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1.
Microwave (MW) hybrid processes are able to disrupt the flocculent structure of complex waste activated sludge, and help promote the recovery of phosphorus as struvite. In this study, to optimize struvite yield, (1) the characteristics of matter released in MW-hybrid treatments were compared, including MW, MW-acid, MW-alkali, MW-H2O2, and MW-H2O2-alkali. The results showed that selective release of carbon, nitrogen, phosphorus, Ca2 +, and Mg2 + achieved by sludge pretreatment using MW-hybrid processes. MW-H2O2 is the recommended sludge pretreatment process for phosphorus recovery in the form of struvite. The ratio of Mg2 +:NH4+-N:PO43 −-P was 1.2:2.9:1 in the supernatant. (2) To clarify the effects of organic matter on struvite recovery, the composition and molecular weight distribution of organic matters were analyzed. Low molecular weight COD was found to facilitate the removal rate of NH4+-N and PO43-P via crystallization, and the amorphous struvite crystals (< 1 kDa) from the filtered solutions had high purity. Therefore, the present study reveals the necessity of taking into consideration the interference effect of high molecular weight organic matters during struvite crystallization from sewage sludge. 相似文献
2.
An efficient technology to treat heavy metal--lead--contaminated soil by microwave radiation 总被引:1,自引:0,他引:1
Jou CJ 《Journal of environmental management》2006,78(1):1-4
Microwave (MW) technology can be used to vitrify contaminated soil wastes and immobilize heavy metal ions in soils. More than 93% of the Pb(II)-contaminated soil was vitrified to a glass/ceramic formation after 30 min of MW radiation. In a 6-year study, the Pb(II) concentration of the vitrified soil in the leaching test was less than 1.0 mg/l, which is substantially below the USEPA regulatory limit of 5.0 mg/l. 相似文献
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Microwave-Assisted Solvent-Free or Aqueous-Based Synthesis of Biodegradable Polymers 总被引:4,自引:0,他引:4
Microwave radiation was used as the energy source for various types of chemical derivatizations of polysaccharides and for the synthesis of biodegradable polyesters in solvent-free or aqueous-based reaction systems. A medium to high degree of substitution was obtained for starch acetates, starch succinates, carboxymethyl konjac, aminated starch, and aminated chitosan. Ring-opening polymerization of lactide and -caprolactone proceeded rapidly even at low power output in the presence of tin octanoate catalyst. Complete monomer conversion and high molecular weight were achieved in less than 6 minutes under nonisothermal conditions. The yield rapidly increased with increasing power output and showed no significant change in a wide range of batch sizes. Polycaprolactone was successfully grafted from starch and konjac acetate in 3 minutes, yielding as high as 24% grafting efficiency and 25% grafting degree. 相似文献
5.
上海城市污水厂污泥处理与利用系统分析 总被引:1,自引:0,他引:1
上海市城市污水处理规划的实施,将在2020年前使该市的城市污水厂污泥产生量从现状的85tDS/d增长至1300-1500tDS/d,将形成可观的污泥消纳压力。预期了该市的污水污泥产生状况,以现有污水污泥处置与利用技术为基础,测算了可行的污泥处置与利用方向及相应的容量,以及满足容量利用的前处理要求。以此为基础,推荐了适宜的容量利用方案,并建议以生物稳定化干化处理为污泥处置与利用前的改性处理步骤,且可在适当的条件下增加厌氧消化环节,提高处理体系的水平与容量宽余度。此污泥处理与利用体系可达到污泥消纳运行的柔性化和可靠性,兼具环境安全性与经济合理性。 相似文献
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城市污水厂污泥热干燥处理技术及其应用分析 总被引:26,自引:0,他引:26
提出采用热干燥处理技术进一步降低脱水泥饼的含水率,介绍了现行的污泥热干燥处理技术,并就该技术在污泥处理中的应用尤其是在焚烧预处理中的应用进行了分析。 相似文献
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微波密封消解法快速测定CODcr 总被引:7,自引:1,他引:7
标准法──重铬酸钾法测定CODCr的缺点是测定时间长,氯离子干扰大。微波密封消解法对此进行了改进。实验结果表明,该法具有消解时间短,减轻了二次污染,准确度高,精密度好等优点,可同标准回流法等效使用。 相似文献
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介绍了放射性废物微波真空干燥处理器的微波漏能现状及所采取的防护措施。监测结果表明,经过防护,有效地减弱了设备的微波漏能,达到了国家防护标准。 相似文献
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