrient outcomes.